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Previously, we have derived a generalization of the canonical fluctuation relation between heat capacity and energy fluctuations $C=\beta^{2}<\delta U^{2}>$, which is able to describe the existence of macrostates with negative heat…

Statistical Mechanics · Physics 2013-07-31 L. Velazquez , S. Curilef

We demonstrate that the Gibbs-Shannon entropy is applicable to non-equilibrium systems of any size and boundary conditions. The change in microscopic entropy can be attributed to the stochastic nature of dynamic processes and to the…

Statistical Mechanics · Physics 2020-10-13 Jianzhong Wu

The Fluctuation-Dissipation Theorem (FDT) is a powerful tool to estimate the thermal noise of physical systems in equilibrium. In general however, thermal equilibrium is an approximation, or cannot be assumed at all. A more general…

Statistical Mechanics · Physics 2021-10-08 Alex Fontana , Richard Pedurand , Vincent Dolique , Ghaouti Hansali , Ludovic Bellon

Thermodynamics of quantum coherence has attracted growing attention recently, where the thermodynamic advantage of quantum superposition is characterized in terms of quantum thermodynamics. We investigate thermodynamic effects of quantum…

Statistical Mechanics · Physics 2017-10-25 Yûto Murashita , Zongping Gong , Yuto Ashida , Masahito Ueda

The thermal response of nonequilibrium systems requires the knowledge of concepts that go beyond entropy production. This is showed for systems obeying overdamped Langevin dynamics, either in steady states or going through a relaxation…

Statistical Mechanics · Physics 2016-08-31 Gianmaria Falasco , Marco Baiesi

In small systems where relevant energies are comparable to thermal agitation, fluctuations are of the order of average values. In systems in thermodynamical equilibrium, the variance of these fluctuations can be related to the dissipation…

Statistical Mechanics · Physics 2007-05-23 Nicolas Garnier , Ciliberto Sergio

Although nonequilibrium work and fluctuation relations have been studied in detail within classical statistical physics, extending these results to open quantum systems has proven to be conceptually difficult. For systems that undergo…

In Szilard's engine, measurement and feedback allows to extract work from an equilibrium environment, a process otherwise forbidden by the laws of thermodynamics. Recent theoretical developments have established fluctuation theorems and…

Mesoscale and Nanoscale Physics · Physics 2025-11-14 David Barker , Sebastian Lehmann , Kimberly A. Dick , Peter Samuelsson , Ville Maisi , Patrick P. Potts

Time-integrated quantities such as work and heat increase incessantly in time during nonequilibrium processes near steady states. In the long-time limit, the average values of work and heat become asymptotically equivalent to each other,…

Statistical Mechanics · Physics 2015-03-26 Kwangmoo Kim , Chulan Kwon , Hyunggyu Park

A system is glassy when the observation time is much smaller than the equilibration time. A unifying thermodynamic picture of the glassy state is presented. Slow configurational modes are in quasi-equilibrium at an effective temperature. It…

Statistical Mechanics · Physics 2009-10-31 Th. M. Nieuwenhuizen

Thermodynamic length is a path function that generalizes the notion of length to the surface of thermodynamic states. Here, we show how to measure thermodynamic length in far-from-equilibrium single molecule experiments using the work…

Statistical Mechanics · Physics 2014-05-27 Edward H. Feng , Gavin E. Crooks

We have analyzed the spectral density of fluctuations of the energy flux through a mesoscopic constriction between two equilibrium reservoirs. It is shown that at finite frequencies, the fluctuating energy flux is not related to the thermal…

Mesoscale and Nanoscale Physics · Physics 2015-05-18 Dmitri V. Averin , Jukka P. Pekola

Fluctuation theorems establish exact relations for nonequilibrium dynamics, profoundly advancing the field of stochastic thermodynamics. In this work, we extend quantum fluctuation theorems beyond the traditional thermodynamic framework to…

Quantum Physics · Physics 2026-02-24 Kun Zhang , Mo-Yang Ni , Hai-Long Shi , Xiao-Hui Wang , Jin Wang

We derive the fluctuation theorem for quantum-state statistics that can be obtained when we initially measure the total energy of a quantum system at thermal equilibrium, let the system evolve unitarily, and record the quantum-state data…

Statistical Mechanics · Physics 2018-08-01 Naoto Tsuji , Masahito Ueda

Two-state models provide phenomenological descriptions of many different systems, ranging from physics to chemistry and biology. We investigate work fluctuations in an ensemble of two-state systems driven out of equilibrium under the action…

Statistical Mechanics · Physics 2009-11-10 F. Ritort

Dispersion forces between neutral material bodies are due to fluctuations of the polarization of the bodies. For bodies in equilibrium these forces are often referred to as Casimir-Lifshitz forces. For bodies in relative motion, in addition…

Quantum Physics · Physics 2022-09-12 Iver Brevik , Boris Shapiro , Mário Silveirinha

An intriguing phenomenon in non-equilibrium quantum thermodynamics is the asymmetry of thermal processes. Relaxation to thermal equilibrium is the most important dissipative process, being a key concept for the design of heat engines and…

Quantum Physics · Physics 2025-04-09 Álvaro Tejero , Rafael Sánchez , Laiachi El Kaoutit , Daniel Manzano , Antonio Lasanta

In the context of the dynamical evolution in a non-stationary thermal bath, we construct a family of fluctuation relations for the entropy production that are not verified by the work performed on the system. We exhibit fluctuation…

Statistical Mechanics · Physics 2013-05-29 Raphael Chetrite

In this work, we have studied simple models that can be solved analytically to illustrate various fluctuation theorems. These fluctuation theorems provide symmetries individually to the distributions of physical quantities like the…

Statistical Mechanics · Physics 2015-05-20 Mamata Sahoo , Sourabh Lahiri , A. M. Jayannavar

We study Brownian motion driven with both conservative and nonconservative external forces. By using the thermodynamic approach of the theory of Brownian motion we obtain the Fokker-Planck equation and derive expressions for the Fluctuation…

Statistical Mechanics · Physics 2009-11-13 A. Perez-Madrid , I. Santamaria-Holek
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