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It is shown that a minimum realization of the dynamical mean-field theory (DMFT) can be achieved by mapping a correlated lattice model onto an impurity model in which the impurity is coupled to an uncorrelated bath that consists of a single…

Strongly Correlated Electrons · Physics 2009-11-07 M. Potthoff

In the near future, material and drug design may be aided by quantum computer assisted simulations. These have the potential to target chemical systems intractable by the most powerful classical computers. However, the resources offered by…

The simulation of strongly correlated electron systems remains a formidable challenge. Certain experimentally relevant dynamical response functions are especially difficult to calculate, due to issues of finite-size effects and the ill…

Strongly Correlated Electrons · Physics 2026-03-25 Petar Brinić , Hugo U. R. Strand , Jakša Vučičević

Recently we proposed an information entropy based method for electronic structure calculations within the density-matrix functional theory(DMFT) (Phys. Rev. Lett. 128, 013001), dubbed as $i$-DMFT. Comments have been raised regarding the…

Quantum Physics · Physics 2022-07-07 Jian Wang , Evert Jan Baerends

A density functional theory for many-body lattice models is considered in which the single-particle density matrix is the basic variable. Eigenvalue equations are derived for solving Levy's constrained search of the interaction energy…

Strongly Correlated Electrons · Physics 2009-10-31 R. Lopez-Sandoval , G. M. Pastor

In this work we introduce a generalized flavor, in the sense of generalized Kohn-Sham density functional theory (gKS-DFT), of the recently derived local potential functional embedding theory (LPFET) [J. Chem. Theory Comput. 2025, 21, 20,…

Strongly Correlated Electrons · Physics 2026-02-18 Wafa Makhlouf , Bruno Senjean , Emmanuel Fromager

Density functional theory (DFT) has greatly expanded our ability to affordably compute and understand electronic ground states, by replacing intractable {\em ab initio} calculations by models based on paradigmatic physics from high- and…

Chemical Physics · Physics 2023-03-29 Tim Gould , Derk P. Kooi , Paola Gori-Giorgi , Stefano Pittalis

Two (so-called left and right) variants of N-centered ensemble density-functional theory (DFT) [Senjean and Fromager, Phys. Rev. A 98, 022513 (2018)] are presented. Unlike the original formulation of the theory, these variants allow for the…

Strongly Correlated Electrons · Physics 2020-02-25 Bruno Senjean , Emmanuel Fromager

A density functional theory (DFT) framework is presented that links functional derivatives of free-energy functionals to non-linear static density response functions in quantum many-body systems. Within this framework, explicit expressions…

In this work, we introduce an original self-consistent scheme based on the one-body reduced density matrix ($\gamma$) formalism. A significant feature of this methodology is the utilization of an optimal unitary transformation of the…

Strongly Correlated Electrons · Physics 2023-11-10 Quentin Marécat , Benjamin Lasorne , Emmanuel Fromager , Matthieu Saubanère

This work presents an alternative, general, and in-principle exact extension of electronic Kohn-Sham density functional theory (KS-DFT) to the fully quantum-mechanical molecular problem. Unlike in existing multi-component or…

Chemical Physics · Physics 2024-05-14 Emmanuel Fromager , Benjamin Lasorne

The one-dimensional Hubbard model is investigated by means of two different cluster schemes suited to introduce short-range spatial correlations beyond the single-site Dynamical Mean-Field Theory, namely the Cluster-Dynamical Mean-Field…

Strongly Correlated Electrons · Physics 2007-08-07 M. Capone , M. Civelli , S. S. Kancharla , C. Castellani , G. Kotliar

We present a molecular extension of our recently proposed Green's function embedding method, interacting-bath dynamical embedding theory (ibDET), for computing charged excitation energies at the $GW$ and EOM-CCSD levels. Starting from…

Chemical Physics · Physics 2026-04-06 Christian Venturella , Jiachen Li , Tianyu Zhu

In this work we get insight into the impact of reduced density matrix functionals on the quality of removal/addition energies obtained using the Extended Koopmans' Theorem (EKT). Within reduced density matrix functional theory (RDMFT) the…

Strongly Correlated Electrons · Physics 2022-12-26 S. Di Sabatino , J. Koskelo , J. A. Berger , P. Romaniello

We use exact diagonalization to study the eigenstate thermalization hypothesis (ETH) in the quantum dimer model on the square and triangular lattices. Due to the nonergodicity of the local plaquette-flip dynamics, the Hilbert space, which…

Statistical Mechanics · Physics 2017-09-25 Zhihao Lan , Stephen Powell

The process of renormalisation in nonperturbative Hamiltonian Effective Field Theory (HEFT) is examined in the $\Delta$-resonance scattering channel. As an extension of effective field theory incorporating the L\"uscher formalism, HEFT…

High Energy Physics - Lattice · Physics 2022-08-31 Curtis D. Abell , Derek B. Leinweber , Anthony W. Thomas , Jia-Jun Wu

We construct and apply an exchange-correlation functional for the one-dimensional Hubbard model. This functional has built into it the Luttinger-liquid and Mott-insulator correlations, present in the Hubbard model, in the same way in which…

Strongly Correlated Electrons · Physics 2007-05-23 K. Capelle , N. A. Lima , M. F. Silva , L. N. Oliveira

Ensemble density functional theory (eDFT) is an exact time-independent alternative to time-dependent DFT (TD-DFT) for the calculation of excitation energies. Despite its formal simplicity and advantages in contrast to TD-DFT (multiple…

Strongly Correlated Electrons · Physics 2017-01-19 Killian Deur , Laurent Mazouin , Emmanuel Fromager

Electronic correlated systems are often well described by dynamical mean field theory (DMFT). While DMFT studies have mainly focused hitherto on one-particle properties, valuable information is also enclosed into local two-particle Green's…

Strongly Correlated Electrons · Physics 2012-09-25 Georg Rohringer , Angelo Valli , Alessandro Toschi

We present an embedding approach based on localized basis functions which permits an efficient application of the dynamical mean field theory (DMFT) to inhomogeneous correlated materials, such as semi-infinite surfaces and heterostructures.…

Strongly Correlated Electrons · Physics 2009-11-13 H. Ishida , A. Liebsch
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