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This is a critical review of MAX-phase carbides and nitrides from an electronic-structure and chemical bonding perspective. This large group of nanolaminated materials is of great scientific and technological interest and exhibit a…

Materials Science · Physics 2016-12-15 Martin Magnuson , Maurizio Mattesini

The challenge of increasing copper (Cu) resistivity with diminishing Cu interconnect dimensions in complementary metal-oxide-semiconductor (CMOS) transistors, along with the imperative for efficient electron transport paths to fulfill…

MAX phases are a family of layered, hexagonal-structure ternary carbides or nitrides of a transitional metal and an A-group element. What makes this type of material fascinating and potentially useful is their remarkable combinations of…

Materials Science · Physics 2020-07-06 Yiming Zhang , Zeyu Mao , Qi Han , Youbing Li , Mian Li , Shiyu Du , Zhifang Chai , Qing Huang

The structural, elastic, electronic, thermal and optical properties of superconducting MAX phases Ti2InX (X = C, N) are investigated by density functional theory (DFT). The results obtained from the least studied nitride phase are discussed…

Superconductivity · Physics 2012-07-25 M. Roknuzzaman , A. K. M. A. Islam

The elemental diversity is crucial to screen out ternary MAX phases with outstanding properties via tuning of bonding types and strength between constitutive atoms. As a matter of fact, the interactions between M and A atoms largely…

MAX phases are nanolaminated ternary materials that combine metallic and ceramic properties. Currently, the A-site elements replacement in traditional ones by later transition-metals opens a door to explore new types of MAX phases. In this…

Materials Science · Physics 2021-11-25 Erxiao Wu , Yiming Zhang , Mian Li , Youbing Li , Kan Luo , Shiyu Du , Qing Huang

As interconnect dimensions continue to shrink, the industry-standard copper faces a critical increase in resistivity, presenting a significant hurdle to overall device performance. To overcome this limitation, this work investigates the…

Materials Science · Physics 2026-03-26 Gyungho Maeng , Subeen Lim , Bonggeun Shong , Yeonghun Lee

Titanium nitride halides, TiNX (X = F, Cl, Br, I) in the {\alpha}-phase (orthorhombic) are exciting quasi two-dimensional (2D) electronic systems exhibiting a fascinating series of electronic ground states under different conditions.…

Materials Science · Physics 2020-04-22 M. M. Hossain , S. H. Naqib

The charge transport properties of single superconducting tin nanowires, encapsulated by multiwalled carbon nanotubes have been investigated by multi-probe measurements. The multiwalled carbon nanotube protects the tin nanowire from…

Complex intermetallic materials known as MAX phases exhibit exceptional properties from both metals and ceramics, largely thanks to their nanolayered structure. With high-resolution scanning transmission electron microscopy supported by…

Materials Science · Physics 2023-03-17 Julien Guénolé , Vincent Taupin , Maxime Vallet , Wenbo Yu , Antoine Guitton

We present first-principles calculations of phase coherent electron transport in a carbon nanotube (CNT) with realistic contacts. We focus on the zero-bias response of open metallic CNT's considering two archetypal contact geometries (end…

Materials Science · Physics 2009-11-07 J. J. Palacios , A. J. Perez-Jimenez , E. Louis , E. SanFabian , J. A. Verges

Recent chemical exfoliation of layered MAX phase compounds to novel two-dimensional transition metal carbides and nitrides, so called MXenes, has brought new opportunity to materials science and technology. This review highlights the…

Materials Science · Physics 2017-05-09 Mohammad Khazaei , Ahmad Ranjbar , Masao Arai , Taizo Sasaki , Seiji Yunoki

The electronic properties of interfaces between two different solids can differ strikingly from those of the constituent materials. For instance, metallic conductivity, and even superconductivity, have been recently discovered at interfaces…

Materials Science · Physics 2009-11-13 H. Dias Alves , A. S. Molinari , H. Xie , A. F. Morpurgo

The sharp increase in resistivity of copper interconnects at ultra-scaled dimensions threatens the continued miniaturization of integrated circuits. Topological semimetals (TSMs) with gapless surface states (Fermi arcs) provide conduction…

Mesoscale and Nanoscale Physics · Physics 2026-02-27 Alexander C. Tyner , William Rogers , Po-Hsin Shih , Yi-Hsin Tu , Gengchiau Liang , Hsin Lin , Ching-Tzu Chen , James M. Rondinelli

We have investigated electrical transport in a diffusive multiwalled carbon nanotube contacted using superconducting leads made of Al/Ti sandwich structure. We find proximity-induced superconductivity with measured critical currents up to…

Superconductivity · Physics 2015-06-25 T. Tsuneta , L. Lechner , P. J. Hakonen

The structural, elastic and electronic properties of two-dimensional (2D) titanium carbide/nitride based pristine (Tin+1Cn/Tin+1Nn) and functionalized MXenes (Tin+1CnT2/Tin+1NnT2, T stands for the terminal groups: -F, -O and -OH, n = 1, 2,…

Materials Science · Physics 2018-07-06 Ning Zhang , Yu Hong , Sanaz Yazdanparast , Mohsen Asle Zaeem

The increasing resistance of Cu interconnects for decreasing dimensions is a major challenge in continued downscaling of integrated circuits beyond the 7-nm technology node as it leads to unacceptable signal delays and power consumption in…

Two-dimensional (2D) transition metal carbides and nitrides, known as MXenes, possess unique physical and chemical properties, enabling diverse applications in fields ranging from energy storage to communication, catalysis, sensing,…

The use of oxide glasses is pervasive throughout everyday amenities and commodities. Such glasses are typically electrical insulators, and endowing them with electrical conductivity without changing their salutary mechanical properties,…

MXenes are an emerging class of 2D materials of interest in applications ranging from energy storage to electromagnetic shielding. MXenes are synthesized by selective etching of layered bulk MAX phases into sheets of 2D MXenes. Their…

Materials Science · Physics 2023-07-27 Kat Nykiel , Alejandro Strachan
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