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GeSe and SnSe monochalcogenide monolayers and bilayers undergo a two-dimensional phase transition from a rectangular unit cell to a square unit cell at a temperature $T_c$ well below the melting point. Its consequences on material…

The newly emerged two-dimensional (2D) materials family of MSi2N4, where M is a transition metal atom (i.e., Mo, W, etc.), has the potential to be named after the conventional and very popular transition metal di-chalcogenides (TMDC), which…

Materials Science · Physics 2024-05-16 Chayan Das , Abhishek , Dibyajyoti Saikia , Appala Naidu Gandi , Satyajit Sahu

In this work, we have presented a first principle simulation study on the electronic properties of MoS2/MX2/MoS2 (M=Mo or W; X=S or Se) trilayer heterostrcuture. We have investigated the effect of stacking configuration, bi-axial…

Computational Physics · Physics 2018-02-27 Kanak Datta , Quazi D. M. Khosru

Monolayers of transition-metal dichalcogenides (TMDs) hold great promise as future nanoelectronic and optoelectronic devices. An essential feature for achieving high device performance is the use of suitable supporting substrates, which can…

Materials Science · Physics 2021-03-10 Nourdine Zibouche , Martin Schlipf , Feliciano Giustino

The interactions between different layers in van der Waals heterostructures have a significant impact on the electronic and optical characteristics. By utilizing the intrinsic dipole moment of Janus transition metal dichalcogenides (TMDs),…

Materials Science · Physics 2024-01-18 Ö. C. Yelgel

Binary transition metal nitride with a graphene-like structure and strong magnetic properties is rare. Based on the first-principles calculations, we design two kinds of $M$N$_4$ ($M$ =transition metal) monolayers, which are transition…

Materials Science · Physics 2024-06-19 Shuo Zhang , Panjun Feng , Dapeng Liu , Hongfen Wu , Miao Gao , Tongshuai Xu , Xun-Wang Yan , Z. Y. Xie

Organohalide perovskite with a variety of surface structures and morphologies have shown promising potential owing to the choice of the type of heterostructure dependent stability. We systematically investigate and discuss the impact of…

Applied Physics · Physics 2022-07-18 Rahul Singh , Prashant Singh , Ganesh Balasubramanian

I present first principles calculations of the phonon dispersions of TiSe$_2$ in the $P\overline{3}c1$ phase, which is the currently accepted low-temperature structure of this material. They show weak instabilities in the acoustic branches…

Materials Science · Physics 2022-11-15 Alaska Subedi

Manipulating crystal structure and the corresponding electronic properties in quantum materials provides opportunities for the exploration of exotic physics and practical applications. Here, by ultrafast electron diffraction, structure…

The ground-state structure of monolayers and nanoplatelets of SnS with a thickness from two to five monolayers is calculated from first principles. It is shown that nanoobjects with only odd number of monolayers are ferroelectric. The…

Materials Science · Physics 2018-10-30 Alexander I. Lebedev

We present a detailed first principles density functional theory study of intrinsic and extrinsic point defects in monolayer (ML) WSe2. Among the intrinsic point defects, Se vacancies (Sevac) have the lowest formation energy (disregarding…

Materials Science · Physics 2019-01-17 Yu Jie Zheng , Su Ying Quek

SnSe monolayers experience a temperature induced two-dimensional Pnm2$_1 \to$ P4/nmm structural transformation precipitated by the softening of vibrational modes. The standard theoretical treatment of thermoelectricity---which relies on a…

Materials Science · Physics 2021-01-22 John W. Villanova , Salvador Barraza-Lopez

Neutron diffraction with static and pulsed magnetic fields is used to directly probe the magnetic structures in LiNiPO$_4$ up to 25T and 42T, respectively. By combining these results with magnetometry and electric polarization measurements…

Recently-synthesised MoSi$_2$N$_4$ is the first septuple layer two-dimensional material, which doesn't naturally occurs as a layered crystal, and has been obtained with CVD growth. It can be considered as MoN$_2$ crystal (with a crystal…

Mesoscale and Nanoscale Physics · Physics 2025-01-10 Tatiana Latychevskaia , Denis A. Bandurin , Kostya S. Novoselov

Mechanical stability of the ZnIn2X4 monolayers. The ZnIn2S4 and ZnIn2Se4 are semiconductors with direct band gaps of 3.94 and 2.77 eV, respectively whereas the ZnIn2Te4 shows an indirect band gap of 1.84 eV at the G0W0 level. The optical…

Intrinsic electron- and hole-phonon interactions are investigated in monolayer transition metal dichalcogenides MX$_2$ (M=Mo,W; X=S,Se) based on a density functional theory formalism. Due to their structural similarities, all four materials…

Mesoscale and Nanoscale Physics · Physics 2015-06-22 Zhenghe Jin , Xiaodong Li , Jeffrey Thomas Mullen , Ki Wook Kim

Atomic monolayers represent a novel class of materials to study localized and free excitons in two dimensions and to engineer optoelectronic devices based on their significant optical response. Here, we investigate the role of the substrate…

Mesoscale and Nanoscale Physics · Physics 2017-07-21 Oliver Iff , Yu-Ming He , Nils Lundt , Sebastian Stoll , Vasilij Baumann , Sven Höfling , Christian Schneider

In the past decade, it has been demonstrated that monolayers of metal dichalcogenides are well-suited for thermoelectric applications. ZrX2N4 (X = Si, Ge) is a reasonable choice for thermoelectric applications when considering a favorable…

Materials Science · Physics 2024-08-09 Chayan Das , Dibyajyoti Saikia , Satyajit Sahu

Molybdenum disulfide (MoS$_2$), a layered van der Waals material, has attracted considerable attention as a promising alternative to graphene for applications in field-effect transistors and nanophotonic devices because of its sizable band…

Materials Science · Physics 2026-04-16 Shunsuke Hirai , Ibuki Terada , Michi-To Suzuki

We have decoupled the intrinsic optical and electrostatic effects arising in monolayer and few-layer molybdenum disulphide from those influenced by the flake-substrate interaction.

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