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Modelling electrolytes accurately on both a nanoscale and cell level can contribute to improving battery chemistries.[Armand and Tarascon, Nature, 2008, 451, 652-657] We previously presented a thermodynamic continuum model for…

Chemical Physics · Physics 2024-08-09 Constantin Schwetlick , Max Schammer , Arnulf Latz , Birger Horstmann

We systematically evaluate the prospects of a novel 2D nanomaterial, phosphorene, as anode for Na-ion batteries. Using first-principles calculations, we determine the Na adsorption energy, specific capacity and Na diffusion barriers on…

Materials Science · Physics 2015-06-24 Vadym V. Kulish , Oleksandr I. Malyi , Clas Persson , Ping Wu

In recent years, the mixed phosphates based polyanionic electrode materials have attracted great attention in sodium-ion batteries due to their structural stability during cycling and open framework for ion diffusion. Here, we report the…

Applied Physics · Physics 2021-07-21 Pravin K. Dwivedi , Simranjot K. Sapra , Jayashree Pati , Rajendra S. Dhaka

We present a novel tin based flexible, gel polymer negative electrode for use in sodium-ion devices. The electrodes have been prepared by trapping tin micro-particles in a porous electrolyte membrane formed by immersion precipitation…

Materials Science · Physics 2022-01-25 Nitish Yadav , S. A. Hashmi

A swift chemical route to synthesize Co-doped SnO$_2$ nanopowders is described. Pure and highly stable Sn$_{1-x}$Co$_x$O$_{2-\delta}$ (0 $\le$ x $\le$ 0.15) crystalline nanoparticles were synthesized, with mean grain sizes < 5 nm and the…

Materials Science · Physics 2015-03-31 T. Entradas , J. Cabrita , S. Dalui , M. R. Nunes , O. C. Monteiro , A. J. Silvestre

Here we discuss two alternative approaches for building flexible batteries for applications in smart textiles. The first approach uses well-studied inorganic electrochemistry (Al-NaOCl galvanic cell) and innovative packaging in order to…

An approach is presented to modify the WF of solution-processed sol-gel derived ZnOover an exceptionally wide range of more than 2.3 eV. This approach relies on the formation of dense and homogeneous self-assembled monolayers based on…

The Li-Air battery is a very promising candidate for powering future mobility, but finding a suitable electrolyte solvent for this technology turned out to be a major problem. We present a systematic computational investigation of the known…

Chemical Physics · Physics 2015-10-28 Tamara Husch , Martin Korth

This manuscript explores recent advancements in solid-state sodium-based battery technology, particularly focusing on electrochemical performance and the challenges associated with developing efficient solid electrolytes. The replacement of…

All solid state batteries are claimed to be the next-generation battery system, in view of their safety accompanied by high energy densities. A new advanced, multiscale compatible, and fully three dimensional model for solid electrolytes is…

Applied Physics · Physics 2022-03-15 L. Cabras , D. Danilov , W. Subber , V. Oancea , A. Salvadori

In search of the potential cathode materials for sodium-ion batteries and to understand the diffusion kinetics, we report the detailed analysis of electrochemical investigation of honeycomb structured Na$_{2}$Ni$_{2}$TeO$_{6}$ material…

Chemical Physics · Physics 2021-12-02 Jayashree Pati , Hari Raj , Simranjot K. Sapra , Anita Dhaka , A. K. Bera , S. M. Yusuf , R. S. Dhaka

This work reports a simple, novel, cost effective and eco-friendly electrolytic synthesis of silver nanoparticles using AgNO3 as metal precursor. The synthesis rate is much faster than other methods and this approach is suitable for large…

General Physics · Physics 2011-11-02 T. Theivasanthi , M. Alagar

La$_2$NiO$_4$ is a very promising cathode material for intermediate and low temperature solid oxide cell applications, due to its good electronic and ionic conductivity, together with its high oxygen exchange activity with a low activation…

Li-O$_2$ batteries (LOB) performance degradation ultimately occurs through the accumulation of discharge products and irreversible clogging of the porous electrode during the cycling. Electrode binder degradation in the presence of reduced…

MoO2/C-composites have been fabricated for the first time by a tartaric acid/glucose-assisted sol-gel method with post-annealing at 500 {\deg}C for 1 h in N2 flow. The synthesized materials were fully characterized with respect to…

Materials Science · Physics 2020-12-11 G. S. Zakharova , L. Singer , Z. A. Fattakhova , S. Wegener , E. Thauer , Q. Zhu , E. V. Shalaeva , R. Klingeler

Sodium ion batteries become popular due to their low cost. Among possible anode materials of sodium ion batteries, phosphorus has great potential owing to its high theoretical capacity. Previous research that yielded high capacity and long…

Applied Physics · Physics 2021-08-20 Changyu Deng , Wei Lu

Lithium iron phosphate (LiFePO$_4$) is the prototypical two-phase battery material, whose complex patterns of lithium ion intercalation provide a testing ground for theories of electrochemical thermodynamics. Using a depth-averaged (a-b…

Chemical Physics · Physics 2018-08-21 Daniel A. Cogswell , Martin Z. Bazant

The present study describes a facile route of zinc oxide (ZnO) grows using the solution-dependent electrostatic spray deposition (ESD) method at temperatures ranging from 300 {\deg}C - 500 {\deg}C. In this work, zinc chloride (ZnCl2) was…

Materials Science · Physics 2024-06-21 Fysol Ibna Abbas , Mutsumi Sugiyama

Tin monoxide (SnO) is a p-type oxide semiconductor whose electronic properties can be widely modified via atomic-scale engineering. Using density functional theory, we investigate the electronic and magnetic properties of transition-metal…

Materials Science · Physics 2026-05-26 Yuya Fukuta , Souren Adhikary , Kazuhito Tsukagoshi , Katsunori Wakabayashi

High oxidation potential indicates anodes have high oxidation power and high current efficiency for organics oxidation. In this paper, we prepared Ti/Cu-SnO2 anodes using spray pyrolysis method. The Ti/Cu-SnO2 anodes have an ultra-high…

Materials Science · Physics 2016-06-22 Aqing Chen , Xudong Zhu Junhua Xi , Haiying Qin , Zhenguo Ji