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In order to detect the effect of the surface charge discreteness on the properties at the solid-liquid interface, molecular dynamics simulation model taking consideration of the vibration of wall atoms was used to investigate the ion and…

Chemical Physics · Physics 2016-12-20 Yinghua Qiu , Yunfei Chen

Deposition of particles while flowing past constrictions is a ubiquitous phenomenon observed in diverse systems. Some common examples are jamming of salt crystals near the orifice of saltshakers, clogging of filter systems, gridlock in…

Soft Condensed Matter · Physics 2021-12-09 P. Prakash , A. Z. Abdulla , M. Varma

Mean-field theory is used to model polyelectrolyte adsorption and the possibility of overcompensation of charged surfaces. For charged surfaces that are also chemically attractive, the overcharging is large in high salt conditions,…

Soft Condensed Matter · Physics 2009-11-10 Adi Shafir , David Andelman

An evaporating droplet is a dynamic system in which flow is spontaneously generated to minimize the surface energy, dragging particles to the borders and ultimately resulting in the so-called "coffee-stain effect". The situation becomes…

Fluid Dynamics · Physics 2015-11-24 Alvaro Marin , Robert Liepelt , Massimiliano Rossi , Christian J. Kähler

Charge separation at moving three-phase contact lines is observed in nature as well as technological processes. Despite the growing number of experimental investigations in recent years, the physical mechanism behind the charging remains…

Soft Condensed Matter · Physics 2023-05-04 Aaron D. Ratschow , Lisa S. Bauer , Pravash Bista , Stefan A. L. Weber , Hans-Jürgen Butt , Steffen Hardt

We study the distribution of multivalent counterions next to a dielectric slab, bearing a quenched, random distribution of charges on one of its solution interfaces, with a given mean and variance, both in the absence and in the presence of…

Soft Condensed Matter · Physics 2015-06-22 Ali Naji , Malihe Ghodrat , Haniyeh Komaie-Moghaddam , Rudolf Podgornik

The open water surface is known to be charged. Yet, the magnitude of the charge and the physical mechanism of the charging remain unclear, causing heated debates across the scientific community. Here we directly measure the charge Q of…

Surface charging is a phenomenon ubiquitously observable in in-situ transmission electron microscopy of non-conducting specimens as a result of electron beam/sample interactions or optical stimuli and often limits the achievable image…

Mesoscale and Nanoscale Physics · Physics 2024-08-27 Jonathan T. Weber , Sascha Schäfer

The interaction between charged objects in solution is generally expected to recapitulate two central principles of electromagnetics: (i) like-charged objects repel, and (ii) they do so regardless of the sign of their electrical charge.…

Soft Condensed Matter · Physics 2022-12-27 Sida Wang , Rowan Walker-Gibbons , Bethany Watkins , Melissa Flynn , Madhavi Krishnan

Interfering liquid surface waves are generated by electrically driven vertical oscillations of two or more equispaced pins immersed in a liquid (water). The corresponding intensity distribution, resulting from diffraction of monochromatic…

Optics · Physics 2009-11-10 Tarun Kr. Barik , Anushree Roy , Sayan Kar

From soap-covered dishes to freshly cleaned floors, surfactants can make surfaces slippery; yet, the underlying mechanism remains poorly understood. Here, we identify the molecular origin behind this ubiquitous phenomenon using macroscopic…

We present a continuum model describing dissolution and growth of a crystal contact confined against a substrate. Diffusion and hydrodynamics in the liquid film separating the crystal and the substrate are modeled within the lubrication…

Soft Condensed Matter · Physics 2018-01-31 Luca Gagliardi , Olivier Pierre-Louis

Mineral replacement reactions under advective flow often suffer from severe spatial inefficiency: dissolution causes the flow to self-focus into a few dominant wormholes that bypass the surrounding matrix, leaving most of the rock…

Fluid Dynamics · Physics 2026-03-31 Agnieszka Budek , Tomasz Szawełło , Vaughan Voller , Piotr Szymczak

The microscopic and fundamental origin of slide electrification, where droplets of water move across insulating surfaces accumulating and depositing electrical charges, is still debated. Charge transfer is often attributed to ion transfer…

Soft Condensed Matter · Physics 2026-04-30 Rutvik Lathia , Benjamin Leibauer , Aaron D. Ratschow , Werner Steffen , Hans-Jürgen Butt

We present a theory for phase-separated liquid coacervates with salt, taking into account spatial heterogeneities and interfacial profiles. We find that charged layers of alternating sign can form around the interface while the bulk phases…

Soft Condensed Matter · Physics 2024-08-07 Arghya Majee , Christoph A. Weber , Frank Jülicher

We consider a system consisting of a geometric evolution equation for a hypersurface and a parabolic equation on this evolving hypersurface. More precisely, we discuss mean curvature flow scaled with a term that depends on a quantity…

Analysis of PDEs · Mathematics 2022-05-06 Helmut Abels , Felicitas Bürger , Harald Garcke

Diffusiophoresis, a ubiquitous phenomenon that induces particle transport whenever solute concentration gradients are present, was recently observed in the context of microsystems and shown to strongly impact colloidal transport (patterning…

We predict a condensation phenomenon in an overall neutral system, consisting of a single charged plate and its oppositely charged counterions. Based on the ``two-fluid'' model, in which the counterions are divided into a ``free'' and a…

Soft Condensed Matter · Physics 2016-08-31 A. W. C. Lau , D. B. Lukatsky , P. Pincus , S. A. Safran

Surface specific vibrational spectroscopies revolutionized the study of charged interfaces, by sensitively probing water's response in the electric double layer (EDL) and correlating it with surface charge via models like Gouy Chapmann…

Chemical Physics · Physics 2025-04-07 Wanlin Chen , Marie-Pierre Gaigeot , Simone Pezzotti

A phase-field approach to the dynamics of liquid-solid interfaces that evolve due to precipitation and/or dissolution is presented. For the purpose of illustration and comparison with other methods, phase field simulations were carried out…

Computational Physics · Physics 2018-07-04 Zhijie Xu , Paul Meakin