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For the investigation of chemical reaction networks, the identification of all relevant intermediates and elementary reactions is mandatory. Many algorithmic approaches exist that perform explorations efficiently and automatedly. These…

Chemical Physics · Physics 2019-05-24 Gregor N. Simm , Alain C. Vaucher , Markus Reiher

The ability to reason beyond established knowledge allows Organic Chemists to solve synthetic problems and to invent novel transformations. Here, we propose a model which mimics chemical reasoning and formalises reaction prediction as…

Artificial Intelligence · Computer Science 2017-12-27 Marwin H. S. Segler , Mark P. Waller

The Bond Graph approach and the Chemical Reaction Network approach to modelling biomolecular systems developed independently. This paper brings together the two approaches by providing a bond graph interpretation of the chemical reaction…

Molecular Networks · Quantitative Biology 2019-07-04 Peter J. Gawthrop , Edmund J. Crampin

A compositional Petri net-based semantics is given to a simple language allowing pointer manipulation and parallelism. The model is then applied to give a notion of validity to the judgements made by concurrent separation logic that…

Logic in Computer Science · Computer Science 2015-07-01 Jonathan Hayman , Glynn Winskel

The reachability semantics for Petri nets can be studied using open Petri nets. For us an "open" Petri net is one with certain places designated as inputs and outputs via a cospan of sets. We can compose open Petri nets by gluing the…

Category Theory · Mathematics 2022-07-26 John C. Baez , Jade Master

Motor enzymes catalyze chemical reactions, like the hydrolysis of ATP, and in the process they also perform work. Recent studies indicate that motor enzymes perform work with specific intermediate steps in their catalyzed reactions,…

Biological Physics · Physics 2007-05-23 Josh E. Baker

Recent work by the authors equips Petri occurrence nets (PN) with probability distributions which fully replace nondeterminism. To avoid the so-called confusion problem, the construction imposes additional causal dependencies which restrict…

Logic in Computer Science · Computer Science 2018-07-18 Roberto Bruni , Hernán Melgratti , Ugo Montanari

The dynamics of a chemical reaction network (CRN) is often modelled under the assumption of mass action kinetics by a system of ordinary differential equations (ODEs) with polynomial right-hand sides that describe the time evolution of…

Dynamical Systems · Mathematics 2023-01-05 Radek Erban , Hye-Won Kang

Continuous-time Markov chains are frequently used as stochastic models for chemical reaction networks, especially in the growing field of systems biology. A fundamental problem for these Stochastic Chemical Reaction Networks (SCRNs) is to…

Probability · Mathematics 2023-04-12 Felipe A. Campos , Simone Bruno , Yi Fu , Domitilla Del Vecchio , Ruth J. Williams

Finding representative reaction pathways is necessary for understanding mechanisms of molecular processes, but is considered to be extremely challenging. We propose a new method to construct reaction paths based on mean first-passage times.…

Chemical Physics · Physics 2015-06-26 Sanghyun Park , Klaus Schulten

We propose a framework for reasoning about unbounded dynamic networks of infinite-state processes. We propose Constrained Petri Nets (CPN) as generic models for these networks. They can be seen as Petri nets where tokens (representing…

Logic in Computer Science · Computer Science 2015-07-01 Ahmed Bouajjani , Cezara Dragoi , Constantin Enea , Yan Jurski , Mihaela Sighireanu

A cell has the ability to convert an environmental change into the expression of genetic information through a chain of intracellular signal transduction reactions. Here, we aimed to develop a method for quantifying this signal…

Molecular Networks · Quantitative Biology 2017-03-09 Tatsuaki Tsuruyama

At the microscopic scale, open chemical reaction networks are described by stochastic reactions that follow mass-action kinetics and are coupled to chemostats. We show that closed chemical reaction networks -- with specific stoichiometries…

Molecular Networks · Quantitative Biology 2025-06-30 Benedikt Remlein , Massimiliano Esposito , Francesco Avanzini

Chemical reaction networks describe interactions between biochemical species. Once an underlying reaction network is given for a biochemical system, the system dynamics can be modelled with various mathematical frameworks such as continuous…

Probability · Mathematics 2023-06-22 German Enciso , Radek Erban , Jinsu Kim

Supply chains involve geographically distributed manufacturing and assembly sites that must be coordinated under strict timing and resource constraints. While many existing approaches rely on Colored Petri Nets to model material flows, this…

Systems and Control · Electrical Eng. & Systems 2026-04-07 Eric Lubat , Pierre-Emmanuel Hladik , Yoann Mateu , Rémi Sauvère

Reaction networks are mainly used to model the time-evolution of molecules of interacting chemical species. Stochastic models are typically used when the counts of the molecules are low, whereas deterministic models are used when the counts…

Probability · Mathematics 2019-10-04 David Anderson , Daniele Cappelletti , Jinsu Kim , Tung Nguyen

Similarly to gear systems in vehicles, most chemical reaction networks (CRNs) involved in energy transduction have at their disposal multiple transduction pathways, each characterized by distinct efficiencies. We conceptualize these…

Molecular Networks · Quantitative Biology 2025-07-24 Massimo Bilancioni , Massimiliano Esposito

For two molecules to react they first have to meet. Yet, reaction times are rarely on par with the first-passage times that govern such molecular encounters. A prime reason for this discrepancy is stochastic transitions between reactive and…

Statistical Mechanics · Physics 2021-07-21 Yuval Scher , Shlomi Reuveni

The analysis of the structure of chemical reaction networks is crucial for a better understanding of chemical processes. Such networks are well described as hypergraphs. However, due to the available methods, analyses regarding network…

Computational Complexity · Computer Science 2013-09-30 Rolf Fagerberg , Christoph Flamm , Daniel Merkle , Philipp Peters , Peter F. Stadler

We discuss a method to describe the qualitative dynamics of chemical reaction networks in terms of symbolic dynamics. The method, that can be applied to mass-action reaction networks with separated timescales, uses solutions of the partial…

Molecular Networks · Quantitative Biology 2022-05-17 Aurélien Desoeuvres , Peter Szmolyan , Ovidiu Radulescu
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