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Related papers: Rapid Recombination by Cadmium Vacancies in CdTe

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In photovoltaic diodes recombination of photogenerated electrons and holes is a major loss process. Biological light harvesting complexes (LHCs) prevent recombination via the use of cascade structures, which lead to spatial separation of…

Layered indium selenide (InSe) is a van der Waals solid that has emerged as a promising material for high-performance ultrathin solar cells. The optoelectronic parameters that are critical to photoconversion efficiencies, such as hot…

Metastable defects can decisively influence the diode factor and thus the efficiency of a solar cell. The diode factor is also influenced by the doping level and the recombination mechanisms in the solar cell. Here we quantify how the…

Applied Physics · Physics 2025-12-01 T. Wang , F. Ehre , T. P. Weiss , B. Veith-Wolf , V. Titova , N. Valle , M. Melchiorre , J. Schmidt , S. Siebentritt

Studies of n-CdZnTe crystals (photoluminescence, extrinsic photoconductivity, Hall effect, time-of-flight technique) have shown that the excess concentration of vacancies of cadmium (Vcd) is the main reason of low, as a rule, values of…

Materials Science · Physics 2007-05-23 O. A. Matveev , V. E. Sedov , V. P. Karpenko , A. I. Terent'ev , N. K. Zelenina , A. A. Tomasov

The radiative recombination of electron-hole pairs represents a great challenge to the photon-to-charge efficiency in photocell. In this paper, we visit the radiative recombination rate (RRR) in a quantum photocell with or without three…

Mesoscale and Nanoscale Physics · Physics 2024-02-26 Jing-Yi Chen , Shun-Cai Zhao

This paper reports on the investigation of the electronic properties of a thin film CdS/CdTe solar cell with the Ion Beam Induced Charge (IBIC) technique. The device under test is a thin film (total thickness around 10 um) multilayer…

Instrumentation and Detectors · Physics 2016-08-31 E. Colombo , A. Bosio , S. Calusi , L. Giuntini , A. Lo Giudice , C. Manfredotti , M. Massi , P. Olivero , A. Romeo , N. Romeo , E. Vittone

By application of the ac admittance spectroscopy method, the defect state energy distributions were determined in CdTe incorporated in thin film solar cell structures concluded on ZnO, ZnSe, and ZnS buffer layers. Together with the…

Materials Science · Physics 2015-10-30 Y. G. Fedorenko , J. D. Major , A. Pressman , L. J. Phillips , K. Durose

There is evidence that interface recombination in Cu2ZnSnS4 solar cells contributes to the open-circuit voltage deficit. Our hybrid density functional theory calculations suggest that electron-hole recombination at the Cu2ZnSnS4/CdS…

Materials Science · Physics 2019-01-23 Ji-Sang Park , Sunghyun Kim , Samantha N. Hood , Aron Walsh

The power conversion efficiencies (PCEs) of organic solar cells (OSCs) using non-fullerene acceptors (NFAs) have now reached 18%. However, this is still lower than inorganic solar cells, for which PCEs >20% are commonplace. A key reason is…

Electrodeposited thin film cells have been fabricated with record-breaking efficiencies of 11.4%. This presentation examines conversion mechanisms in cells with a focus on the effect of CdS buffer layers using a range of complementary…

Mesoscale and Nanoscale Physics · Physics 2010-06-10 J. P. Connolly , Z. Djebbour , A. Darga , C. Bazin , D. Mencaraglia , M. Benosman , N. Bodereau , JF Guillemoles , D. Lincot , J. Kessler , N. Naghavi , J. Kurdi , O. Kerrec

Surface recombination has a major impact on the open-circuit voltage ($V_\text{oc}$) of organic photovoltaics. Here, we study how this loss mechanism is influenced by imbalanced charge transport in the photoactive layer. As a model system,…

Cadmium sulfide (CdS) is a well-known low-bandgap photocatalyst, but its efficiency is often hindered by rapid photo-generated carrier recombination and a limited number of active catalytic sites. To overcome these challenges, this study…

We propose a solar thermal energy conversion system consisting of a solar absorber, a thermoradiative cell or negative illumination photodiode, and a photovoltaic cell. Because it is a heat engine, this system can also be paired with…

Pnictogen chalcohalides (MChX, M = Bi, Sb; Ch = S, Se; X = I, Br) represent an emerging class of nontoxic photovoltaic absorbers, valued for their favorable synthesis conditions and excellent optoelectronic properties. Despite their…

CdTe has been a special semiconductor for constructing the lowest-cost solar cells and the CdTe-based Cd1-xZnxTe alloy has been the leading semiconductor for radiation detection applications. The performance currently achieved for the…

Numerical and semi-analytical models are presented for photon-enhanced-thermionic-emission (PETE) devices. The models take diffusion of electrons, inhomogeneous photogeneration, and bulk and surface recombination into account. The…

Materials Science · Physics 2012-08-27 Aapo Varpula , Mika Prunnila

Recombination of photogenerated charge carriers in polymer bulk heterojunction (BHJ) solar cells reduces the short circuit current (Jsc) and the fill factor (FF). Identifying the mechanism of recombination is, therefore, fundamentally…

Materials Science · Physics 2015-05-20 Sarah R. Cowan , Anshuman Roy , Alan J. Heeger

Reducing the thickness of Cu(In,Ga)Se2 solar cells is a key objective in order to reduce production cost and to improve sustainability. The major challenge for sub-micron Cu(In,Ga)Se2 cells is the recombination at the backside. In standard…

CdTe and CdS are emerging as the most promising materials for thin film photovoltaics in the quest of the achievement of grid parity. The major challenge for the advancement of grid parity is the achievement of high quality at the same time…

Interface recombination at the absorber buffer interface impedes the efficiency of a solar cell with an otherwise excellent absorber. The internal voltage or the quasi-Fermi level splitting (qFLs) measures the quality of the absorber.…