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MA2Z4 monolayers form a new class of hexagonal non-centrosymmetric materials hosting extraordinary spin-valley physics. While only two compounds (MoSi2N4 and WSi2N4) were recently synthesized, theory predicts interesting (opto)electronic…

Twelve two-dimensional group-IV monochalcogenide monolayers (SiS, SiSe, SiTe, GeS, GeSe, GeTe, SnS, SnSe, SnTe, PbS, PbSe, and PbTe) with a buckled honeycomb atomistic structure--belonging to symmetry group P3m1--and an out-of-plane…

Materials Science · Physics 2021-02-24 Shiva P. Poudel , Salvador Barraza-Lopez

The realization of multifunctional two-dimensional (2D) materials is fundamentally intriguing, such as combination of piezoelectricity with topological insulating phase or ferromagnetism. In this work, a Janus monolayer…

Materials Science · Physics 2021-03-08 San-Dong Guo , Yu-Tong Zhu , Wen-Qi Mu , Xing-Qiu Chen

We use first principles calculations to investigate the lattice properties of group-IV monochalcogenides. These include static dielectric permittivity, elastic and piezoelectric tensors. For the monolayer, it is found that the static…

Mesoscale and Nanoscale Physics · Physics 2016-01-20 Lídia C. Gomes , A. Carvalho , A. H. Castro Neto

Two-dimensional (2D) magnetic oxides are increasingly studied for their multifunctional potential in fields like spintronics, optoelectronics, and energy conversion. In this research, we conduct a detailed first-principles study of pure…

Materials Science · Physics 2025-12-12 Sikander Azam , Qaiser Rafiq , Rajwali Khan , Hamdy Khamees Thabet

A two-dimensional (2D) material system with both piezoelectricity and ferromagnetic (FM) order, referred to as a 2D piezoelectric ferromagnetism (PFM), may open up unprecedented opportunities for intriguing physics. Inspired by…

Materials Science · Physics 2021-06-16 San-Dong Guo , Xiao-Shu Guo , Xiu-Xia Cai , Wen-Qi Mu , Wen-Cai Ren

Two-dimensional materials that exhibit spontaneous electric polarization are of notable interest for functional materials. However, despite many two-dimensional polar materials are predicted in theory, the number of experimentally confirmed…

Materials Science · Physics 2020-11-04 Weiwei Gao , James R Chelikowsky

Sb and Bi monolayers, as single-elemental ferroelectric materials with similar atomic structure, hold intrinsic piezoelectricity theoretically, which makes them highly promising for applications in functional nano-devices such as sensors…

Materials Science · Physics 2023-09-22 Yunfei Hong , Junkai Deng , Qi Kong , Xiangdong Ding , Jun Sun , Jefferson Zhe Liu

The combination of piezoelectricity with other unique properties (like topological insulating phase and intrinsic ferromagnetism) in two-dimensional (2D) materials is much worthy of intensive study. In this work, the piezoelectric…

Materials Science · Physics 2021-01-29 San-Dong Guo , Wen-Qi Mu , Yu-Tong Zhu , Shao-Qing Wang , Guang-Zhao Wang

We used first-principles calculations to investigate the laterally stitched monolayered MoSi2N4/XSi2N4 (X=W, Ti) 2D heterostructures. The structural stability of such heterostructures is confirmed by the phonon spectra exhibiting no…

Manipulation of spin-polarized electronic states of two-dimensional (2D) materials under ambient conditions is necessary for developing new quantum devices with small physical dimensions. Here, we explore spin-dependent electronic…

Mesoscale and Nanoscale Physics · Physics 2021-11-24 Rajibul Islam , Barun Ghosh , Carmine Autieri , Sugata Chowdhury , Arun Bansil , Amit Agarwal , Bahadur Singh

Recently, two-dimensional monolayer MoSi2N4 with hexagonal structure was successfully synthesized in experiment (Hong et al 2020 Science 369, 670). The fabricated monolayer MoSi2N4 is predicted to have excellent mechanical properties.…

Mesoscale and Nanoscale Physics · Physics 2021-04-14 Qingfang Li , Wanxin Zhou , Xiangang Wan , Jian Zhou

Two-dimensional (2D) MoSi$_2$N$_4$ monolayer is an emerging class of air-stable 2D semiconductor possessing exceptional electrical and mechanical properties. Despite intensive recent research efforts devoted to uncover the material…

Materials Science · Physics 2021-02-03 Liemao Cao , Guanghui Zhou , Qianqian Wang , L. K. Ang , Yee Sin Ang

In this work, the electrical and spin properties of monolayer MoSi2X4 (X= N, P, As, and Sb) under vertical strain are investigated. The band structures state that MoSi2N4 is an indirect semiconductor, whereas other compounds are direct…

Materials Science · Physics 2021-09-22 Shoeib Babaee Touski , Nayereh Ghobadi

Motivated by the recently synthesized two-dimensional semiconducting MoSi$_2$N$_4$, we systematically investigate the quasiparticle band alignment and exciton in monolayer MA$_2$Z$_4$ (M = Mo, W, Ti; A= Si, Ge; Z = N, P, As) using ab initio…

Materials Science · Physics 2022-07-18 Hongxia Zhong , Guangyong Zhang , Cheng Lu , Shiyuan Gao

With exceptional electrical and mechanical properties and at the same time air-stability, layered MoSi2N4 has recently draw great attention. However, band structure engineering via strain and electric field, which is vital for practical…

Materials Science · Physics 2021-03-31 Qingyun Wu , Liemao Cao , Yee Sin Ang , Lay Kee Ang

Group IV and V monolayers are the promising state-of-the-art 2D materials owing to their high carrier mobility, tunable bandgaps, and optical linear dichroism along with outstanding electronic and thermoelectric properties. Furthermore,…

Computational Physics · Physics 2021-07-07 X. Q. Shu , J. H. Lin , H. Zhang

Recent discovery of ultrathick $\mathrm{MoSi_2N_4(MoN)_n}$ monolayers open up an exciting platform to engineer 2D material properties via intercalation architecture. Here we computationally investigate a series of ultrathick…

Materials Science · Physics 2023-11-16 Che Chen Tho , Xukun Feng , Zhuoling Jiang , Liemao Cao , Chit Siong Lau , San-Dong Guo , Yee Sin Ang

We demonstrate that an applied electric field causes piezoelectric distortion across single molecular monolayers of oligopeptides. We deposited self-assembled monolayers ~1.5 nm high onto smooth gold surfaces. These monolayers exhibit…

Applied Physics · Physics 2017-10-13 Xinfeng Quan , Jeffry D. Madura , Geoffrey R. Hutchison

Reduced dielectric screening in two-dimensional materials enables bound excitons, which modifies their optical absorption and optoelectronic response even at room temperature. Here, we demonstrate the existence of excitons in the bandgap of…

Mesoscale and Nanoscale Physics · Physics 2022-07-12 Pushpendra Yadav , Bramhachari Khamari , Bahadur Singh , K. V. Adarsh , Amit Agarwal