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Second harmonic generation (SHG) is a nonlinear optical response arising exclusively from broken inversion symmetry in the electric-dipole limit. Recently, SHG has attracted widespread interest as a versatile and noninvasive tool for…

Systematic exploration of amorphous ABC heterostructures revealed that nanoscale morphological modifications markedly improved their artificial bulk second-order susceptibility. These amorphous birefringent heterostructures were fabricated…

To add the detailed information to the existed knowledge of nonlinear optics field, the nonlinear optical processes of the second and third order have been discussed in their respective susceptibility tensors in the presence of degenerate…

Optics · Physics 2018-01-29 A Srinivasa Rao

The spatial structure of the transition region between an insulator and an electrolyte solution was studied with x-ray scattering.The electron density profile across the n-hexane/silica sol interface (solutions with 5-nm, 7-nm, and 12-nm…

Soft Condensed Matter · Physics 2009-11-11 Aleksey M. Tikhonov

Second-order nonlinear optical materials enable frequency doubling of light (second-harmonic generation, SHG), which is essential for optoelectronic applications ranging from materials characterization to quantum technologies. However,…

Materials Science · Physics 2026-03-25 Aubrey G. J. Nyiri , Michael J. Waters , James M. Rondinelli

We show that the nonlinear optical response reflects sensitively the electronic structure of transition-metal surfaces and interfaces. $d$ and $s$ electrons may contribute rather differently to the second harmonic generation (SHG) signal.…

Condensed Matter · Physics 2007-05-23 W. H"ubner , K. H. Bennemann , K. Böhmer

In this paper, we propose an improved phase field model for interface capturing in simulating two-phase incompressible flows. The model incorporates a second-order diffusion term, which utilizes a nonlinear coefficient to assess the degree…

Fluid Dynamics · Physics 2025-01-20 Jing-Wei Chen , Chun-Yu Zhang , Hao-Ran Liu , Hang Ding

The linear and nonlinear dynamical susceptibilities of a two level system are calculated as it undergoes a transition to a decoherent state. Analogously to the Glover-Tinkham-Ferrell sum rule of superconductivity, spectral weight in the…

Condensed Matter · Physics 2009-10-31 Gregory Levine

Third-order bound-charge electronic nonlinearities of Si nanocrystals (NCs) embedded in a wide band-gap matrix representing silica are theoretically studied using an atomistic pseudopotential approach. Nonlinear refractive index, two-photon…

Materials Science · Physics 2016-08-17 Hasan Yıldırım , Ceyhun Bulutay

Recent experiments and calculations in topological semimetals have observed anomalously strong second-order optical nonlinearity, but yet whether the enhancement also occurs at surfaces of topological semimetals in general remains an open…

We study nonlinear optical responses in superconducting systems with inversion ($\mathcal{I}$) symmetry-breaking order parameters. We first show that any superconducting system with $\mathcal{I}$ and time-reversal ($\mathcal{T}$) symmetries…

Superconductivity · Physics 2019-12-11 Tianrui Xu , Takahiro Morimoto , Joel E. Moore

The line tension of an electrolyte wetting a non-polar substrate is computed analytically and numerically. The results show that, depending on the value of the apparent contact angle, positive or negative line tension values may be…

Chemical Physics · Physics 2014-11-06 Aaron Dörr , Steffen Hardt

We experimentally explore the fingerprint of the microscopic electron dynamics in second-order harmonic generation (SHG). It is shown that the interbond electron hopping induces a novel source of nonlinear polarization and plays an…

A novel liquid-liquid phase transition has been proposed and investigated in a wide variety of pure substances recently, including water, silica and silicon. From computer simulations using the Stillinger-Weber classical empirical…

Statistical Mechanics · Physics 2015-05-27 Vishwas V Vasisht , Shibu Saw , Srikanth Sastry

Second-order nonlinear optical response allows to detect different properties of the system associated with the inversion symmetry breaking. Here, we use a second harmonic generation effect to investigate the alignment of a…

Mesoscale and Nanoscale Physics · Physics 2020-07-03 E. A. Stepanov , S. V. Semin , C. R. Woods , M. Vandelli , A. V. Kimel , K. S. Novoselov , M. I. Katsnelson

In this work the role that charge delocalization plays in the non-linear optical response of ionic liquids is evaluated. The first hyperpolarizability for the non-linear process of second harmonic generation (SHG) and second…

Materials Science · Physics 2024-02-01 C. D. Rodriguez-Fernandez L. M. Varela , C. Schroder , E. Lopez Lago

We present in detail the formulation of the ab initio theory we have developed for the calculation of the macroscopic second-order susceptibility $\chi^{(2)}$. We find a general expression for $\chi^{(2)}$ valid for any fields, containing…

Materials Science · Physics 2015-05-19 Eleonora Luppi , Hannes Hübener , Valérie Véniard

Chip-scale nonlinear optics enables strong light-matter interactions within compact devices, serving as a fundamental platform for multifunctional integrated photonics from classical optical signal processing to quantum information…

High-order harmonic generation (HHG) provides a powerful optical tool for probing ultrafast dynamics on the attosecond timescale. While its mechanisms in gases and solids are well-established, understanding nonlinear optical responses in…

Charge transport processes at interfaces which are governed by complex interfacial electronic structure play a crucial role in catalytic reactions, energy storage, photovoltaics, and many biological processes. Here, the first soft X-ray…