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This article is a short version of a longer article to appear in Physics Reports (cond-mat/9708200). The essential postulates of classical thermodynamics are formulated, from which the second law is deduced as the principle of increase of…

Mathematical Physics · Physics 2007-05-23 Elliott H. Lieb , Jakob Yngvason

Interpolation inequalities play an essential role in Analysis with fundamental consequences in Mathematical Physics, Nonlinear Partial Differential Equations (PDEs), Markov Processes, etc., and have a wide range of applications in various…

Analysis of PDEs · Mathematics 2021-10-19 Jean Dolbeault

We derive the law of entropy non-decrease directly from the Kelvin-Planck principle for simple and compound systems without using the Clausius inequality. A key of the derivation is a new formulation of entropy in terms of work by a Carnot…

Statistical Mechanics · Physics 2025-10-21 Yuki Izumida

Boltzmann's struggle with a derivation of the Second Law of Thermodynamics is sketched. So is his first derivation of the connection between entropy and probability in 1877. Planck's derivation and quantum mechanical modifications of…

History and Philosophy of Physics · Physics 2008-07-11 E. G. D. Cohen

The universal validity of the second law of thermodynamics is widely attributed to a finely tuned initial condition of the universe. This creates a problem: why is the universe atypical? We suggest that the problem is an artefact created by…

General Relativity and Quantum Cosmology · Physics 2015-07-27 Julian Barbour , Tim Koslowski , Flavio Mercati

In our recent letter [1] we discussed that thermodynamics is violated in quantum Brownian motion beyond the weak coupling limit. In his comment, Tasaki [2] derives an inequality for the relative entropy and claims, without making any…

Statistical Mechanics · Physics 2007-05-23 A. E. Allahverdyan , Th. M. Nieuwenhuizen

Entropy has emerged as a dynamic, interdisciplinary, and widely accepted quantitative measure of uncertainty across different disciplines. A unified understanding of entropy measures, supported by a detailed review of their theoretical…

Probability · Mathematics 2025-03-21 Naveen Kumar , Ambesh Dixit , Vivek Vijay

The physical foundations of a variety of emerging technologies --- ranging from the applications of quantum entanglement in quantum information to the applications of nonequilibrium bulk and interface phenomena in microfluidics, biology,…

Quantum Physics · Physics 2014-03-25 Gian Paolo Beretta , Enzo Zanchini

We generalize, improve and unify theorems of Rumin, and Maassen--Uffink about classical entropies associated to quantum density matrices. These theorems refer to the classical entropies of the diagonals of a density matrix in two different…

Mathematical Physics · Physics 2015-05-30 Rupert L. Frank , Elliott H. Lieb

This is a review on entropy in various fields of mathematics and science. Its scope is to convey a unified vision of the classical as well as some newer entropy notions to a broad audience with an intermediate background in dynamical…

Dynamical Systems · Mathematics 2022-02-08 José M. Amigó , Karsten Keller , Valentina Unakafova

Thermodynamics allows the application of Statistical Mechanics to finite and even small systems. As surface effects cannot be scaled away, one has to be careful with the standard arguments of splitting a system into two or bringing two…

Statistical Mechanics · Physics 2007-05-23 D. H. E. Gross

A new notion of partition-determined functions is introduced, and several basic inequalities are developed for the entropy of such functions of independent random variables, as well as for cardinalities of compound sets obtained using these…

Information Theory · Computer Science 2012-06-05 Mokshay Madiman , Adam Marcus , Prasad Tetali

Based on the property of extensivity (mathematically, homogeneity of first degree), we derive in a mathematically consistent manner the explicit expressions of the chemical potential $\mu$ and the Clausius entropy $S$ for the case of…

Statistical Mechanics · Physics 2013-01-15 Thomas Oikonomou , G. Baris Bagci

This paper is an introduction to the von Neumann entropy in a historic approach. Von Neumann's gedanken experiment is repeated, which led him to the formula of thermodynamic entropy of a statistical operator. In the analysis of his ideas we…

Mathematical Physics · Physics 2007-05-23 D. Petz

It is proved here that, as a consequence of the unitary quantum evolution, the expectation value of a properly defined quantum entropy operator (as opposed to the non-evolving von Neumann entropy) can only increase during non adiabatic…

Quantum Physics · Physics 2008-11-25 Michele Campisi

The notion of group entropy is proposed. It enables to unify and generalize many different definitions of entropy known in the literature, as those of Boltzmann-Gibbs, Tsallis, Abe and Kaniadakis. Other new entropic functionals are…

Statistical Mechanics · Physics 2015-05-28 Piergiulio Tempesta

Motivated by the notion that the mathematics of gravity can be reproduced from a statistical requirement of maximal entropy, we study the consequence of introducing an entropic source term in the Einstein-Hilbert action. For a spatially…

General Relativity and Quantum Cosmology · Physics 2024-03-20 Soumya Chakrabarti

We use the distances introduced in a previous joint paper to exhibit the gradient flow structure of some drift-diffusion equations for a wide class of entropy functionals. Functional inequalities obtained by the comparison of the entropy…

Analysis of PDEs · Mathematics 2012-12-06 Jean Dolbeault , Bruno Nazaret , Giuseppe Savaré

In this paper we propose the use of concepts from thermodynamics in the study of crowd dynamics. Our continuous model consists of the continuity equation for the density of the crowd and a kinetic equation for the velocity field. The latter…

Analysis of PDEs · Mathematics 2013-05-15 Joep Evers , Adrian Muntean , Fons van de Ven

In classical Hamiltonian theories, entropy may be understood either as a statistical property of canonical systems, or as a mechanical property, that is, as a monotonic function of the phase space along trajectories. In classical mechanics,…

General Relativity and Quantum Cosmology · Physics 2016-10-14 Marius Oltean , Luca Bonetti , Alessandro D. A. M. Spallicci , Carlos F. Sopuerta