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Kohn-Sham Density Functional Theory (KS-DFT) provides the exact ground state energy and electron density of a molecule, contingent on the as-yet-unknown universal exchange-correlation (XC) functional. Recent research has demonstrated that…

We calculate Heisenberg-type magnetic exchange interactions for SrMnO$_3$ under isotropic volume expansion using an approach that is based on total energy variations due to infinitesimal spin rotations around a given reference state. Our…

Materials Science · Physics 2020-02-12 Xiangzhou Zhu , Alexander Edström , Claude Ederer

We study the spin-crossover molecule Fe(phen)$_2$(NCS)$_2$ using density functional theory (DFT) plus dynamical mean-field theory, which allows access to observables not attainable with traditional quantum chemical or electronic structure…

Materials Science · Physics 2015-06-30 Jia Chen , Andrew Millis , Chris Marianetti

Charge transfer plays a crucial role in many processes of interest in physics, chemistry, and bio-chemistry. In many applications the size of the systems involved calls for time-dependent density functional theory (TDDFT) to be used in…

Chemical Physics · Physics 2017-10-11 Neepa T. Maitra

Density functional theory (DFT) is one of the most widely used tools to solve the many-body Schrodinger equation. The core uncertainty inside DFT theory is the exchange-correlation (XC) functional, the exact form of which is still unknown.…

Computational Physics · Physics 2019-10-15 Alexander Ryabov , Iskander Akhatov , Petr Zhilyaev

The Hohenberg-Kohn theorem of density functional theory (DFT) for the case of electrons interacting with an external magnetic field (that couples to spin only) is examined in more detail than previously. A unexpected generalization is…

Strongly Correlated Electrons · Physics 2009-10-31 H. Eschrig , W. E. Pickett

We present a method which uses density functional theory (DFT) to treat transport through a single molecule connected to two conducting leads for the weak and intermediate coupling. This case is not accessible to standard non-equilibrium…

Mesoscale and Nanoscale Physics · Physics 2011-01-21 Fatemeh Mirjani , Joseph M. Thijssen

To understand spin interactions in materials of the Cu$_2$Sb structure type, inelastic neutron scattering of Fe$_2$As single crystals was examined at different temperatures and incident neutron energies. The experimental phonon spectra…

We introduce the formalism to describe heavy-ion Double-Charge-Exchange (DCE) processes in the eikonal approximation. We focus on the low-momentum-transfer limit -- corresponding to the differential cross section at $\theta=0^\circ$ -- and,…

Nuclear Theory · Physics 2018-12-12 E. Santopinto , H. García-Tecocoatzi , R. I. Magaña-Vsevolodovna , J. Ferretti

We present a density functional theory (DFT) for lattice models with local electron-electron (e-e) and electron-phonon (e-ph) interactions. Exchange-correlation potentials are derived via dynamical mean field theory for the…

Strongly Correlated Electrons · Physics 2019-09-04 E. Viñas Boström , P. Helmer , P. Werner , C. Verdozzi

A microscopic model of indirect exchange interaction between transition metal impurities in dilute magnetic semiconductors (DMS) is proposed. The hybridization of the impurity d-electrons with the heavy hole band states is largely…

Strongly Correlated Electrons · Physics 2009-11-10 P. M. Krstajic , F. M. Peeters , V. A. Ivanov , V. Fleurov , K. Kikoin

This a review article, which presents a general framework for the analysis of interatomic magnetic interactions in the spin-density-functional theory, which is based on the magnetic force theorem, make a link with the models for…

Materials Science · Physics 2007-05-23 I. V. Solovyev

A versatile method for combining density functional theory (DFT) in the local density approximation (LDA) with dynamical mean-field theory (DMFT) is presented. Starting from a general basis-independent formulation, we use Wannier functions…

Strongly Correlated Electrons · Physics 2009-11-11 F. Lechermann , A. Georges , A. Poteryaev , S. Biermann , M. Posternak , A. Yamasaki , O. K. Andersen

The magnetic ground state of FeRh is highly sensitive towards the lattice constant. This, in addition to partially filled d-shells of Fe and Rh, posed a significant challenge for Density Functional Theory (DFT) calculations in the past.…

Materials Science · Physics 2024-01-24 Shishir Kumar Pandey , Saikat Debnath , Zhanghao Zhouyina , Qiangqiang Gu

We investigate abilities of various linear response based techniques for extracting parameters of antisymmetric Dzyaloshinskii-Moriya (DM) interactions from the first-principles electronic structure calculations. For these purposes, we…

Materials Science · Physics 2023-03-02 I. V. Solovyev

Quantum rings can be characterized by a specific radius and ring width. For this rich class of physical systems, an accurate approximation for the exchange-hole potential and thus for the exchange energy is derived from first principles.…

Strongly Correlated Electrons · Physics 2009-02-04 E. Rasanen , S. Pittalis , C. R. Proetto , E. K. U. Gross

High-throughput computational screening has emerged as a critical component of materials discovery. Direct density functional theory (DFT) simulation of inorganic materials and molecular transition metal complexes is often used to describe…

Materials Science · Physics 2017-05-18 Jon Paul Janet , Heather J. Kulik

Energy functionals serve as the basis for different models and methods in quantum and classical many-particle physics. Arguably, one of the most successful and widely used approaches in material science at both ambient and extreme…

Plasma Physics · Physics 2024-10-22 Z. Moldabekov , J. Vorberger , T. Dornheim

Empirical energy density functionals (EDFs) are generally successful in describing nuclear properties across the table of nuclides. But their limitations motivate using the density-matrix expansion (DME) to embed long-range pion…

Nuclear Theory · Physics 2021-02-08 L. Zurek , E. A. Coello Pérez , S. K. Bogner , R. J. Furnstahl , A. Schwenk

We have performed a thorough computational study to assess the accuracy of density functional theory (DFT) methods in describing the interactions of CO2 with model alkali-earth-metal (AEM, Ca and Li) decorated carbon structures, namely…

Materials Science · Physics 2013-01-15 Claudio Cazorla , Stephen A. Shevlin