Elucidating contact electrification mechanism of water
Abstract
The open water surface is known to be charged. Yet, the magnitude of the charge and the physical mechanism of the charging remain unclear, causing heated debates across the scientific community. Here we directly measure the charge Q of microdrops ejected from hydrophilic and hydrophobic capillaries and show that the water surface can take both positive or negative charge values depending on pH and the capillary type. Our experiments, theory, and simulations provide evidence that a junction of two aqueous interfaces with a different ion adsorption energy (e.g., liquid-solid and liquid-air interfaces) develops a pH-dependent contact potential difference {\Delta}{\phi} up to 52 mV. The longitudinal charge transfer between the interfaces stimulated by {\Delta}{\phi} determines the charge of the open water surface. The suggested static electrification mechanism provides far-reaching insights into the origin of electrical potentials in biological and electrochemical energy systems.
Keywords
Cite
@article{arxiv.2212.14758,
title = {Elucidating contact electrification mechanism of water},
author = {Vasily Artemov and Laura Frank and Roman Doronin and Philipp Stärk and Alexander Schlaich and Anton Andreev and Thomas Leisner and Aleksandra Radenovic and Alexei Kiselev},
journal= {arXiv preprint arXiv:2212.14758},
year = {2026}
}
Comments
21 pages main text, 4 figures, supporting information, including the theory of the charge transfer between two dissimilar aqueous interfaces induced by the contact potential difference, details of molecular dynamics simulations, and additional graphs, photos, and diagrams, including Figures S1 to S18 and Table S1