Related papers: Shift of CO2-I absorption bands in diamond: a pres…
CO2 ices are known to exist in different astrophysical environments. In spite of this, its physical properties (structure, density, refractive index) have not been as widely studied as those of water ice. It would be of great value to study…
Discovery of superconductivity in the impurity band formed by heavy doping of boron into diamond (C:B) as well as doping of boron into silicon (Si:B) has provided a rout for the possibility of new families of superconducting materials.…
In dense clouds of the interstellar medium, dust grains are covered by ice mantles, dominated by H$_2$O. CO and CO$_2$ are common ice components observed in infrared spectra, while infrared inactive N$_2$ is expected to be present in the…
We investigate the mid-infrared (IR) emission in the Orion Bar photodissociation region, using archival photometric and spectroscopic observations from UKIRT, Spitzer, ISO, and SOFIA telescopes. Specifically, we consider flux densities of…
The James Webb Space Telescope now enables the spectral study of ices with unprecedented sensitivity and angular resolution. Water ice plays a crucial role in the growth of grains and in planetary formation but its spatial distribution in…
Absorption, excitation and emission spectra of cadmium fluoride crystals doped with rare-earth ions were investigated. In contrast to alkaline-earth fluorides the absorption spectra due to 4f - 5d transitions of Ce$^{3+}$, Pr$^{3+}$ and…
The ST2 center is an optically addressable point defect in diamond that facilitates spin initialization and readout. However, while this study presents the discovery of ST2 centers first observed in a natural diamond and provides a reliable…
We study the variability of major atmospheric absorption features in the disk-integrated spectra of the Earth with future application to Earth-analogs in mind, concentrating on the diurnal timescale. We first analyze observations of the…
Optical conductivity spectra of cubic pyrochlore $Y_{2-x} Bi_x Ru_2 O_7$ (0.0$\leq ${\it x}$\leq $2.0) compounds are investigated. As a metal-insulator transition (MIT) occurs around {\it x}$=$0.8, large spectral changes are observed. With…
Weakly-bound CO2-Rg2 trimers are studied by high resolution (0.002 cm-1) infrared spectroscopy in the region of the CO2 nu3 fundamental band (~2350 cm-1), using a tunable OPO to probe a pulsed supersonic slit jet expansion with an effective…
The observation of electronic phase separation textures in vanadium dioxide (VO2), a prototypical electron-correlated oxide, has recently added new perspectives on the long standing debate about its metal-insulator transition and its…
Understanding the profile of a qubit's wavefunction is key to its quantum applications. Unlike conducting systems, where a scanning tunneling microscope can be used to probe the electron distribution, there is no direct method for…
Diamond is studied by path integral molecular dynamics simulations of the atomic nuclei in combination with a tight-binding Hamiltonian to describe its electronic structure and total energy. This approach allows us to quantify the influence…
Potential vibrational modes associated with diffuse interstellar bands (DIBs) could be discerned by examining energy differences between correlated DIBs. Consequently, $\approx 10^3$ higher correlated DIB pairs ($r-\sigma_r \ge 0.8$, $\ge…
We present measurements of the 3.4-micron hydrocarbon dust absorption feature, and four visual diffuse interstellar bands, for twelve highly reddened (9.0<A(V)<15.8), early-type stars identified from the Stephenson (1992) catalogue,…
Gem-dicarbonyls of transition metals supported on metal (oxide) surfaces are common intermediates in heterogeneous catalysis. While infrared (IR) spectroscopy is a standard tool for detecting these species on applied catalysts, the…
X-ray diffraction experiments under pressure in a diamond anvil cell have been performed to gauge any response of the crystalline lattice of URu2Si2 to the "hidden order" or antiferromagnetic transitions, the latter of which is accessible…
We present a new approach to constrain the spectral energy distribution of the intergalactic UV background observationally by studying metal absorption systems. We study single-component metal line systems exhibiting various well-measured…
The spectroscopic characteristics of systems with adsorbed d impurities on noble metal surfaces should depend on the number and geometric arrangement of the adsorbed atoms and also on their d band filling. Recent experiments using scanning…
The infrared spectrum of the weakly-bound C2H4-CO2 complex is investigated in the region of the nu3 fundamental band of CO2 (~2350 cm-1), using a tunable OPO laser source to probe a pulsed supersonic slit jet expansion. The spacing of the…