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Density functional theory (DFT) embedding provides a formally exact framework for interfacing correlated wave-function theory (WFT) methods with lower-level descriptions of electronic structure. Here, we report techniques to improve the…

Chemical Physics · Physics 2015-06-12 Jason D. Goodpaster , Taylor A. Barnes , Frederick R. Manby , Thomas F. Miller

Adsorbed transition metal atoms can have partially filled $d$- or $f$-shells due to strong on-site Coulomb interaction. Capturing all effects originating from electron correlation in such strongly correlated systems is a challenge for…

Strongly Correlated Electrons · Physics 2018-01-17 Marc Philipp Bahlke , Michael Karolak , Carmen Herrmann

Electron-ion interactions play a central role for the energy relaxation processes and ultra-fast structure dynamics in laser-heated matter. The accurate prediction of the electron-ion energy exchange in a transient excited two-temperature…

Other Condensed Matter · Physics 2024-01-17 Jia Zhang , Rui Qin , Wenjun Zhu , Jan Vorberger

Fundamental understanding of interatomic forces in molecules must emerge from quantum mechanics, yet widely used empirical force fields rely on simplified mechanistic approximations that often fail to capture the complexity of many-body…

We consider quasi-two-dimensional gas of electrons in a typical Si-MOSFET, assuming repulsive contact interaction between electrons. Magnetisation and susceptibility are evaluated within the mean-field approach. Finite thickness of the…

Mesoscale and Nanoscale Physics · Physics 2017-06-28 D. I. Golosov

Multireference density functional theory (MR-DFT) has been a pivotal method for studying nuclear low-lying states and neutrinoless double-beta ($0\nu\beta\beta$) decay. However, quantifying their theoretical uncertainties has been a…

Nuclear Theory · Physics 2025-08-26 X. Zhang , C. C. Wang , C. R. Ding , J. M. Yao

Within the DWBA framework, we develop a theoretical description of single and double heavy ion charge exchange (CE) reactions. We show that absorption effects are particularly important for heavy ion reactions, leading to a noticeable…

Nuclear Theory · Physics 2019-03-14 M. Colonna , J. I. Bellone , S. Burrello , J-A Lay , H. Lenske

Exact (Hartree Fock) exchange is needed to overcome some of the limitations of local and semilocal approximations of density functional theory (DFT). So far, however, computational cost has limited the use of exact exchange in plane wave…

Strongly Correlated Electrons · Physics 2009-11-13 Xifan Wu , Annabella Selloni , Roberto Car

A new density functional theory (DFT) exchange-correlation functional for the exploration of reaction mechanisms is proposed. This new functional, denoted BMK (Boese-Martin for Kinetics), has an accuracy in the 2 kcal/mol range for…

Chemical Physics · Physics 2007-05-23 A. Daniel Boese , Jan M. L. Martin

The work reports nonmagnetic behavior (0.04 $\mu$B) in two-dimensional (2D) V2C-OF MXene and ferromagnetism in MnO$_2$ adsorbed V2C-OF MXene. The density functional theory (DFT) calculations were carried out to study the magnetic moments of…

Mesoscale and Nanoscale Physics · Physics 2025-05-06 Mahjabeen Fatima , Saleem Ayaz Khan , Syed Rizwan

Using density functional theory (DFT), we calculate the magnetic short-ranged exchange forces between a magnetic tip and an adatom adsorbed on the antiferromagnetic Mn monolayer on the W(110) surface [Mn/W(110)]. These exchange forces can…

Materials Science · Physics 2024-07-17 Soumyajyoti Haldar , Stefan Heinze

We have developed a theoretical method to study scattering processes of an incident electron through an N-electron quantum dot (QD) embedded in a two-dimensional (2D) semiconductor. The generalized Lippmann-Schwinger equations including the…

Other Condensed Matter · Physics 2007-11-19 L. K. Castelano , G. -Q. Hai , M. -T. Lee

A treatment of many-electron polar and $s-d(f)$ exchange models is carried out in connection with the development of the theory of magnetism of transition and rare-earth metals, as well as their compounds. Particular emphasis is placed on…

Strongly Correlated Electrons · Physics 2021-02-18 Valentin Yu. Irkhin

We introduce DeepDFT, a deep learning model for predicting the electronic charge density around atoms, the fundamental variable in electronic structure simulations from which all ground state properties can be calculated. The model is…

Computational Physics · Physics 2020-11-09 Peter Bjørn Jørgensen , Arghya Bhowmik

The interaction between excited states of a closed-shell chromophore and a nearby free radical species gives rise to spin-coupled doublet states, namely singdoublet and tripdoublet, as well as a quartet state. This coupling facilitates…

Chemical Physics · Physics 2025-03-25 Chenyu Liu , Yang Xu , Peng Bao , Yangyi Lu , Jiali Gao

We introduce a theoretical framework for computaions of anisotropic multipolar exchange interactions found in many spin--orbit coupled magnetic systems and propose a method to extract these coupling constants using a density functional…

Strongly Correlated Electrons · Physics 2014-08-01 Shu-Ting Pi , Ravindra Nanguneri , Sergey Savrasov

Correlated materials with open-shell d- and f-ions having degenerate band edge states show a rich variety of interesting properties ranging from metal-insulator transition to unconventional superconductivity. The textbook view for the…

Strongly Correlated Electrons · Physics 2020-07-15 Yubo Zhang , James Furnes , Ruiqi Zhang , Zhi Wang , Alex Zunger , Jianwei Sun

Density functional theory (DFT) remains the most widely used electronic structure method. Although exact in principle, in practice, it relies on approximations to the exchange-correlation (XC) functional, which is known to be a unique…

Computational Physics · Physics 2025-10-14 Vishal Subramanian , Bikash Kanungo , Vikram Gavini

A dense form of matter is formed in relativistic heavy ion collisions. The constituent degrees of freedom in this dense matter are currently unknown. Long-range, forward-backward multiplicity correlations (LRC) are expected to arise due to…

Nuclear Experiment · Physics 2012-11-07 Terence J. Tarnowsky

In this paper, we systematically investigate the general dark matter-electron interactions within the framework of effective field theories (EFT). We consider both the non-relativistic (NR) EFT and the relativistic EFT descriptions of the…

High Energy Physics - Phenomenology · Physics 2024-07-23 Jin-Han Liang , Yi Liao , Xiao-Dong Ma , Hao-Lin Wang