Related papers: Water and Methanol Ice in L1544
Complex organic molecules, such as propylene (CH3CHCH2), are detected in molecular clouds (such as TMC1) with high fractional abundances (~2.10^{-9}, relative to hydrogen) that cannot be explained by gas-phase chemical reactions under…
The results of experiments on the formation of molecular hydrogen on low density and high density amorphous ice surfaces are analyzed using a rate equation model. The activation energy barriers for the relevant diffusion and desorption…
Dense cloud cores present chemical differentiation due to the different distribution of C-bearing and N-bearing molecules, the latter being less affected by freeze-out onto dust grains. In this letter we show that two C-bearing molecules,…
Context. Observations of $\rm ^{14}N/^{15}N$ in the interstellar medium are becoming more frequent thanks to the increased telescope capabilities. However, interpreting these data is still puzzling. In particular, measurements of $\rm…
1-propanol (CH3CH2CH2OH) is a three carbon-bearing representative of primary linear alcohols that may have its origin in the cold dark cores in interstellar space. To test this, we investigated in the laboratory whether 1-propanol ice can…
OH(1720 MHz) and methanol masers are now recognized to be excellent probes of the interactions of supernova remnants with molecular clouds and tracers of massive star formation, respectively. To better understand the nature of star…
The inheritance of material across the star and planet formation process is traced by deuterium fractionation. We report here the first detection of doubly deuterated methanol towards pre-stellar cores. We study the deuterium fractionation…
It is speculated that there might be some linkage between interstellar aldehydes and their corresponding alcohols. Here, an observational study and astrochemical modeling are coupled together to illustrate the connection between them. The…
The destiny of complex organic molecules (COMs) in star-forming regions is interlinked with various evolutionary phases. Therefore, identifying these species in diversified environments of identical star-forming regions would help to…
In this paper we use observations of molecular tracers in metal rich and alpha-enhanced galaxies to study the effect of abundance changes on molecular chemistry. We selected a sample of metal rich spiral and star bursting objects from the…
The chemical evolution in star forming regions is driven by the interplay between gas and ice mantles. Identifying the ice compositions at the early stage of star formation thus provides constraints on the chemical processes inaccessible…
We observed the pre-stellar core L1521F in dust emission at 1.2mm and in two transitions each of N2H+, N2D+, C18O, and C17O in order to increase the sample of well studied centrally concentrated and chemically evolved starless cores, likely…
The first detection of gas-phase methanol in a protoplanetary disk (TW Hya) is presented. In addition to being one of the largest molecules detected in disks to date, methanol is also the first disk organic molecule with an unambiguous ice…
Molecular segregation in methanol-water mixtures is studied across a wide concentration range as a function of temperature and pressure. Cluster distributions obtained from both neutron diffraction and molecular dynamics simulations point…
We have observed the $^{13}$CH$_3$OH $5_1-4_1$ A$^+$, $^{13}$CH$_3$OH $14_1-13_2$ A$^-$, and CH$_2$DOH $8_{2,6}-8_{1,7}$ $e_0$ lines toward 24 high-mass star-forming regions by using Atacama Large Millimeter/submillimeter Array (ALMA) with…
Context. Recent Monte Carlo simulations and laboratory studies of interstellar ices have proposed an alternative pathway involving the radical-molecule H-atom abstraction reaction in the overall mechanism of methanol (CH3OH) formation in…
Context. The number of identified complex organic molecules (COMs) in inter- and circumstellar gas-phase environments is steadily increasing. Recent laboratory studies show that many such species form on icy dust grains. At present only…
The recent discovery of methyl formate and dimethyl ether in the gas phase of cold cores with temperatures as cold as 10 K challenges our previous astrochemical models concerning the formation of complex organic molecules. The strong…
Comparison of their chemical compositions shows, to first order, a good agreement between the cometary and interstellar abundances. However, a complex O-bearing organic molecule, ethylene glycol (CH$_{2}$OH)$_{2}$, seems to depart from this…
We present the results of the first complete survey of the Large and Small Magellanic Clouds for 6668-MHz methanol and 6035-MHz excited-state hydroxyl masers. In addition to the survey, higher-sensitivity targeted searches towards known…