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In a low-temperature study with a scanning tunneling microscope (STM), the irreducible lateral motion of a CO molecule adsorbed on a Si(001) surface showed a hyperlinear dependence on the tunneling current. This dependence implies that the…

Using scanning tunneling microscopy and spectroscopy we investigate the adsorption properties and ring-closing reaction of a diarylethene derivative (C5F-4Py) on a Ag(111) surface. We identify an electron-induced reaction mechanism, with a…

Mesoscale and Nanoscale Physics · Physics 2020-12-22 Gaël Reecht , Christian Lotze , Dmytro Sysoiev , Thomas Huhn , Katharina J Franke

We report the mechanically induced formation of a silicon-hydrogen covalent bond and its application in engineering nanoelectronic devices. We show that using the tip of a non-contact atomic force microscope (NC-AFM), a single hydrogen atom…

Mesoscale and Nanoscale Physics · Physics 2017-08-03 Taleana Huff , Hatem Labidi , Mohammad Rashidi , Mohammad Koleini , Roshan Achal , Mark Salomons , Robert A. Wolkow

In their article, Zhang et al. [Phys. Rev. B 86, 024516 (2012)] present a remarkable result for A$_x$(S)$_y$TiNCl compounds ($\alpha$-phase TiNCl partially intercalated with alkali A and optionally co-intercalated molecular species S),…

Superconductivity · Physics 2015-06-23 Dale R. Harshman , Anthony T. Fiory

The Si(111)7x7 surface was observed by reflection electron microscopy (REM) and scanning tunneling microscopy (STM) simultaneously in an ultra-high vacuum electron microscope. The distance between the STM tip and the Si surface was detected…

Materials Science · Physics 2007-05-23 Y. Naitoh , K. Takayanagi , Y. Ohshima , H. Hirayama

In CaFe2As2, superconductivity can be achieved by applying a modest c-axis pressure of several kbar. Here we use scanning tunneling microscopy/spectroscopy (STM/S) to explore the STM tip pressure effect on single crystals of CaFe2As2. When…

Superconductivity · Physics 2016-05-06 J. -X. Yin , J. H. Wang , Z. Wu , A. Li , X. J. Liang , H. Q. Mao , G. F. Chen , B. Lv , C. -W. Chu , H. Ding , S. H. Pan

Spin-momentum locking in the surface mode of topological insulators (TI) leads to the surface accumulation of spin-polarized electrons caused by bias current flows through TI samples. Here, we demonstrate that scanning tunneling microscopy…

Mesoscale and Nanoscale Physics · Physics 2020-04-08 S. Tyagi , M. Dreyer , D. Bowen , D. Hinkel , P. J. Taylor , A. L. Friedman , R. E. Butera , C. Krafft , I. Mayergoyz

The hydrogen abstraction reaction between H and H$_2$S, yielding HS and H$_2$ as products, has been studied within the framework of interstellar surface chemistry. High-temperature rate constants up to 2000 K are calculated in the gas phase…

Astrophysics of Galaxies · Physics 2017-12-07 Thanja Lamberts , Johannes Kästner

A first principles theory of inelastic tunneling between a model probe tip and an atom adsorbed on a surface is presented, extending the elastic tunneling theory of Tersoff and Hamann. The inelastic current is proportional to the change in…

Materials Science · Physics 2009-10-31 K. Stokbro , Ben Yu-Kuang Hu , C. Thirstrup , X. C. Xie

In this work, we studied the adsorption behavior of deposited Si atoms along with their diffusion and other dynamic processes on a Pb monolayer-covered Si(111) surface from 125-230 K using a variable-temperature scanning tunneling…

Mesoscale and Nanoscale Physics · Physics 2017-06-28 Rakesh Kumar , Chuang-Kai Fang , Chih-Hao Lee , Ing-Shouh Hwang

We report on the experimental observation by scanning tunneling microscopy at low temperature of ring-like features that appear around Co metal clusters deposited on a clean (110) oriented surface of cleaved p-type InAs crystals. These…

Materials Science · Physics 2012-03-14 D. A. Muzychenko , K. Schouteden , S. V. Savinov , N. S. Maslova , V. I. Panov , C. Van Haesendonck

Recent experiments on the silicon terminated $3\times 2$ SiC(100) surface indicated an unexpected metallic character upon hydrogen adsorption. This effect was attributed to the bonding of hydrogen to a row of Si atoms and to the…

Materials Science · Physics 2009-11-11 R. Di Felice , C. M. Bertoni , C. A. Pignedoli , A. Catellani

Here we report the direct observation of single electron charging of a single atomic Dangling Bond (DB) on the H-Si(100) 2x1 surface. The tip of a scanning tunneling microscope is placed adjacent to the DB to serve as a single electron…

Mesoscale and Nanoscale Physics · Physics 2015-06-15 Marco Taucer , Lucian Livadaru , Paul G. Piva , Roshan Achal , Hatem Labidi , Jason L. Pitters , Robert A. Wolkow

We report a characterization of surfaces of the dichalcogenide TaSe$_2$ using scanning tunneling microscopy and spectroscopy (STM/S) at 150 mK. When the top layer has the 2H structure and the layer immediately below the 1T structure, we…

The temperature dependence of hydrogen (H) desorption from Si(100) H-terminated surfaces by a scanning tunneling microscope (STM) is reported for negative sample bias. It is found that the STM induced H desorption rate ($R$) decreases…

Materials Science · Physics 2009-10-31 C. Thirstrup , M. Sakurai , T. Nakayama , K. Stokbro

Controlling selectivity of reactions is a quest in chemistry. Here, we demonstrate reversible and selective bond formation and dissociation promoted by tip-induced reduction-oxidation reactions on a surface. Molecular rearrangements leading…

Chemical Physics · Physics 2022-07-19 Florian Albrecht , Shadi Fatayer , Iago Pozo , Ivano Tavernelli , Jascha Repp , Diego Peña , Leo Gross

An understanding of hydrogen diffusion on metal surfaces is important, not just for its role in heterogeneous catalysis and hydrogen fuel cell technology, but also because it provides model systems where tunneling can be studied under…

Chemical Physics · Physics 2014-04-30 Eliza M. McIntosh , K. Thor Wikfeldt , John Ellis , Angelos Michaelides , William Allison

We report on the oxidation of self-assembled silicene nanoribbons grown on the Ag(110) surface using Scanning Tunneling Microscopy and High-Resolution Photoemission Spectroscopy. The results show that silicene nanoribbons present a strong…

The conductance of C60 on Cu(100) is investigated with a low-temperature scanning tunneling microscope. At the transition from tunneling to the contact regime the conductance of C60 adsorbed with a pentagon-hexagon bond rises rapidly to…

Materials Science · Physics 2011-12-12 N. Neel , J. Kroger , L. Limot , T. Frederiksen , M. Brandbyge , R. Berndt

Hydrogen (H) plays a key role in the near-to-room temperature superconductivity of hydrides at megabar pressures. This suggests that H doping could have similar effects on the electronic and phononic spectra of materials at ambient pressure…

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