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Gas-phase hydroxylamine (NH$_2$OH) has recently been detected within dense clouds in the interstellar medium. However, it is also likely present within interstellar ices, as well as on the icy surfaces of outer Solar System bodies, where it…
Hydroxylamine, NH2OH, is one of the already detected interstellar molecules with the highest prebiotic potential. Yet, the abundance of this molecule found by astronomical observations is rather low for a relatively simple molecule, $\sim$…
Our interpretation of terrestrial exoplanet atmospheric spectra will always be limited by the accuracy of the data we use as input in our forward and retrieval models. Ultraviolet molecular absorption cross sections are one category of…
Formamide (NH$_2$CHO), a potential prebiotic precursor, has been proposed to play an important role in the context of origin of life on our planet. It has been observed in different environments in space including the protostellar regions…
The molecule studied in this work, 2-hydroxyprop-2-enal, is among the candidates to be searched for in the interstellar medium (ISM), as it is a dehydration product of C3 sugars and contains structural motifs typical for some interstellar…
Formamide (NH2CHO) has been proposed as a pre-biotic precursor with a key role in the emergence of life on Earth. While this molecule has been observed in space, most of its detections correspond to high-mass star-forming regions. Motivated…
\ Nitrous oxide (N$_2$O) ice is likely to exist in trans-Neptunian objects such as Pluto and Triton, potentially formed through ultraviolet (UV) radiation from the Sun or cosmic ray irradiation of N$_2$ and CO ices. However, the…
Far-UV photons (E<13.6 eV) from hot massive stars regulate, or at least influence, the heating, ionization, and chemistry of most of the neutral interstellar medium. Investigating the interaction between FUV radiation and interstellar…
Ultraviolet photodesorption of molecules from icy interstellar grains can explain observations of cold gas in regions where thermal desorption is negligible. This non-thermal desorption mechanism should be especially important where UV…
A new two-dimensional axi-symmetric ultraviolet radiative transfer code is presented, which is used to calculate photodissociation and ionization rates for use in chemistry models of flaring circumstellar disks. Scattering and absorption of…
The interstellar medium (ISM) seems to have a significant surplus of oxygen which was dubbed as the "O crisis": independent of the adopted interstellar reference abundance, the total number of O atoms depleted from the gas phase far exceeds…
To understand the environment and extended structure of the host galactic gas whose molecular absorption line chemistry, we previously observed along the microscopic line of sight to the blazar/radiocontinuum source NRAO150 (aka B0355+508),…
We present the first detection in space of thionylimide (HNSO) toward the Galactic Center molecular cloud G+0.693-0.027, thanks to the superb sensitivity of an ultradeep molecular line survey carried out with the Yebes 40$\,$m and IRAM…
We present a study of the photochemistry of abiotic habitable planets with anoxic CO$_2$-N$_2$ atmospheres. Such worlds are representative of early Earth, Mars and Venus, and analogous exoplanets. H$_2$O photodissociation controls the…
When a slightly defective rutile TiO$_2$(110) surface is exposed to O$_2$ at elevated temperatures, the molecule dissociates at defects, filling O vacancies (\ov) and creating O adatoms (\oad) on {\tifc} rows. The adsorption of molecular…
Context. The detection of NH2CH2CH2OH (ethanolamine) in molecular cloud G+0.693-0.027 adds an additional player to the prebiotic molecules discovered so far in the interstellar medium (ISM). As this molecule might be formed through…
We present a new approach to constrain the spectral energy distribution of the intergalactic UV background observationally by studying metal absorption systems. We study single-component metal line systems exhibiting various well-measured…
Estimating molecular abundances ratios from the direct measurement of the emission of the molecules towards a variety of interstellar environments is indeed very useful to advance in our understanding of the chemical evolution of the…
We have done theoretical calculations and simulations for infrared spectroscopy at the MMT 6.5 m with laser guide star AO, which provides almost full sky coverage. The results show we can expect 40-60% of the photons from a unresolved…
The peptide-like molecules, cyanoformamide (NCCONH2), is the cyano (CN) derivative of formamide (NH2CHO). It is known to play a role in the synthesis of nucleic acid precursors under prebiotic conditions. In this paper, we present a…