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Partial atomic charges are a useful and intuitive concept for understanding molecular properties and chemical reaction mechanisms, showing how changes in molecular geometry can affect the flow of electronic charge within a molecule.…

Chemical Physics · Physics 2022-01-14 Ryan J. MacDonell , Serguei Patchkovskii , Michael S. Schuurman

A full set of vibrationally-resolved cross sections for electron impact excitation of NO(X2{\Pi}, v) molecules is calculated from ab initio molecular dynamics, in the framework of the local-complex-potential approach. Electron-vibration…

Atomic Physics · Physics 2024-11-15 V Laporta , L Vialetto , V Guerra

We study the coherent dynamics of excitations on vibrating chains. By applying an external field and matching the field strength with the oscillation frequency of the chain it is possible to obtain an (average) transport of an initial…

Quantum Physics · Physics 2015-05-20 Oliver Muelken , Maximilian Bauer

There have been concerted efforts in recent years to realize the next generation of clocks using alkaline earth atoms in an optical lattice. Assuming that the atoms are independent, such a clock would benefit from a $\sqrt{N}$ enhancement…

Quantum Physics · Physics 2019-02-04 Loïc Henriet , James S. Douglas , Darrick E. Chang , Andreas Albrecht

Oscillation is an important cellular process that regulates timing of different vital life cycles. However, in the noisy cellular environment, oscillations can be highly inaccurate due to phase fluctuations. It remains poorly understood how…

Biological Physics · Physics 2015-09-30 Yuansheng Cao , Hongli Wang , Qi Ouyang , Yuhai Tu

The charge ordering transition induced by the nearest-neighbor Coulomb repulsion, V, in the 1/4-filled extended Hubbard model is investigated using Cellular Dynamical Mean-Field Theory. We find a transition to a strongly renormalized charge…

Strongly Correlated Electrons · Physics 2009-11-13 Jaime Merino

Molecular dynamical (MD) simulations are performed to simulate two dimensional vibrofluidized granular materials in this work. Statistics on simulation results indicate that there exist shocks propagating upward in each vibrating cycle.…

Soft Condensed Matter · Physics 2007-05-23 Kai Huang , Guoqing Miao , Peng Zhang , Yifei Zhu , Rongjue Wei

Force fields uniquely assign interatomic forces for a given set of atomic coordinates. The underlying assumption is that electrons are in their quantum-mechanical ground state or in thermal equilibrium. However, there is an abundance of…

Materials Science · Physics 2013-08-19 Wolf B. Dapp , Martin H. Müser

We simulate the long-range inter-complex electronic energy transfer in Photosystem II -- from the antenna complex, via a core complex, to the reaction center -- using a non-Markovian (ZOFE) quantum master equation description that allows us…

Chemical Physics · Physics 2016-07-27 Jan J. J. Roden , Doran I. G. Bennett , K. Birgitta Whaley

Atomic clock interferometers are a valuable tool to test the interface between quantum theory and gravity, in particular via the measurement of gravitational time dilation in the quantum regime. Here, we investigate whether gravitational…

Quantum Physics · Physics 2023-03-15 Carlo Cepollaro , Flaminia Giacomini , Matteo G. A. Paris

In time-resolved pump-probe vibrational spectroscopy the internal stretch mode of polar molecules is utilized as a key observable to characterize the ultrafast dynamics of adsorbates on surfaces. The adsorbates non-adiabatic intermode…

Materials Science · Physics 2023-03-13 Raúl Bombín , Alberto S. Muzas , Dino Novko , J. Iñaki Juaristi , Maite Alducin

We have studied electrical switching with S-shaped I-V characteristics in two-terminal MOM devices based on vanadium dioxide thin films. The switching effect is associated with the metal-insulator phase transition. Relaxation oscillations…

Applied Physics · Physics 2020-01-08 Alexander Pergament , Andrei Velichko , Maksim Belyaev , Vadim Putrolaynen

Electron channeling in silicon crystals has brought forward the possibility of having detected a particle's "internal clock", as an intrinsic oscillation with de Broglie's frequency. The transmission probability along a major axial…

Quantum Physics · Physics 2014-03-27 M. Bauer

Atomic vibrations control all thermally activated processes in materials including diffusion, heat transport, phase transformations, and surface chemistry. Recent developments in monochromated, aberration-corrected scanning transmission…

Materials Science · Physics 2020-01-08 Kartik Venkatraman , Barnaby D. A. Levin , Katia March , Peter Rez , Peter A. Crozier

By treating the electron-ion interaction as perturbation in the first-principles Hamiltonian, we have calculated the density response functions of a fluid alkali metal to find an interesting charge instability due to anomalous electronic…

Strongly Correlated Electrons · Physics 2009-11-13 H. Maebashi , Y. Takada

A time-dependent approach is used to explore inelastic effects during electron transport through few-level systems. We study a tight-binding chain with one and two sites connected to vibrations. This simple but transparent model gives…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 S. Monturet , N. Lorente

Sensitivity to temporal variation of the fundamental constants may be strongly enhanced in transitions between narrow close levels of different nature. This enhancement may be realized in a large number of molecules due to cancelation…

Atomic Physics · Physics 2008-11-26 V. V. Flambaum , M. G. Kozlov

Heat dissipation is ubiquitous in living systems, which constantly convert distinct forms of energy into each other. The transport of thermal energy in liquids and even within proteins is well understood but kinetic energy transfer across a…

Soft Condensed Matter · Physics 2026-01-07 Brandon Neff , Matthias Heyden

Molecular dynamics simulations have been performed to study frictional slip and its influence on energy dissipation and momentum transfer at atomically smooth solid/water interfaces. By modifying surface chemistry, we investigate the…

Fluid Dynamics · Physics 2016-08-08 Kai Huang , Izabela Szlufarska

Neutral quantum absorbers in optical lattices have emerged as a leading platform for achieving clocks with exquisite spectroscopic resolution. However, the studies of these clocks and their systematic shifts have so far been limited to…

Atomic Physics · Physics 2023-04-04 K. H. Leung , B. Iritani , E. Tiberi , I. Majewska , M. Borkowski , R. Moszynski , T. Zelevinsky