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Silicon anodes offer high energy densities for next-generation lithium-ion batteries; however, their application is limited by severe volume expansion during cycling. Making silicon porous or nanostructured mitigates this expansion but…

Nanostructured Si is the most promising high-capacity anode material to substantially increase the energy density of Li-ion batteries. Among the remaining challenges is its low rate capability as compared to conventional materials. To…

Disordered Systems and Neural Networks · Physics 2019-01-29 Nongnuch Artrith , Alexander Urban , Yan Wang , Gerbrand Ceder

Photo-rechargeable (solar) battery can be considered as an energy harvesting cum storage system, where it can charge the conventional metal-ion battery using light instead of electricity, without having other parasitic reactions. Here we…

The lithium (Li) metal anode is essential for next generation high energy density rechargeable Li metal batteries. Although extensive studies have been performed to prolong the cycle life of Li metal batteries, the calendar life, which…

Materials Science · Physics 2022-04-26 Bingyu Lu , Weikang Li , Diyi Cheng , Miguel Ceja , Wurigumula Bao , Chengcheng Fang , Ying Shirley Meng

Fast-growing electronics industry and future energy storage needs have encouraged the design of rechargeable batteries with higher storage capacities, and longer life times. In this regard, two-dimensional (2D) materials, specifically boron…

Applied Physics · Physics 2018-03-21 Meysam Makaremi , Bohayra Mortazavi , Chandra Veer Singh

Energy storage technologies that can meet the unprecedented demands of a sustainable energy system based on intermittent energy sources require new battery materials. We investigate high ionic conductors, Li$_3$ClO glasses. In the present…

Materials Science · Physics 2021-04-09 Young Won Choi , Moyses Araujo , Levente Vitos , Raquel Lizárraga

The identification of alternatives to the Lithium-ion battery architecture remains a crucial priority in the diversification of energy storage technologies. Accompanied by the low reduction potential of $\mathrm{Ca^{2+}/Ca}$, -2.87 V vs.…

Materials Science · Physics 2021-07-29 Wang Lu , Juefan Wang , Gopalakrishnan Sai Gautam , Pieremanuele Canepa

The potential of tetra-penta-deca-hexagonal graphene (TPDH-gr), a recently proposed 2D carbon allotrope as an anodic material in lithium ion batteries (LIB), was investigated through density functional theory (DFT) calculations. The results…

Aqueous rechargeable batteries are promising energy storage devices for the high safety, environmental friendliness, and easy assembly. However, their cycle stability and low temperature performance are limited by the narrow electrochemical…

Chemical Physics · Physics 2022-06-17 Yuewang Yang , Sijing Liu , Zhaowen Bai , Baoling Huang

Controlling nanostructure from molecular, crystal lattice to the electrode level remains as arts in practice, where nucleation and growth of the crystals still require more fundamental understanding and precise control to shape the…

Li$_{7-4x}$Ge$_x$La$_3$Zr$_2$O$_{12}$ has been synthesized using the conventional solid-state reaction method by substituting Germanium (Ge) at the Li site, which increases the Li-ion vacancies and leads to an increase in conductivity with…

Materials Science · Physics 2023-08-15 Muktai Aote , A. V. Deshpande

Sodium-titanate \ce{Na2Ti3O7} (NTO) is regarded as a highly promising anode material with a very low voltage for Na-ion batteries and capacitors, but suffered from relatively low specific capacity and poor electron conductivity. Here we…

Materials Science · Physics 2020-06-19 Chol-Jun Yu , Suk-Gyong Hwang , Yong-Chol Pak , Song-Hyok Choe , Jin-Song Kim , Kum-Chol Ri

Developing sustainable battery electrode manufacturing methods is particularly pressing for alloying-type active materials, such as silicon, which often require additional energy-intensive and solvent-based processing to reinforce them with…

Materials Science · Physics 2022-06-30 Moumita Rana , Afshin Pendashteh , Richard Schäufele , Joaquim Gispert , Juan J. Vilatela

We demonstrate that for polycrystalline LiNi0.33Mn0.33Co0.33O2 c-axis textured thin film cathodes of rechargeable lithium-ion batteries, the kinetics of Li storage and release including maximum specific capacity is determined by Li…

Materials Science · Physics 2025-09-11 Erwin Hüger , Harald Schmidt

In Lithium ion batteries (LIBs), proper design of cathode materials influences its intercalation behavior, overall cost, structural stability, and its impact on environment. At present, the most common type of cathode materials, NCA , has…

Materials Science · Physics 2018-04-03 Kamalika Ghatak , Hemant Kumar , Siva Nadimpalli , Dibakar Datta

The storage mechanism and diffusion kinetics of Na$_{3}$V$_{2-x}$Ni$_{x}$(PO$_{4}$)$_{2}$F$_{3}$/C ($x=$ 0--0.07) cathodes are investigated through electrochemical impedance spectroscopy (EIS), galvanostatic intermittent titration technique…

Materials Science · Physics 2025-10-01 Simranjot K. Sapra , Jeng-Kuei Chang , Rajendra S. Dhaka

A safe lithium-sulfur (Li-S) battery employs a composite polymer electrolyte based on a poly(ethylene glycol) dimethyl ether (PEGDME) solid at room temperature. The electrolyte membrane enables a stable and reversible Li-S electrochemical…

Applied Physics · Physics 2021-10-27 Vittorio Marangon , Daniele Di Lecce , Luca Minnetti , Jusef Hassoun

Li-O$_2$ batteries (LOB) performance degradation ultimately occurs through the accumulation of discharge products and irreversible clogging of the porous electrode during the cycling. Electrode binder degradation in the presence of reduced…

In this study, we have employed a DFT+U calculation using quantum-espresso (QE) code to investigate the structural, electronic, optical, and magnetic properties of LiFePO$\rm_{4}$ cathode material for Li-ion batteries. Crystals of…

Materials Science · Physics 2023-05-22 A. K. Wabeto , K. N. Nigussa , L. D. Deja

The performance of modern lithium-sulfur (Li/S) battery systems critically depends on the electrolyte and solvent compositions. For fundamental molecular insights and rational guidance of experimental developments, efficient and…