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Quantifying the composition of the material in protoplanetary disks is paramount to determining the potential for exoplanetary systems to produce and support habitable environments. A key complex organic molecule (COM) to detect is methanol…

We present the results of 0.1-pc-scale observations in 250 GHz and 350GHz towards a newly-discovered hot molecular core in a nearby low-metallicity galaxy, the Large Magellanic Cloud (LMC), with the Atacama Large Millimeter/submillimeter…

We present new radio-frequency interferometric maps of emission from the 14NH3, 15NH3, and 14NH2D isotopologues of ammonia, and the 12CH3OH and 13CH3OH isotopologues of methanol toward Sgr B2(N). With a resolution of ~3'' (0.1 pc), we are…

Astrophysics of Galaxies · Physics 2018-12-26 E. A. C. Mills , J. Corby , A. R. Clements , N. Butterfield , P. Jones , M. Cunningham , J. Ott

To study the impact of the initial effects of metallicity (i.e., the abundance of elements heavier than helium) on star formation and the formation of different molecular species, we searched for hot molecular cores in the sub-solar…

Methanol (CH$_3$OH) is at the root of organic ice chemistry in protoplanetary disks. However, its weak emission has made detections difficult. To date, gas-phase CH$_3$OH has been detected in only one Class II disk, TW Hya. We use the…

Solar and Stellar Astrophysics · Physics 2019-03-20 M. T. Carney , M. R. Hogerheijde , V. V. Guzmán , C. Walsh , K. I. Öberg , E. C. Fayolle , L. I. Cleeves , J. M. Carpenter , C. Qi

We characterize the molecular environment of candidate massive young stellar objects (MYSOs) signposted by methanol masers. Single pixel observations of 10 transitions of HCO^+, CO and CS isotopomers were carried out, using the IRAM 30m…

Astrophysics · Physics 2009-11-13 M. Szymczak , A. Bartkiewicz , A. M. S. Richards

Molecular oxygen has been the subject of many observational searches as chemical models predicted it to be a reservoir of oxygen. Although it has been detected in two regions of the interstellar medium, its rarity is a challenge for…

Astrophysics of Galaxies · Physics 2019-06-04 V. Wakelam , M. Ruaud , P. Gratier , I. A. Bonnell

Excess levels of 15N isotopes which have been detected in primitive solar system materials are explained as a remnant of interstellar chemistry which took place in regions of the protosolar nebula. Chemical models of nitrogen fractionation…

Astrophysics of Galaxies · Physics 2015-05-18 Luca Bizzocchi , Paola Caselli , Luca Dore

Despite its potential reactivity due to ring strain, ethylene oxide (c-C2H4O) is a complex molecule that seems to be stable under the physical conditions of an interstellar dense core; indeed it has been detected towards several high-mass…

Astrophysics of Galaxies · Physics 2015-06-11 A. Occhiogrosso , S. Viti , M. D. Ward , S. D. Price

We studied class I methanol masers in the transition 7_0-6_1 A+ at the frequency 44 GHz with the VLA. The observations on the VLA were made with the angular resolution 0''.1, which was the highest at the moment. It was shown that the masers…

Astrophysics · Physics 2007-05-23 V. I. Slysh , I. E. Val'tts , S. V. Kalenskii

Hydrogenation reactions of CO in inter- and circumstellar ices are regarded as an important starting point in the formation of more complex species. Previous laboratory measurements by two groups on the hydrogenation of CO ices resulted in…

Solar and Stellar Astrophysics · Physics 2009-06-15 G. W. Fuchs , H. M. Cuppen , S. Ioppolo , C. Romanzin , S. E. Bisschop , S. Andersson , E. F. van Dishoeck , H. Linnartz

Column density ratios of complex organic molecules are generally constant across protostellar systems with some low-level scatter. However, the scatter in formamide (NH$_2$CHO) to methanol (CH$_3$OH) column density ratio is one of the…

Astrophysics of Galaxies · Physics 2024-07-24 P. Nazari , B. Tabone , G. P. Rosotti , E. F. van Dishoeck

Extensive molecular dynamics computer simulations have been conducted for ethanol-water liquid mixtures in the water-rich side of the composition range, with 10, 20 and 30 mol % of the alcohol, at temperatures between room temperature and…

Chemical Physics · Physics 2019-06-12 Szilvia Pothoczki , László Pusztai , Imre Bakó

Deuterated molecules have been detected and studied toward Orion BN/KL in the past decades, mostly with single-dish telescopes. However, high angular resolution data are critical not only for interpreting the spatial distribution of the…

Astrophysics of Galaxies · Physics 2015-06-05 T. -C. Peng , D. Despois , N. Brouillet , B. Parise , A. Baudry

Water is a crucial molecule in molecular astrophysics as it controls much of the gas/grain chemistry, including the formation and evolution of more complex organic molecules in ices. Pre-stellar cores provide the original reservoir of…

The 6.7 GHz maser transition of methanol has been found exclusively towards massive star forming regions. A majority of the masers have been found to lack the presence of any associated radio continuum. This could be due to the maser…

Astrophysics of Galaxies · Physics 2015-05-19 J. D. Pandian , E. Momjian , Y. Xu , K. M. Menten , P. F. Goldsmith

We report the results of a SEST 1.2 mm continuum emission survey toward regions previously identified as harbouring a methanol maser and/or an UC HII region, typically indicative of massive star formation. Emission is detected toward all of…

Astrophysics · Physics 2009-11-11 T. Hill , M. G. Burton , V. Minier , M. A. Thompson , A. J. Walsh , M. Hunt-Cunningham , G. Garay

The hot gas in galaxy halos may account for a significant fraction of missing baryons in galaxies, and some of these gases can be traced by high ionization absorption systems in QSO UV spectra. Using high S/N ratio $ HST$/COS spectra, we…

Astrophysics of Galaxies · Physics 2016-12-14 Zhijie Qu , Joel N. Bregman

Large ammonia clusters represent a model system of ices which are omnipresent throughout the space. The interaction of ammonia ices with other hydrogen-boding molecules such as methanol or water and their behavior upon an ionization are…

Atomic and Molecular Clusters · Physics 2018-10-15 Michal Fárník , Andriy Pysanenko , Kamila Moriová , Lorenz Ballauf , Paul Scheier , Jan Chalabala , Petr Slavícek

We investigate the molecular evolution and D/H abundance ratios that develop as star formation proceeds from a dense-cloud core to a protostellar core, by solving a gas-grain reaction network applied to a 1-D radiative hydrodynamic model…

Astrophysics of Galaxies · Physics 2015-06-11 Yuri Aikawa , Valentine Wakelam , Franck Hersant , Robin T. Garrod , Eric Herbst