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In multiferroic BiFeO3 thin films grown on highly mismatched LaAlO3 substrates, we reveal the coexistence of two differently distorted polymorphs that leads to striking features in the temperature dependence of the structural and…

In this paper, the photocatalytic activity of multiferroics BiFeO3 (BFO) and Bi0.8La0.2FeO3 (BLFO) nanocrystals with two different morphologies which were synthesized by two different sol-gel (SG) and hydrothermal (HT) methods have been…

Materials Science · Physics 2018-07-10 Hamed Maleki

Local structural distortions in Na0.5Bi0.5TiO3-based solid solutions have been proved to play a crucial role in understanding and tuning their enhanced piezoelectric properties near the morphotropic phase boundary. In this work all local…

Materials Science · Physics 2017-10-06 Alexandra Neagu , Cheuk-Wai Tai

A surface layer ("skin") that is functionally and structurally different from the bulk was found in single crystals of BiFeO3. Impedance analysis indicates that a previously reported anomaly at T* ~ 275 \pm 5 ^/circC corresponds to a phase…

Materials Science · Physics 2015-05-20 X. Marti , P. Ferrer , J. Herrero-Albillos , J. Narvaez , V. Holy , N. Barrett , M. Alexe , G. Catalan

Multiferroic composites with the composition (1-x) BaTi0.8Sn0.2O3 - (x) La0.5Ca0.5MnO3 (x =0, 0.3, 0.5, 0.7, 0.9 and 1) were prepared by sol-gel techniques. Rietveld refinements of the composites with 0-3 and 3-0 type connectivities exhibit…

Pb(Mg1/3Nb2/3)O3-PbTiO3 solid solution (PMN(1-x)-PTx) ceramics with 0 <x<1 have been prepared by homo-epitaxial templated grain growth (HTGG) using cubic PMN-PT single crystal seeds as templates and nanoparticles for thes ceramic matrix.…

Materials Science · Physics 2007-05-23 Mai Thi Pham , Gregory March , Philippe Colomban

High-quality crystalline FeSe is successfully synthesized in 5 minutes by an electrochemical deposition technique via increasing the solution temperature. The synthesis of FeSe have been controlled by the applied voltage, synthesis time and…

Superconductivity · Physics 2017-06-28 Aichi Yamashita , Masashi Tanaka , Hiroyuki Takeya , Yoshihiko Takano

This Perspective critically assesses recent advances in ultrafast sintering and highlights open scientific questions and emerging technological opportunities. Mechanistic studies of flash sintering indicate that the flash event initiates as…

Materials Science · Physics 2026-05-14 Jian Luo

Magnetic phase transitions in multiferroic bismuth ferrite (BiFeO3) induced by magnetic field, epitaxial strain, and composition modification are considered. These transitions from a spatially modulated spin spiral state to a homogenous…

Strongly Correlated Electrons · Physics 2008-12-28 A. M. Kadomtseva , Yu. F. Popov , A. P. Pyatakov , G. P. Vorob'ev , A. K. Zvezdin , D. Viehland

We report on the growth of epitaxial bilayers of the La2/3Sr1/3MnO3 (LSMO) half-metallic ferromagnet and the BiFeO3 (BFO) multiferroic, on SrTiO3(001) by pulsed laser deposition. The growth mode of both layers is two-dimensional, which…

BiFeO$_3$ (BFO) shows both ferroelectricity and magnetic ordering at room temperature but its ferromagnetic component, which is due to spin canting, is negligible. Substitution of transition-metal atoms such as Co for Fe is known to enhance…

The present work describes a synthesis route for bulk Ta4AlC3 MAX phase ceramics with high phase purity. Pressure assisted densification was achieved by both hot pressing and spark plasma sintering of tantalum hydride, aluminium and carbon…

(1-x)Pb(Fe1/2Nb1/2)O3-PbTiO3(PFN-xPT)Ceramics with x = 0.13 sintered at 1473K show diffuse phase transition and very high dielectric constant at lower frequencies.The high value of dielectric constant at lower frequencies is shown to be due…

Materials Science · Physics 2007-05-23 Satendra Pal Singh , Akhilesh Kumar Singh , Dhananjai Pandey

Research over the years has shown that the formation of the Fe$_3$Si phase in FINEMET (Fe-Si-Nb-B-Cu) alloys leads to superior soft magnetic properties. In this work, we use a CALPHAD approach to derive Fe-Si phase diagrams to identify the…

Materials Science · Physics 2018-02-20 Rajesh Jha , David R. Diercks , Aaron P. Stebner , Cristian V. Ciobanu

The X-ray diffraction, Raman and infrared spectroscopies and magnetic measurements were used to explore the correlated changes of the structure, lattice dynamics and magnetic properties of the LuFeO3 nanoparticles, which appear in…

We report a study on the thermodynamic stability and structure analysis of the epitaxial BiFeO3 (BFO) thin films grown on YAlO3 (YAO) substrate. First we observe a phase transition of MC-MA-T occurs in thin sample (<60 nm) with an utter…

Materials Science · Physics 2015-06-04 Heng-Jui Liu , Hsiang-Jung Chen , Wen-I Liang , Chen-Wei Liang , Hsin-Yi Lee , Su-Jien Lin , Ying-Hao Chu

Lead-free Ba0.85Ca0.15Zr0.10Ti0.90O3 (BCZT) ceramics have demonstrated excellent dielectric, ferroelectric and piezoelectric properties in comparison to lead-based materials. The synthesis of pure and crystalline BCZT nanopowders at low…

In this work we demonstrate a NASICON film sintered in situ onto a fused silica substrate. This production method drastically reduces the manufacturing time by combining the use of a spray-coated sol-gel solution and near-infrared (NIR)…

Single phase (001)-oriented BiFeO3 (BFO) thin films grown by pulsed laser deposition can only be obtained in a narrow window of deposition pressure and temperature and have a low magnetic moment. Out of the stability window Fe- or Bi-rich…

Materials Science · Physics 2007-05-23 Helene Bea , Manuel Bibes , Eric Jacquet , Karsten Rode , Peter Bencok , Agnes Barthelemy

The phase diagram of lead-free piezoelectric (1-x)K0.5Na0.5NbO3-xBi0.5Na0.5TiO3 system has been studied by high-resolution synchrotron powder diffraction, neutron powder diffraction and selected area electron diffraction (SAED). The two…

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