Related papers: Crystal Growth and High-Pressure Effects of Bi-Bas…
We studied the c-axis transport of Bi$_2$Sr$_2$CaCu$_2$O$_{8+\delta}$ (Bi2212) cross-whisker junctions formed by annealing ``naturally'' formed whisker junctions. These frequently appear during growth when the $ab$-faces of neighboring…
The first step towards high critical currents in Bi-2212 wires was the comprehension that the supercurrent is blocked over long lengths by filament-diameter bubbles grown during the melt stage, which cause expansion of the wire diameter and…
Large crystals of La$_{2-x}$Ca$_{1+x}$Cu$_2$O$_{6}$ (La-Ca-2126) with $x=0.10$ and 0.15 have been grown and converted to bulk superconductors by high-pressure oxygen annealing. The superconducting transition temperature, $T_c$, is as high…
Here, we describe synthesis of TMD crystals using a two-step flux growth method that eliminates a major potential source of contamination. Detailed characterization of TMDs grown by this two-step method reveals charged and isovalent defects…
PrOBiS2 single crystals were successfully grown using a KCl flux. The obtained crystals had a plate-like shape with a typical size of 0.5-1.0 mm and well-developed ab-plane. The Pr valence of the grown crystals, as determined by an X-ray…
An intrinsic Josephson junction has been successfully fabricated without any micro-fabrication technique. Two Bi2212 whiskers were crossed with one another and joined by post-annealing. The inter-whisker electrical transport properties were…
We present a two-step technique for the synthesis of superconducting CuxBi2Se3. Cu0.15Bi2Se3 single crystals were synthesized using the melt-growth method. Although these samples are non-superconducting, they can be employed to generate…
Since the discovery of superconductivity at 200 K in H3S [1] similar or higher transition temperatures, Tcs, have been reported for various hydrogen-rich compounds under ultra-high pressures [2]. Superconductivity was experimentally proved…
We have studied Bi-2212 microcrystals aged at ambient conditions for 40 days. Combined x-ray absorption near edge structure and x-ray fluorescence measurements with micrometer space resolution show both an increase of Cu$^{+}$ with respect…
We report anomalous features in the normal-state resistivity of single crystalline Bi_2Sr_2CaCu_2O_8 whiskers near some characteristic temperature T* \~ 250 K. From these varied oxygen-doping samples, the resistance (R) was found to deviate…
A parent insulator of the Bi-based high-$T_c$ superconductor Bi$_2$Sr$_{2-x}$La$_x$CaCu$_2$O$_{8+\delta}$ was successfully grown by a traveling solvent floating zone method. The in-plane resistivity $\rho_{ab}$ shows metallic behavior…
Single crystals of thallium-based cuprates with the general formula Tl$_{2}$Ba$_{2}$Ca$_{n-1}$Cu$_{n}$O$_{x}$(n=1,2,3) have been grown by the flux method. The superconducting transition temperatures determined by the ac magnetic…
High-quality single crystals are essentially needed for the investigation of the novel bulk properties of unconventional superconductors. The availability of such crystals grown by the floating-zone method has helped to unveil the…
Measurements on resistivity and magnetic susceptibility have been carried out for Bi single crystals under pressures up to 10.5GPa. The temperature dependent resistivity shows a semimetallic behavior at ambient and low pressures (below…
[(SnSe)$_{1+\delta}$]$_m$(NbSe$_2$) ($m$ = 1-6, 8, and 12) highly orientated crystals 1-2 mm in size and well-defined c-planes were successfully grown using CsCl/KCl flux, including the first growth of crystals with $m = 12$. The stacked…
Highly-perfect platelet single crystals of Tl_2Ba_2CuO_{6+d} (Tl-2201) were grown by a self-flux technique. A novel encapsulation scheme allowed the precursors to react prior to the sealing required to contain volatile thallium oxides, and…
We grew (Hg,Re)Ba$_2$Ca$_2$Cu$_3$O$_{8+\delta}$ ((Hg,Re)1223) single crystals with good reproducibility via the single-step flux method using monoxides as raw materials. A double-sealing method using a thick-walled quartz tube and a…
Pressure effects on a recently discovered BiS2-based superconductor Bi2(O,F)S2 (Tc = 5.1 K) were examined via two different methods; high pressure resistivity measurement and high pressure annealing. The effects of these two methods on the…
A new method to grow very high quality single crystals of the superconducting HgBa2CuO4+{\delta} mercury cuprates is reported. The single crystals are platelet-shaped, with surfaces of high optical quality and good crystallographic…
High-quality Bi$_{2+x}$Sr$_{2-x}$CuO$_{6+\delta}$(0$<$x$\leq$0.5) single crystals have been grown successfully using the travelling-solvent floating-zone(TSFZ) technique. The samples with $x >$ 0.05 are in the underdoped level. The…