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Following long-standing predictions associated with hydrogen, high-temperature superconductivity has recently been observed in several hydride-based materials. Nevertheless, these high-$T_c$ phases only exist at extremely high pressures,…

Recent predictions of metastable high-temperature hydride superconductors give hope that superconductivity at ambient conditions is within reach. In this work, we predict RbPH$_3$ as a new compound with a superconducting critical…

Inspired by recent predictions of superconductivity in B-C framework clathrates, we employ density functional theory to explore potential superconductors among hexagonal hydride-substituted compounds with compositions XB$_8$C, XB$_7$C$_2$,…

Superconductivity · Physics 2025-03-11 Bin Li , Yuxiang Fan , Chuanhui Yin , Junjie Zhai , Cong Zhu , Zhisi Cao , Jie Cheng , Shengli Liu

Superconductivity (SC) was experimentally observed for the first time in antimony polyhydride. The diamond anvil cell combined with laser heating system was used to synthesize the antimony polyhydride sample at high pressure and high…

Recently, the thorium hydride ThH9 possessing an H-rich clathrate structure has been experimentally synthesized to exhibit a superconducting transition temperature Tc of 146 K at 170-175 GPa, while the more H-rich clathrate thorium hydride…

Superconductivity · Physics 2023-02-15 Shichang Yao , Chongze Wang , Hyunsoo Jeon , Liangliang Liu , Jin Mo Bok , Yunkyu Bang , Yu Jia , Jun-Hyung Cho

The compression of SH$_2$ and its subsequent decomposition to SH$_3$, presumably in a cubic Im$\overline{3}$m structure, has lead to the discovery of conventional superconductivity with the highest measured and confirmed $T_c$ to date, 203…

Materials Science · Physics 2019-02-20 Maximilian Amsler

Lu5Rh6Sn18 is one of the caged-type quasiskutterudite superconductors with superconducting transition temperature Tc = 4.12 K. Here, we investigate the effect of pressure on the superconductivity in Lu5Rh6Sn18 by combining high pressure…

Superconductivity · Physics 2023-10-20 Chao Xiong , Cuiying Pei , Qi Wang , Yi Zhao , Yuyang Jiang , Changhua Li , Weizheng Cao , Na Yu , Lili Zhang , Yanpeng Qi

Binary uranium hydrides, UHx (x = 1, 2, 3, 5, 6, 7, 8), with different crystal symmetries are potentially interesting compounds for high-Tc superconductivity and as hydrogen storage systems. In this work we have explored the structural,…

Materials Science · Physics 2023-06-12 Md. Ashraful Alam , F. Parvin , S. H. Naqib

We report superconductivity at 1.4K in the ternary SrPt$_{10}$P$_4$ with a complex new structure. SrPt$_{10}$P$_4$ crystallizes in a monoclinic space-group C2/c (\#15) with lattice parameters a= 22.9151(9)$\AA$, b= 13.1664(5)$\AA$,…

Superconductivity · Physics 2017-12-07 Bing Lv , BenMaan I. Jawdat , Zheng Wu , Sheng Li , Ching-Wu Chu

Recently, C. M. P\'epin \textit{et al.} [Science \textbf{357}, 382 (2017)] reported the formation of several new iron polyhydrides FeH$_x$ at pressures in the megabar range, and spotted FeH$_5$, which forms above 130 GPa, as a potential…

Superconductivity · Physics 2018-06-15 Christoph Heil , Giovanni B. Bachelet , Lilia Boeri

High-temperature high-pressure superconducting hydrides are typically characterized by cage-like hydrogenic lattices filled with electropositive metal atoms. Here, density functional theory based evolutionary crystal structure searches find…

Superconductivity · Physics 2024-09-18 Morgan Redington , Eva Zurek

Rhodium-containing compounds offer a fertile playground to explore novel materials with superconductivity and other fantastic electronic correlation effects. A new ternary rhodium-antimonide La$_2$Rh$_{3+\delta}$Sb$_4$ ($\delta\approx 1/8$)…

Superconductivity · Physics 2022-10-14 Kangqiao Cheng , Wei Xie , Shuo Zou , Huanpeng Bu , Jin-Ke Bao , Zengwei Zhu , Hanjie Guo , Chao Cao , Yongkang Luo

In the last decade, there has been great progress in predicting and synthesizing polyhydrides that exhibit superconductivity when squeezed. Dopants allow these compounds to become metals at pressures lower than those required to metallize…

Materials Science · Physics 2024-05-21 Xiaoyu Wang , Nisha Geng , Kyla de Villa , Burkard Militzer , Eva Zurek

Evolutionary searches predicted a number of ternary phases that could be synthesized at pressures of 100-300~GPa. $P6_3/mmc$ CaSH$_2$, $Pnma$ CaSH$_2$, $Cmc2_1$ CaSH$_6$, and $I\bar{4}$ CaSH$_{20}$ were composed of a Ca-S lattice along with…

Superconductivity · Physics 2021-01-01 Yan Yan , Tiange Bi , Nisha Geng , Xiaoyu Wang , Eva Zurek

We report the ac magnetic susceptibility, electrical resistance, and X-ray diffraction measurements of platinum hydride (PtHx) in diamond anvil cells, which reveal its superconducting transition. At 32 GPa, when PtHx is in a P63/mmc…

By replacing the alkali element in the newly discovered K2Mo3As3 superconductor, we successfully synthesized ternary molybdenum pnictides Rb2Mo3As3 and Cs2Mo3As3 through solid state reaction method. Powder X-ray diffraction analysis reveals…

Superconductivity · Physics 2018-05-30 Kang Zhao , Qing-Ge Mu , Tong Liu , Bo-Jin Pan , Bin-Bin Ruan , Lei Shan , Gen-Fu Chen , Zhi-An Ren

This article updates version 1 by restricting consideration to only the resistive data and excluding the questioned 287.7-K datum reported for carbonaceous sulfur hydride in Snider et al., Nature $\textbf{585}$, 373 (2020). The…

Superconductivity · Physics 2023-07-18 Dale R. Harshman , Anthony T. Fiory

Recent experiments have shown that CeH9 and (Ce,La)H9 can be synthesized under high pressure between 90-170GPa and become a superconductor with a high value of superconducting critical temperature (Tc) between 100-200K. In this work, we…

Superconductivity · Physics 2022-04-13 Prutthipong Tsuppayakorn-aek , Udomsilp Pinsook , Thiti Bovornratanaraks

8K superconductivity was observed in the metal rich Li-Pd-B ternary system. Structural, microstructural, electrical and magnetic investigations for various compositions proved that Li2Pd3B compound, which has a cubic structure composed of…

Superconductivity · Physics 2009-11-10 K. Togano , P. Badica , Y. Nakamori , S. Orimo , H. Takeya , K. Hirata

Inspired by the synthesis of XB3C3 (X= Sr, La) compounds in the bipartite sodalite clathrate structure, density functional theory (DFT) calculations are performed on members of this family containing up to two different metal atoms. A…

Superconductivity · Physics 2023-01-27 Nisha Geng , Katerina P. Hilleke , Li Zhu , Xiaoyu Wang , Timothy A. Strobel , Eva Zurek
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