Related papers: Shift of CO2-I absorption bands in diamond: a pres…
Diamond single crystals showing Infra-red features of pressurized CO2-I phase were studied using Transmission Electron Microscopy (TEM) and tomography. Numerous O-containing precipitates with sizes up to 45 nm are observed. The absolute…
The surfaces of icy moons are primarily composed of water ice that can be mixed with other compounds, such as carbon dioxide. The carbon dioxide (CO$_2)$ stretching fundamental band observed on Europa and Ganymede appears to be a…
We report first-principles calculations of the frequency dependent linear and second-order optical properties of the two probable extended-solid phases of CO$_2$--V, i.e. $I\bar42d$ and $P2_12_12_1$. Compared to the parent $Cmca$ phase the…
Carbon dioxide is abundant in ice mantles of dust grains; some is found in the pure crystalline form as inferred from the double peak splitting of the bending profile at about 650 cm$^{-1}$. To study how CO$_2$ segregates into the pure form…
JWST NIRSpec IFU (2.9-5.3 mu) and MIRI MRS (4.9-28.5 mu) observations were performed on both the leading and trailing hemispheres of Ganymede with a spectral resolution of ~2700. Reflectance spectra show signatures of water ice, CO2 and…
The abundances of ices in planetary environments have historically been obtained through measurements of near-infrared absorption features (lambda = 1.0-2.5 microns), and near-IR transmission measurements of materials present in the…
Infrared spectra of the CO2-N2 dimer are observed in the carbon dioxide nu3 asymmetric stretch region (~2350 cm-1) using a tunable infrared optical parametric oscillator to probe a pulsed slit jet supersonic expansion. Previous results for…
H2O is the most abundant component of astrophysical ices. In most lines of sight it is not possible to fit both the H2O 3 um stretching, the 6 um bending and the 13 um libration band intensities with a single pure H2O spectrum. Recent…
Analyses of infrared signatures of CO$_2$ in water dominated ices in the ISM can give information on the physical state of CO$_2$ in icy grains and on the thermal history of the ices themselves. In many sources, CO$_2$ was found in the…
None of the well established Nitrogen related IR absorption bands, common in synthetic and terrestrial diamonds, have been identified in the pre-solar diamond spectra. In the carbonado diamond spectra only the single nitrogen impurity (C…
A laboratory study on the band profiles and band strengths of H2O in CO ice, and vice versa, is presented and interpreted in terms of two models. The results show that a mutual interaction takes place between the two species in the solid,…
In order to facilitate IR absorption measurements of mass-selected ions isolated in cryogenic matrices, we have upgraded an ion beam deposition apparatus encompassing a Bruker IFS66v/S FTIR spectrometer. A synthetic diamond beam splitter…
We present an experimental study of the absorption, between 40 and 640 cm$^{-1}$, by CO$_2$, CH$_4$ and H$_2$ gases as well as by H$_2$+CO$_2$ and CH$_4$+CO$_2$ mixtures at room temperature. A Fourier transform spectrometer associated to a…
Any distortion of a chemical structure causes new features to appear in the absorption spectrum of the structure, especially in the visible and near UV (see Paper I). Chemical modeling, using molecular orbital theory, showed that the…
The weak infrared spectrum of CO2-Ar corresponding to the (0111) <-- (0110) hot band of CO2 is detected in the region of the carbon dioxide nu3 fundamental vibration (~2340 cm-1), using a tunable OPO laser source to probe a pulsed…
The spectra of pure, mixed and layered CO and CO2 ices have been studied systematically under laboratory conditions using infrared spectroscopy. This work provides improved resolution spectra (0.5 cm-1) of the CO2 bending and asymmetric…
Titanium dioxide (TiO2) is a wide band gap semiconducting material which is promising for photocatalysis. Here we present first-principles calculations to study the pressure dependence of structural and electronic properties of two TiO2…
IRTF/SpeX observations of Pluto's near-infrared reflectance spectrum during 2013 show vibrational absorption features of CO and N$_2$ ices at 1.58 and 2.15 {\mu}m, respectively, that are weaker than had been observed during the preceding…
The intensive development of technology for fabrication semiconducting CVD diamond layers poses an important task of developing a precise and non-destructive method for estimation the boron content in thin epitaxial layers. For bulk and…
The first complete infrared FTIR absorption spectra for carbonado-diamond confirm the interstellar origin for the most enigmatic diamonds known as carbonado. All previous attempts failed to measure the absorption of carbonado-diamond in the…