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Silicon offers great promise as a potential anode active material and the optimum alternative to lithium metal in all-solid-state lithium-ion batteries. However, its practical application is limited by severe volume expansion (~300%) during…

Oxidative decomposition of organic-solvent-based liquid electrolytes at cathode material interfaces has been identified as a main reason for rapid capacity fade in high-voltage lithium ion batteries. The evolution of "cathode electrolyte…

Materials Science · Physics 2020-03-10 Kevin Leung , Rosy , Malachi Noked

Sodium-titanate \ce{Na2Ti3O7} (NTO) is regarded as a highly promising anode material with a very low voltage for Na-ion batteries and capacitors, but suffered from relatively low specific capacity and poor electron conductivity. Here we…

Materials Science · Physics 2020-06-19 Chol-Jun Yu , Suk-Gyong Hwang , Yong-Chol Pak , Song-Hyok Choe , Jin-Song Kim , Kum-Chol Ri

Developing efficient anode materials with low electrode voltage, high specific capacity and superior rate capability is urgently required on the road to commercially viable sodium-ion batteries (SIBs). Aiming at finding a new SIB anode…

Materials Science · Physics 2019-07-16 Song-Hyok Choe , Chol-Jun Yu , Kum-Chol Ri , Jin-Song Kim , Un-Gi Jong , Yun-Hyok Kye , Song-Nam Hong

The electrochemical deposition of ZnO hierarchical nanostructures directly from PHEMA hydrogel coated electrodes has been successfully demonstrated. A variety of hierarchical ZnO nanostructures, including porous nanoflakes, nanosheets and…

Materials Science · Physics 2013-02-20 Shuxi Dai , Yinyong Li , Zuliang Du , Kenneth R. Carter

All-solid-state batteries (ASSBs) offer a promising route to safer batteries with superior energy density compared to conventional Li-ion batteries (LIBs). However, the design of the composite cathode and optimization of the underlying…

Sodium-ion batteries (SIBs) have received significant attention as promising alternative for energy storage applications owing to the large availability and low cost of sodium. In this paper we study the electrochemical behavior of…

Chemical Physics · Physics 2020-12-02 Jayashree Pati , Mahesh Chandra , Rajendra S. Dhaka

Two-dimensional (2D) materials as electrodes is believed to be the trend for future Li-ion and Na-ion batteries technologies. Here, by using first-principles methods, we predict that the recently reported borophene (2D born sheet) can serve…

Mesoscale and Nanoscale Physics · Physics 2016-10-19 Xiaoming Zhang , Junping Hu , Yingchun Cheng , Hui Ying Yang , Yugui Yao , Shengyuan A. Yang

The technology of silicon anodes appears to be reaching maturity, with high-energy Si cells already in pilot-scale production. However, the performance of these systems can be difficult to replicate in academic settings, making it…

We report a comprehensive study on the electrochemical performance of four different Transition Metal Oxides encapsulated inside carbon nanotubes (CNT). Irrespective of the type of oxide-encapsulate, all these samples exhibit superior…

Hard carbons show significant promise as anode materials for sodium-ion batteries. However, monitoring the sodiation process in the hard carbon electrode during cycling and understanding the sodiation mechanism remain challenging. This…

We report the electrochemical performance of nanostructures of Na$_{0.66}$V$_4$O$_{10}$ as cathode material for rechargeable batteries. The Rietveld refinement of room temperature x-ray diffraction pattern shows the monoclinic phase with…

An important objective of designing lithium-ion rechargeable battery cells is to maximize their rate performance without compromising the energy density, which is mainly achieved through computationally expensive numerical simulations at…

Materials Science · Physics 2020-05-05 Fan Wang , Ming Tang

Understanding the mechanical interplay between silicon anodes and their surrounding solid-electrolyte interphase (SEI) is essential to improve the next generation of lithium-ion batteries. We model and simulate a 2D elliptical silicon…

Applied Physics · Physics 2024-09-13 Raphael Schoof , Lukas Köbbing , Arnulf Latz , Birger Horstmann , Willy Dörfler

We prepared Na$_x$TO$_2$ (T = Mn, Co) nanostructures to use as cathode material in Na-ion batteries. The Rietveld refinement of x-ray diffraction data confirms the hexagonal symmetry. Scanning and transmission electron microscopy…

Materials Science · Physics 2018-06-06 Mahesh Chandra , Rishabh Shukla , Muhammad Rashid , Amit Gupta , Suddhasatwa Basu , R. S. Dhaka

We report the electrochemical performance and diffusion kinetics of a newly designed NASICON type Na$_{3.3}$Mn$_{1.2}$Ti$_{0.75}$Mo$_{0.05}$(PO$_4$)$_3$/C composite material as a cathode for cost-effective sodium-ion batteries. A novel…

Chemical Physics · Physics 2025-10-01 Madhav Sharma , Rajendra S. Dhaka

Enabling lithium (Li)-ion batteries with higher energy densities, longer cycle life, and lower costs will underpin the widespread electrification of the transportation and large-scale energy storage industries. Nickel (Ni)-rich layered…

Mechanical degradation in electrode materials during successive electrochemical cycling is critical for battery lifetime and aging properties. A common strategy to mitigate electrode mechanical degradation is to suppress the volume…

Materials Science · Physics 2024-06-10 Maxime Maréchal , Romain Berthelot , Patrick Rozier , Matthieu Saubanère

In recent years there has been a major interest in developing all solid state batteries, for the sake of safety (issues due to toxic and flammable organic liquid electrolytes are well known) as well as of high energy density…

Materials Science · Physics 2021-05-07 L. Cabras , V. Oancea , A. Salvadori

We report the observation of a two-dimensional electron system (2DES) at the $(110)$ surface of the transparent bulk insulator SnO$_2$, and the tunability of its carrier density by means of temperature or Eu deposition. The 2DES is…

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