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Within the framework of many-body perturbation theory (MBPT) integrated with density functional theory (DFT), a novel defect-subspace projection GW method, the so-called p-GW, is proposed. By avoiding the periodic defect interference…

Materials Science · Physics 2022-11-23 Guido Gandus , Youseung Lee , Leonard Deuschle , Mathieu Luisier , Daniele Passerone

Defects influence the properties and functionality of all crystalline materials. For instance, point defects participate in electronic (e.g. carrier generation and recombination) and optical (e.g. absorption and emission) processes critical…

Materials Science · Physics 2020-06-17 Sunghyun Kim , Samantha N. Hood , Ji-Sang Park , Lucy D. Whalley , Aron Walsh

Precise and scalable defect engineering of 2D nanomaterials is acutely sought-after in contemporary materials science. Here we present defect engineering in monolayer graphene and molybdenum disulfide (MoS$_2$) by irradiation with noble gas…

Atomic layers of black phosphorus (P) isolated from its layered bulk make a new two-dimensional (2D) semiconducting crystal with sizable direct bandgap, high carrier mobility, and promises for 2D electronics and optoelectronics. However,…

Mesoscale and Nanoscale Physics · Physics 2023-05-03 Zenghui Wang , Arnob Islam , Rui Yang , Xu-Qian Zheng , Philip X. -L. Feng

Point defects give rise to sharp modifications in the structures and electronic properties of two-dimensional metals, offering an atomic-level platform for fundamental studies and potential applications. In this work, we investigate…

Mesoscale and Nanoscale Physics · Physics 2026-02-05 Van Dong Pham , Arpit Jain , Chengye Dong , Li-Syuan Lu , Joshua A. Robinson , Achim Trampert , Roman Engel-Herbert

Point defects have a strong influence on the physical properties of materials, often dominating the electronic and optical behavior in semiconductors and insulators. The simulation and analysis of point defects is therefore crucial for…

Materials Science · Physics 2024-03-12 Jimmy-Xuan Shen , Lars F. Voss , Joel Basile Varley

Making use of the energetics and equations of state of defective uranium dioxide that calculated with first-principles method, we demonstrate a possibility of constraining the formation energy of point defects by measuring the transition…

Materials Science · Physics 2013-05-30 Hua Y. Geng , Hong X. Song , Q. Wu

In this work, we have systematically studied structural, electronic and magnetic properties of atomic scale defects in 2D transition metal dichalcogenides MX$_2$, (M = Mo and W; X = S, Se and Te) by density functional theory. Various types…

Mesoscale and Nanoscale Physics · Physics 2015-12-24 Soumyajyoti Haldar , Hakkim Vovusha , Manoj Kumar Yadav , Olle Eriksson , Biplab Sanyal

Drawing on their atomically thin structure, two-dimensional (2D) materials present a groundbreaking avenue for the precision fabrication and systematic manipulation of quantum defects. Through a method grounded in site-symmetry principles,…

Materials Science · Physics 2024-05-22 Jeng-Yuan Tsai , Weiyi Gong , Qimin Yan

The supercell approach enables us to treat the electronic structure of defective crystals, but the calculated energy bands are too complicated to understand or to compare with angle-resolved photoemission spectra because of inevitable zone…

Materials Science · Physics 2014-04-01 M. Farjam

Phase stability and properties of two-dimensional phosphorus carbide, P$_x$C$_{1-x}$, are investigated using the first-principles method in combination with cluster expansion and Monte Carlo simulation. Monolayer P$_x$C$_{1-x}$ is found to…

Materials Science · Physics 2021-03-02 Xiaoyang Ma , Jun Zhou , Tong Yang , Dechun Li , Yuan Ping Feng

Black phosphorus (BP) is receiving significant attention because of its direct 0.4-1.5 eV layer-dependent band gap and high mobility. Because BP devices rely on exfoliation from bulk crystals, there is a need to understand native impurities…

Mesoscale and Nanoscale Physics · Physics 2018-09-11 J. V. Riffle , C. Flynn , B. St. Laurent , C. A. Ayotte , C. A. Caputo , S. M. Hollen

Tuning band gaps in two-dimensional (2D) materials is of great interest in the fundamental and practical aspects of contemporary material sciences. Recently, black phosphorus (BP) consisting of stacked layers of phosphorene was…

Materials Science · Physics 2017-09-13 Sun-Woo Kim , Hyun Jung , Hyun-Jung Kim , Jin-Ho Choi , Su-Huai Wei , Jun-Hyung Cho

The metastable 1$T'$ phase of layered transition metal dichalcogenides has recently attracted considerable interest due to electronic properties, possible topological electronic phases and catalytic activity. We report a comprehensive…

Materials Science · Physics 2018-04-13 Michele Pizzochero , Oleg V. Yazyev

Two-dimensional carbon, or graphene, is a semi-metal that presents unusual low-energy electronic excitations described in terms of Dirac fermions. We analyze in a self-consistent way the effects of localized (impurities or vacancies) and…

Strongly Correlated Electrons · Physics 2009-11-11 N. M. R. Peres , F. Guinea , A. H. Castro Neto

Doping of a two-dimensional (2D) material by impurity atoms occurs \textit{via} two distinct mechanisms: absorption of the dopants by the 2D crystal or adsorption on its surface. To distinguish the relevant mechanism, we systematically dope…

Materials Science · Physics 2023-04-04 Joel Davidsson , Fabian Bertoldo , Kristian S. Thygesen , Rickard Armiento

Deviations from the perfect atomic arrangements in crystals play an important role in affecting their properties. Similarly, diffusion of such deviations is behind many microstructural changes in solids. However, observation of point defect…

Materials Science · Physics 2014-07-28 Jani Kotakoski , Clemens Mangler , Jannik C. Meyer

The influence of intrinsic defects of 1T-TaS2 on charge density waves (CDW) is studied using scanning tunneling microscopy and spectroscopy (STM, STS), angle-resolved photoelectron spectroscopy (ARPES), and density functional theory (DFT).…

We propose an improved structure of an optical biosensor based on a photonic crystal (PC) with a defect layer (DL), which can detect the concentration of SARS-CoV-2 in water by defect mode (DM) shift. We investigated 4 types of defective…

Optics · Physics 2022-08-10 I. M. Efimov , N. A. Vanyushkin , A. H. Gevorgyan

In this paper, the characteristic matrix method is employed to theoretically investigate the propagation of electromagnetic waves through one-dimensional defective lossy photonic crystals (PCs) composed of negative index materials (NIMs)…

Optics · Physics 2013-11-12 Alireza Aghajamali , Mozhgan Hayati , Chien-Jang Wu , Mahmood Barati