Related papers: Extraterrestrial Photochemistry: Principles and Ap…
Advancements in our understanding of exoplanetary atmospheres, from massive gas giants down to rocky worlds, depend on the constructive challenges between observations and models. We are now on a clear trajectory for improvements in…
Electron capture by {\it isolated} atoms and ions proceeds by photorecombination. In this process a species captures a free electron by emitting a photon which carries away the excess energy. It is shown here that in the presence of an {\it…
The first computational model of solid-phase chemistry in cometary nuclear ices is presented. An astrochemical kinetics model, MAGICKAL, is adapted to trace the chemical evolution in multiple layers of cometary ice, over a representative…
The intergalactic medium is expected to be at its coldest point before the formation of the first stars in the universe. Motivated by recent results from the EDGES experiment, we revisit the standard calculation of the kinetic temperature…
Any search for present or past life beyond Earth should consider the initial processes and related environmental controls that might have led to its start. As on Earth, such an understanding lies well beyond how simple organic molecules…
Photosynthesis is central to Earth's biosphere and a prime candidate for sustaining complex life on habitable exoplanets, yet a thermodynamically consistent treatment of the work potential of stellar radiation at planetary surfaces is still…
Stellar atmospheres separate the hot and dense stellar interiors from the emptiness of space. Radiation escapes from the outermost layers of a star, carrying direct physical information. Underneath the atmosphere, the very high opacity…
The first opportunity to detect indications for life outside the Solar System may be provided already within the next decade with upcoming missions such as the James Webb Space Telescope (JWST), the European Extremely Large Telescope…
Detailed characterization of an extrasolar planet's atmosphere provides the best hope for distinguishing the makeup of its outer layers, and the only hope for understanding the interplay between initial composition, chemistry, dynamics &…
The chemistry of the early Universe is a fascinating field of study. Even in the absence of any elements heavier than lithium, a surprising degree of chemical complexity proves to be possible, giving the topic considerable interest in its…
The origin of complex organic molecules such as amino acids and their precursors found in meteorites and comets is unknown. Previous studies have accounted for the complex organic inventory of the Solar System by aqueous chemistry on warm…
Methanol and formaldehyde are two simple organic molecules that are ubiquitously detected in the interstellar medium. An origin in the solid phase and a subsequent nonthermal desorption into the gas phase is often invoked to explain their…
Cosmic rays may be linked to the formation of volatiles necessary for prebiotic chemistry. We explore the effect of cosmic rays in a hydrogen-dominated atmosphere, as a proof-of-concept that ion-neutral chemistry may be important for…
Ionization is a major driver of both physical and chemical evolution in protostellar systems. Recent observations reveal substantial chemical processing in protoplanetary disks by the time the surrounding envelope has cleared. Thus,…
Ionization drives important chemical and dynamical processes within protoplanetary disks, including the formation of organics and water in the cold midplane and the transportation of material via accretion and magneto-hydrodynamic (MHD)…
We present a study of the photochemistry of abiotic habitable planets with anoxic CO$_2$-N$_2$ atmospheres. Such worlds are representative of early Earth, Mars and Venus, and analogous exoplanets. H$_2$O photodissociation controls the…
A new, more comprehensive model of gas-grain chemistry in hot molecular cores is presented, in which nondiffusive reaction processes on dust-grain surfaces and in ice mantles are implemented alongside traditional diffusive surface/bulk-ice…
Context. In dense clouds, hydrogenation reactions on icy dust grains are key in the formation of molecules, like formaldehyde, methanol, and complex organic molecules (COMs). These species form through the sequential hydrogenation of CO…
Electrochemistry exploits local current heterogeneities at various scales ranging from the micrometer to the nanometer. The last decade has witnessed unprecedented progress in the development of a wide range of electroanalytical techniques…
Planets form and obtain their compositions in disks of gas and dust around young stars. The chemical compositions of these planet-forming disks regulate all aspects of planetary compositions from bulk elemental inventories to access to…