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Entropy concept was introduced by Clausius 160 years ago, and has been continually enriched, developed and interpreted by the researchers in many different scientific disciplines ever since. Thermodynamics and other scientific disciplines…

Chemical Physics · Physics 2017-11-21 Marko Popovic

Entropy is a quantity which is of great importance in physics and chemistry. The concept comes out of thermodynamics, proposed by Rudolf Clausius in his analysis of Carnot cycle and linked by Ludwig Boltzmann to the number of specific ways…

Popular Physics · Physics 2015-11-25 Amelia Carolina Sparavigna

In order to undestand how the complex concept of entropy emerged,we propose a trip towards the past reviewing the works of Clausius, Boltzmann, Gibbs and Planck. In particular, since the Gibbs's work is not very well known, we present a…

History and Philosophy of Physics · Physics 2015-06-11 L. Benguigui

The science of thermodynamics was put together in the Nineteenth Century to describe large systems in equilibrium. One part of thermodynamics defines entropy for equilibrium systems and demands an ever-increasing entropy for non-equilibrium…

Statistical Mechanics · Physics 2014-03-26 Leo P. Kadanoff

Meixner's historical remark in 1969 "... it can be shown that the concept of entropy in the absence of equilibrium is in fact not only questionable but that it cannot even be defined...." is investigated from today's insight. Several…

Statistical Mechanics · Physics 2018-10-17 Wolfgang Muschik

In his ninth memoir Clausius summarizes the two principles of thermodynamics as follows: "The whole mechanical theory of heat rests on two fundamental theorems: that of equivalence of heat and work, and that of equivalence of…

Statistical Mechanics · Physics 2023-06-08 Giovanni Jona-Lasinio

Partial differential equations are ubiquitous in almost all applications of mathematics, where they provide a natural mathematical description of many phenomena involving change in physical, chemical, biological, and social processes. The…

Analysis of PDEs · Mathematics 2013-11-07 John M. Ball , Gui-Qiang G. Chen

The microscopic explanation of entropy has been challenged from both experimental and theoretical point of view. The expression of entropy is derived from the first law of thermodynamics indicating that entropy or the second law of…

General Physics · Physics 2007-05-23 Jozsef Garai

Some general considerations on the notion of entropy in physics are presented. An attempt is made to clarify the question of the differentiation between physical entropy (the Clausius-Boltzmann one) and quantities called entropies…

Statistical Mechanics · Physics 2007-05-23 Roberto Luzzi , Áurea R. Vasconcellos , J. Galvão Ramos

Thermodynamics is commonly presented as a theory of macroscopic systems in stable equilibrium, built upon assumptions of extensivity and scaling with system size. In this paper, we present a universal formulation of the elementary…

Quantum Physics · Physics 2026-03-26 Gian Paolo Beretta

Entropy increase is fundamentally related to the breaking of time-reversal symmetry. By adding the 'extra dimension' associated with thermodynamic forces, we extend that discrete symmetry to a continuous symmetry for the dynamical…

Statistical Mechanics · Physics 2025-04-28 Aaron Beyen , Christian Maes

In a recent paper Andrei N. Soklakov explained the foundations of the Lagrangian formulation of classical particle mechanics by means of Kolmogorov complexity. In the present paper we use some of Soklakov ideas in order to derive the second…

Mathematical Physics · Physics 2007-05-23 Adonai S. Sant'Anna

Entropy can signify different things: For instance, heat transfer in thermodynamics or a measure of information in data analysis. Many entropies have been introduced and it can be difficult to ascertain their different importance and…

Mathematical Physics · Physics 2025-07-10 Henrik Jeldtoft Jensen , Piergiulio Tempesta

There are three ways to conceptualize entropy: entropy as an extensive thermodynamic quantity of physical systems (Clausius, Boltzmann, Gibbs), entropy as a measure for information production of ergodic sources (Shannon), and entropy as a…

Statistical Mechanics · Physics 2018-11-05 Stefan Thurner , Bernat Corominas-Murtra , Rudolf Hanel

Thermodynamic entropy, as defined by Clausius, characterizes macroscopic observations of a system based on phenomenological quantities such as temperature and heat. In contrast, information-theoretic entropy, introduced by Shannon, is a…

Quantum Physics · Physics 2017-01-04 Mirjam Weilenmann , Lea Krämer , Philippe Faist , Renato Renner

The principal methods for the definition of thermodynamic entropy are discussed with special reference to those developed by Carath\'eodory, the Keenan School, Lieb and Yngvason, and the present authors. An improvement of the latter method…

Mathematical Physics · Physics 2014-03-25 Enzo Zanchini , Gian Paolo Beretta

The aim of this work is to analyze the entropy, entropy flux and entropy supply rate of granular fluids within the frameworks of the Boltzmann equation and continuum thermodynamics. It is shown that the entropy inequality for a granular gas…

Statistical Mechanics · Physics 2010-11-17 Gilberto M. Kremer

Since its origin in the thermodynamics of the 19th century, the concept of entropy has also permeated other fields of physics and mathematics, such as Classical and Quantum Statistical Mechanics, Information Theory, Probability Theory,…

Machine Learning · Statistics 2025-03-06 Salomé A. Sepúveda Fontaine , José M. Amigó

Here we deconstruct, and then in a reasoned way reconstruct, the concept of "entropy of a system," paying particular attention to where the randomness may be coming from. We start with the core concept of entropy as a COUNT associated with…

General Physics · Physics 2017-05-10 Tommaso Toffoli

Thermodynamic entropy is determined by a heat measurement through the Clausius equality. The entropy then formalizes a fundamental limitation of operations by the second law of thermodynamics. The entropy is also expressed as the Shannon…

Statistical Mechanics · Physics 2015-06-17 Shin-ichi Sasa
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