Related papers: Infrared spectroscopy of endohedral water in C$_{6…
Because it is sensitive to fluctuations occurring over femtoseconds to picoseconds, gigahertz-to-terahertz dielectric relaxation spectroscopy can provide a valuable window into water's most rapid intermolecular motions. In response, we have…
Progress in the emerging field of engineered quantum systems requires the development of devices that can act as quantum memories. The realisation of such devices by doping solid state cavities with paramagnetic ions imposes a trade-off…
A prerequisite for laser cooling a molecular anion, which has not been achieved so far, is the precise knowledge of the relevant transition frequencies in the cooling scheme. To determine these frequencies we present a versatile method that…
Context: Despite the low elemental deuterium abundance in the Galaxy, enhanced molecular D/H ratios have been found in the environments of low-mass star-forming regions and, in particular, the Class 0 protostar IRAS 16293-2422. Aims: The…
Infrared (IR) absorption in the 1000-3700 cm-1 range and 1H NMR spectroscopy reveal the existence of an asymmetric protonated water trimer, H7+O3, in acetonitrile. The core H7+O3 motif persists in larger protonated water clusters in…
The intensities of all rovibrational electric quadrupole absorption lines in $^{16}$O$_2$($X^{3}\Sigma^{-}_{g}$), for which the vibrational quantum number is $v \leq 35$ and the total angular momentum quantum number is $J \leq 40$, are…
Microwave (MW) absorption in liquid 4He is investigated in the frequency range of 40-200 GHz at T = 1.4 - 2.5 K. Whispering gallery of waves was generated by a dielectric disc resonator immersed into the liquid. Resonance absorption of MWs…
We report a direct measurement of the 0-1 R(0) vibrational transition frequency in ground-state hydrogen deuteride (HD) using infrared-ultraviolet double resonance spectroscopy in a molecular beam. Ground-state molecules are vibrationally…
Erbium ions in crystals show considerable promise for the technologies that will form the backbone of future networked quantum information technology. Despite advances in leveraging erbium's fibre-compatible infrared transition for…
We report new observations of the 110-111 (6 cm) and 211-212 (2 cm) transitions of ortho-formaldehyde (o-H2CO) in absorption at z=0.68466 toward the gravitational lens system B0218+357. Radiative transfer modeling indicates that both…
We reconsider the calculation of rovibrational transition frequencies in hydrogen molecular ions. Some previously neglected contributions, such as the deuteron polarizability, are included into consideration in comparison with our previous…
Ionic liquids have attracted a lot of research attention for their applications in novel optoelectronic structures and devices as an optical means of regulating electricity. Although the electro-optic effect of ionic liquids is mentioned in…
The protonated Argon ion, $^{36}$ArH$^{+}$, has been identified recently in the Crab Nebula (Barlow et al. 2013) from Herschel spectra. Given the atmospheric opacity at the frequency of its $J$=1-0 and $J$=2-1 rotational transitions (617.5…
The insulator-to-metal transition in dense fluid hydrogen is an essential phenomenon to understand gas giant planetary interiors and the physical and chemical behavior of highly compressed condensed matter. Using fast laser spectroscopy…
We study the structural changes occurring in the isotropic phase of the C$_{12}$=EO$_6$/H$_2$O lyotropic mixture (up to 35% surfactant weight concentration) upon increasing the concentration and temperature, from small individual micelles…
Here we report a detailed study on spectroscopy, structure and dynamics of water molecules at air/water interface, investigated with Sum Frequency Generation Vibrational Spectroscopy (SFG-VS). Quantitative polarization and experimental…
We have developed x-ray diffraction measurements with high energy-resolution and accuracy to study water structure at three different temperatures (7, 25 and 66 C) under normal pressure. Using a spherically curved Ge crystal an energy…
We report a detection in the interstellar medium of an infrared transition within the electronic ground state of the deuterated hydrogen molecule, HD. Through a deep integration with the Short-Wavelength-Spectrometer on ISO, the pure…
The dynamics and infrared absorption spectrum of the protonated water dimer are reported by full quantum simulation. Strong couplings between the spectroscopically active proton-transfer motion and low-frequency, large-amplitude torsional…
The spectrometers onboard the Infrared Telescope in Space (IRTS) reveal water vapor absorption in early M-type stars, as early as M2. Previous observations detected H_2O vapor absorption only in stars later than M6, with the exception of…