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Magnetic circular dichroism (MCD) is a widely used spectroscopic technique which reveals valuable information about molecular geometry and electronic structure. However, the weak signal and the necessary strong magnets impose major…

Chemical Physics · Physics 2022-11-16 Jiaan Cao , Lyuzhou Ye , Dawei He , Xiao Zheng , Shaul Mukamel

A light beam can carry both spin angular momentum (SAM) and orbital angular momentum (OAM). SAM is commonly evidenced by circular dichroism (CD) experiments {\em i. e.} differential absorption of left and right-handed circularly polarized…

We report here chiroptical amplification effect occurring in the hybrid systems consisting of chiral molecules and Si nanostructures. Under resonant excitation of circularly polarized light, the hybrid systems show strong CD induction…

Optics · Physics 2017-12-27 Weixuan Zhang , Tong Wu , Rongyao Wang , Xiangdong Zhang

Large optical chirality in the vicinity of achiral high index dielectric nanostructures has been recently demonstrated as useful means of enhancing molecular circular dichroism. We theoretically study the spatial dependence of optical…

Optics · Physics 2022-05-25 Krzysztof M. Czajkowski , Tomasz J. Antosiewicz

We present a system consisting of two stacked chiral plasmonic nanoelements, so-called triskelia, that exhibits a high degree of circular dichroism. The optical modes arising from the interactions between the two elements are the main…

Helical dichroism (HD), originating from the interplay between chiral plasmonic structures and left and right vortex light carrying orbital angular momentum (OAM), has attracted significant attention across various disciplines owing to its…

Optics · Physics 2025-08-08 Takahiro Uto , An'an Wu , Tsutomu Shimura , Yoshito Y. Tanaka

The interaction between chiral molecules and circularly polarized light is largely influenced by the local optical chirality density. This interaction prompts substantial demand of the design of nanophotonic platforms capable of enhancing…

Optics · Physics 2025-09-30 Guillermo Serrera , Javier González-Colsa , Pablo Albella

Broken symmetry plays a pivotal role in determining the macroscopic electrical, optical, magnetic, and topological properties of materials. Circular dichroism (CD) has been widely employed to probe broken symmetry in various systems, from…

Mesoscale and Nanoscale Physics · Physics 2024-11-14 Shu-Liang Ren , Simin Pang , Shan Guan , Yu-Jia Sun , Tian-Yu Zhang , Nai Jiang , Jiaqi Guo , Hou-Zhi Zheng , Jun-Wei Luo , Ping-Heng Tan , Chao Shen , Jun Zhang

Chiral crystals show promise for spintronic technologies on account of their high spin selectivity, which has led to significant recent interest in quantitative characterization and first-principles prediction of their spin-optoelectronics…

Materials Science · Physics 2023-12-05 Christian Multunas , Andrew Grieder , Junqing Xu , Yuan Ping , Ravishankar Sundararaman

We use numerical simulations to demonstrate third-harmonic generation with near-unity nonlinear circular dichroism (CD) and high conversion efficiency ($ 10^{-2}\ \text{W}^{-2}$) in asymmetric Si-on-SiO$_2$ metasurfaces. The working…

X-ray magnetic circular dichroism provides a means to identify ferromagnetic, chiral, and altermagnetic orders via their time-reversal-symmetry ($\mathcal{T}$) breaking. However, differentiating magnetic domains related by crystallographic…

We present the design and optical characterization of a plasmonic metasurface engineered to exhibit strong polarization anisotropy under both linearly and circularly polarized light. The metasurface consists of geometrically asymmetric gold…

Circular Dichroism (CD) spectroscopy has evolved from a purely solution based method towards a powerful tool in the analysis of chiral thin films. Although a straightforward technique, the genuine CD signal is often accompanied by artifacts…

Controlling optical chirality at the subwavelength scales is essential for many applications of nanophotonic structures in polarization optics, sensing, and nonlinear photonics. Achieving a strong chiroptical response in planar dielectric…

DNA and proteins are chiral: their three-dimensional structure cannot be superimposed with its mirror image. Circular dichroism spectroscopy is widely used to characterize chiral compounds, but data interpretation is difficult in the case…

Biomolecules · Quantitative Biology 2020-09-09 Steven Daly , Frederic Rosu , Valerie Gabelica

Magnetic circular dichroism (MCD) in the x-ray absorption spectroscopy (XAS) at the L2,3 edges for almost entire series of rare-earth (RE) elements in RE2Fe14B, is studied experimentally and theoretically. By a quantitative comparison of…

Strongly Correlated Electrons · Physics 2009-10-31 K. Fukui , H. Ogasawara , A. Kotani , I. Harada , H. Maruyama , N. Kawamura , K. Kobayashi , J. Chaboy , A. Marcelli

We report on a joint experimental and theoretical study of photoelectron circular dichroism (PECD) in methyloxirane. By detecting O 1s-photoelectrons in coincidence with fragment ions, we deduce the molecule's orientation and photoelectron…

Recent efforts in the field of surface-enhanced spectroscopies have focused on the paradigm of superchirality, entailing the engineering of the local electromagnetic fields to boost the enantiospecific interaction between light and chiral…

Polariton states with high levels of chiral dissymmetry offer exciting prospects for quantum information, sensing, and lasing applications. Such dissymmetry must emanate from either the involved optical resonators or the quantum emitters.…

Chemical Physics · Physics 2022-09-28 Andrew H. Salij , Randall H. Goldsmith , Roel Tempelaar

Optically active achiral metasurfaces offer a promising way to detect chiral molecules based on chiroptic methods. The combination of plasmonic enhanced circular dichroism and reversible optical activity would boost the sensitivity and…