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Molecular wires are essential components for future nanoscale electronics. However, the preparation of individual long conductive molecules is still a challenge. MMX metal-organic polymers are quasi-one-dimensional sequences of single…

Mesoscale and Nanoscale Physics · Physics 2019-10-08 Pablo Ares , Pilar Amo-Ochoa , Jose M. Soler , Juan Jose Palacios , Julio Gomez-Herrero , Felix Zamora

The dependence of electron transfer rates and yields in bridged molecular systems on the bridge length, and the dependence of the zero-bias conduction of molecular wires on wire length are discussed. Both phenomena are controlled by…

Chemical Physics · Physics 2007-05-23 Spiros Skourtis , Abraham Nitzan

We report on a model of polymer nanocomposites with fibrous fillers which explicitly considers the microscopic filler features and replicates the composites as random distributions of particles interconnected via electron tunneling. By…

Disordered Systems and Neural Networks · Physics 2009-09-22 G. Ambrosetti , C. Grimaldi , T. Maeder , A. Danani , P. Ryser

Molecular dynamics simulations were used to explain the origin and properties of electrical double-layer capacitance in short graphene nanochannels with width below 2 nm. The results explain the previously reported experimental result on…

Chemical Physics · Physics 2017-04-06 Yinghua Qiu , Yunfei Chen

Miniaturization of electronic devices aims at manufacturing ever smaller products, from mesoscopic to nanoscopic sizes. This trend is challenging because the increased levels of dissipated power demands a better understanding of heat…

Mesoscale and Nanoscale Physics · Physics 2019-06-04 F. Dominguez-Adame , M . Martin-Gonzalez , D. Sanchez , A. Cantarero

Molecular wires (MW) are the fundamental building blocks for molecular electronic devices. They consist of a molecular unit connected to two continuum reservoirs of electrons (usually metallic leads). We rely on Landauer theory as the basis…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 Eldon Emberly , George Kirczenow

We explore electron transport properties in molecular wires made of heterocyclic molecules (pyrrole, furan and thiophene) by using the Green's function technique. Parametric calculations are given based on the tight-binding model to…

Mesoscale and Nanoscale Physics · Physics 2009-09-13 Santanu K. Maiti , S. N. Karmakar

We investigate quantum transport in aligned carbon nanotube (CNT) fibers fabricated via solution spinning, focusing on the roles of structural dimensionality and quantum interference effects. The fibers exhibit metallic behavior at high…

The electronic properties and nanostructure of InAs nanowires are correlated by creating multiple field effect transistors (FETs) on nanowires grown to have low and high defect density segments. 4.2 K carrier mobilities are ~4X larger in…

Mesoscale and Nanoscale Physics · Physics 2010-10-05 M. D. Schroer , J. R. Petta

The depth distribution of the transport properties as well as the temperature dependence of the low field magneto-conductance for several c-axis oriented GaN nanowall network samples grown with different average wall-widths are…

Mesoscale and Nanoscale Physics · Physics 2014-11-04 H. P. Bhasker , Varun Thakur , S. M. Shivaprasad , S. Dhar

Devices formed from single molecules attached to noble-metal electrodes exhibit large conductance fluctuations, which inhibit their development as reproducible functional units. We demonstrate that single molecules with planar anchor groups…

Mesoscale and Nanoscale Physics · Physics 2014-05-15 Csaba G. Péterfalvi , Colin J. Lambert

The dependence of the transport properties on the specific location of the Fermi level in molecular electronics devices is studied by using electrodes of different materials. The zero-bias transport properties are shown to depend…

Mesoscale and Nanoscale Physics · Physics 2008-12-06 V. M. García-Suárez , C. J. Lambert

Spin-density-functional calculations of tip-suspended gold chains, with molecular oxygen, or dissociated oxygen atoms, incorporated in them, reveal structural transitions for varying lengths. The nanowires exhibit enhanced strength for both…

Mesoscale and Nanoscale Physics · Physics 2015-06-18 Chun Zhang , R. N. Barnett , Uzi Landman

Low dimensional materials provide the possibility of improved thermoelectric performance due to the additional length scale degree of freedom for engineering their electronic and thermal properties. As a result of suppressed phonon…

Mesoscale and Nanoscale Physics · Physics 2010-06-23 Neophytos Neophytou , Martin Wagner , Hans Kosina , Siegfried Selberherr

Using remarkably simple experimental techniques it is possible to gently break a metallic contact and thus form conducting nanowires. During the last stages of the pulling a neck-shaped wire connects the two electrodes, the diameter of…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 Nicolas Agrait , Alfredo Levy Yeyati , Jan M. van Ruitenbeek

Calculations of the conductance of a carbon nanotube (CNT)-molecule-CNT structure are in agreement with experimental measurements [1]. The features in the transmission correspond directly to the features of the isolated molecular orbitals.…

Other Condensed Matter · Physics 2015-05-13 Nicolas A. Bruque , M. K. Ashraf , Roger K. Lake

We achieve, at room temperature, conductance enhancements over two orders of magnitude in single molecule circuits formed with polycyclic benzoquinoidal (BQn) diradicals upon increasing molecular length by ~0.5 nm. We find that this extreme…

Mesoscale and Nanoscale Physics · Physics 2024-03-11 Brent Lawson , Efrain Vidal , Michael M. Haley , Maria Kamenetska

We report on low temperature (2-30K) electron transport and magneto-transport measurements of a chemically synthesized InAs nanowire. Both the temperature, T, and transverse magnetic field dependences of the nanowire conductance are…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 Dong Liang , Mohammed R. Sakr , Xuan P. A. Gao

Besides active, functional molecular building blocks such as diodes or switches, passive components as, e.g., molecular wires, are required to realize molecular-scale electronics. Incorporating metal centers in the molecular backbone…

We introduce a theoretical approach based on scattering theory and total energy methods that treats transport non-linearities, conformational changes and charging effects in molecular wires in a unified way. We apply this approach to…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 Eldon Emberly , George Kirczenow