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Separating the Coulomb potential into short-range and long-range components enables the use of different electron repulsion integral algorithms for each component. The short-range part can be efficiently computed using the analytical…

Chemical Physics · Physics 2023-09-27 Qiming Sun

We present an efficient algorithm for the all-electron periodic Coulomb matrix based on the Ewald summation combined with the Fourier-transformed Coulomb method. The short-range contributions involving compact densities are evaluated in…

Chemical Physics · Physics 2025-09-23 Hieu Q. Dinh , Adam Rettig , Xintian Feng , Joonho Lee

We derive distance-dependent estimators for two-center and three-center electron repulsion integrals over a short-range Coulomb potential, $\textrm{erfc}(\omega r_{12})/r_{12}$. These estimators are much tighter than one based on the…

Chemical Physics · Physics 2021-10-04 Hong-Zhou Ye , Timothy C. Berkelbach

Real-time time-dependent density functional theory (RT-TDDFT) is a powerful approach for investigating various ultrafast phenomena in materials. However, most existing RT-TDDFT studies rely on adiabatic local or semi-local approximations,…

Materials Science · Physics 2025-12-23 Yuyang Ji , Haotian Zhao , Peize Lin , Xinguo Ren , Lixin He

A robust density fitting method for calculating Coulomb matrix elements over Bloch functions based on calculation of two- and three-center matrix elements of the Ewald potential is described and implemented in a Gaussian orbital basis in…

Materials Science · Physics 2021-02-03 Charles H. Patterson

When calculating properties of periodic systems at the thermodynamic limit (TDL), the dominant source of finite size error (FSE) arises from the long-range Coulomb interaction, and can manifest as a slowly converging quadrature error when…

Computational Physics · Physics 2025-06-25 Stephen Jon Quiton , Juan D. F. Pottecher , Xin Xing , Martin Head-Gordon , Lin Lin

We present low-scaling algorithms for $GW$ and constrained random phase approximation based on a symmetry-adapted interpolative separable density fitting (ISDF) procedure that incorporates the space-group symmetries of crystalline systems.…

Materials Science · Physics 2024-01-24 Chia-Nan Yeh , Miguel A. Morales

The expensive cost of computing exact exchange in periodic systems limits the application range of density functional theory with hybrid functionals. To reduce the computational cost of exact change, we present a range-separated algorithm…

Chemical Physics · Physics 2023-07-26 Qiming Sun

We introduce a mixed density fitting scheme that uses both a Gaussian and a plane-wave fitting basis to accurately evaluate electron repulsion integrals in crystalline systems. We use this scheme to enable efficient all-electron Gaussian…

Chemical Physics · Physics 2017-11-22 Qiming Sun , Timothy C. Berkelbach , James D. McClain , Garnet Kin-Lic Chan

By using Poisson's summation formula, we calculate periodic integrals over Gaussian basis functions by partitioning the lattice summations between the real and reciprocal space, where both sums converge exponentially fast with a large…

Strongly Correlated Electrons · Physics 2021-04-06 Sandeep Sharma , Gregory Beylkin

We introduce an accurate and efficient method for a class of nonlocal potential evaluations with free boundary condition, including the 3D/2D Coulomb, 2D Poisson and 3D dipolar potentials. Our method is based on a Gaussian-sum approximation…

Computational Physics · Physics 2016-12-09 Lukas Exl , Norbert J. Mauser , Yong Zhang

We propose a nonparametric density estimator based on the Gaussian process (GP) and derive three novel closed form learning algorithms based on Fisher divergence (FD) score matching. The density estimator is formed by multiplying a base…

Machine Learning · Computer Science 2025-11-17 John Paisley , Wei Zhang , Brian Barr

The $GW$ method for calculating quasi-particle energies of solids commonly begin from a DFT Hamiltonian and Kohn-Sham orbitals in a plane wave basis. Screening of the coulomb interaction is implemented using the inverse dielectric function…

Materials Science · Physics 2026-05-20 Charles H. Patterson

A range-separated double-hybrid (RSDH) scheme which generalizes the usual range-separated hybrids and double hybrids is developed. This scheme consistently uses a two-parameter Coulomb-attenuating-method (CAM)-like decomposition of the…

Chemical Physics · Physics 2018-05-23 Cairedine Kalai , Julien Toulouse

The Gaussian function (GF) is widely used to explain the behavior or statistical distribution of many natural phenomena as well as industrial processes in different disciplines of engineering and applied science. For example, the GF can be…

Signal Processing · Electrical Eng. & Systems 2020-01-08 Ibrahim Al-Nahhal , Octavia A. Dobre , Ertugrul Basar , Cecilia Moloney , Salama Ikki

The quasi-2D electrostatic systems, characterized by periodicity in two dimensions with a free third dimension, have garnered significant interest in many fields. We apply the sum-of-Gaussians (SOG) approximation to the Laplace kernel,…

Numerical Analysis · Mathematics 2024-12-09 Xuanzhao Gao , Shidong Jiang , Jiuyang Liang , Zhenli Xu , Qi Zhou

This work examines the problem of using finite Gaussian mixtures (GM) probability density functions in recursive Bayesian peer-to-peer decentralized data fusion (DDF). It is shown that algorithms for both exact and approximate GM DDF lead…

Signal Processing · Electrical Eng. & Systems 2019-07-10 Nisar R. Ahmed

The 3D Gaussian splatting method has drawn a lot of attention, thanks to its high performance in training and high quality of the rendered image. However, it uses anisotropic Gaussian kernels to represent the scene. Although such…

Computer Vision and Pattern Recognition · Computer Science 2024-03-22 Yuanhao Gong , Lantao Yu , Guanghui Yue

A new estimator for three-center two-particle Coulomb integrals is presented. Our estimator is exact for some classes of integrals and is much more efficient than the standard Schwartz counterpart due to the proper account of distance…

Chemical Physics · Physics 2015-09-02 David S. Hollman , Henry F. Schaefer , Edward F. Valeev

In this paper, a distance between the Gaussian Mixture Models(GMMs) is obtained based on an embedding of the K-component Gaussian Mixture Model into the manifold of the symmetric positive definite matrices. Proof of embedding of K-component…

Differential Geometry · Mathematics 2025-01-14 Amit Vishwakarma , KS Subrahamanian Moosath
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