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As a first step to meet the challenge to calculate the electronic structure and total energy of charged states of atoms and molecules adsorbed on ultrathin-insulating films supported by a metallic substrate using density functional theory…

Materials Science · Physics 2013-11-01 Iván Scivetti , Mats Persson

Mapping the magnetic exchange interactions from model Hamiltonian to density functional theory is a crucial step in multi-scale modeling calculations. Considering the usual magnetic force theorem but with arbitrary rotational angles of the…

Materials Science · Physics 2010-11-23 Samir Lounis , Peter H. Dederichs

The systematic underestimation of band gaps is one of the most fundamental challenges in semilocal density functional theory (DFT). In addition to hindering the application of DFT to predicting electronic properties, the band gap problem is…

Chemical Physics · Physics 2024-08-27 Kyle Bystrom , Stefano Falletta , Boris Kozinsky

Nanoscale optoelectronics and molecular-electronics systems operate with current injection and nonequilibrium tunneling, phenomena that challenge consistent descriptions of the steady-state transport. The current affects the…

Other Condensed Matter · Physics 2009-11-13 Per Hyldgaard

Nucleon exchange mechanism is investigated in the central collisions of ${}^{40}$Ca + ${}^{238}$U and ${}^{48}$Ca + ${}^{238}$U systems near the quasi-fission regime in the framework of the Stochastic Mean-Field (SMF) approach. Sufficiently…

Nuclear Theory · Physics 2016-01-12 S. Ayik , B. Yilmaz , O. Yilmaz

For translationally invariant one-band lattice models, we exploit the ab initio knowledge of the natural orbitals to simplify reduced density matrix functional theory (RDMFT). Striking underlying features are discovered: First, within each…

Quantum Physics · Physics 2019-01-08 Christian Schilling , Rolf Schilling

We present temperature-dependent atomic and magnetic pair distribution function (PDF) analysis of neutron total scattering measurements of antiferromagnetic MnO, an archetypal strongly correlated transition-metal oxide. The known…

Density functional theory (DFT) is shown to provide a novel conceptual and computational framework for entanglement in interacting many-body quantum systems. DFT can, in particular, shed light on the intriguing relationship between quantum…

Quantum Physics · Physics 2009-11-11 L. -A. Wu , M. S. Sarandy , D. A. Lidar , L. J. Sham

We analyze possible ways to calculate magnetic exchange interactions within the density functional theory plus dynamical mean-field theory (DFT+DMFT) approach in the paramagnetic phase. Using the susceptibilities obtained within the ladder…

Strongly Correlated Electrons · Physics 2023-06-09 A. A. Katanin , A. S. Belozerov , A. I. Lichtenstein , M. I. Katsnelson

The theory of heavy ion double charge exchange (DCE) reactions $A(Z,N)\to A(Z\pm 2,N\mp 2)$ is recapitulated emphasizing the role of Double Single Charge Exchange (DSCE) and pion-nucleon Majorana DCE (MDCE) reactions. DSCE reactions are of…

Nuclear Theory · Physics 2024-05-09 Horst Lenske , Jessica Bellone , Maria Colonna , Danilo Gambacurta , Jose-Antonio Lay

Density Functional Theory (DFT) is one of the most widely used methods for "ab initio" calculations of the structure of atoms, molecules, crystals, surfaces, and their interactions. Unfortunately, the customary introduction to DFT is often…

Physics Education · Physics 2010-12-07 Nathan Argaman , Guy Makov

In this paper we present an accurate numerical scheme for extracting inter-atomic exchange parameters ($J_{ij}$) of strongly correlated systems, based on first-principles full-potential electronic structure theory. The electronic structure…

Strongly Correlated Electrons · Physics 2015-03-11 Y. O. Kvashnin , O. Grånäs , I. Di Marco , M. I. Katsnelson , A. I. Lichtenstein , O. Eriksson

In the past two decades, many research groups worldwide have tried to understand and categorize simple regimes in the charge transfer of such biological systems as DNA. Theoretically speaking, the lack of exact theories for electron-nuclear…

Chemical Physics · Physics 2014-05-06 Pablo Ramos , Michele Pavanello

Improving the accuracy and thus broadening the applicability of electronic density functional theory (DFT) is crucial to many research areas, from material science, to theoretical chemistry, biophysics and biochemistry. In the last three…

Strongly Correlated Electrons · Physics 2019-03-27 Paola Gori-Giorgi , Michael Seidl

We investigate charge transfer in prototypical molecular donor-acceptor compounds using hybrid density functional theory (DFT) and the GW approximation at the perturbative level (G0W0) and at full self-consistency (sc-GW). For the systems…

Materials Science · Physics 2014-09-23 Fabio Caruso , Viktor Atalla , Xinguo Ren , Angel Rubio , Matthias Scheffler , Patrick Rinke

To date, density functional theory (DFT) is one of the most accurate and yet practical theory to gain insight about materials properties. Although successful, the computational cost is the main hurdle even today. A way out is combining DFT…

Materials Science · Physics 2019-04-19 Shweta Mehta , Sheena Agarwal , Kavita Joshi

Subsystem Density-Functional Theory (DFT) is an emerging technique for calculating the electronic structure of complex molecular and condensed phase systems. In this topical review, we focus on some recent advances in this field related to…

Chemical Physics · Physics 2015-06-24 Alisa Krishtal , Debalina Sinha , Alessandro Genova , Michele Pavanello

In this study, we use Hubbard-Corrected density functional theory (DFT+$U$) to derive spin model Hamiltonians consisting of Heisenberg exchange interactions up to the fourth nearest neighbors and bi-quadratic interactions. We map the…

Materials Science · Physics 2023-05-03 Mojtaba Alaei , Homa Karimi

A well-known connection between the magnetic susceptibility and the effective exchange parameter is analyzed. It is shown that all current computational schemes use a long-wave approximation which is suitable only for localized moments…

Strongly Correlated Electrons · Physics 2009-11-07 V. P. Antropov

Magnetite has attracted increasing attention in recent years due to its promising and diverse applications in biomedicine. Theoretical modelling can play an important role in understanding magnetite-based nanomaterials at the atomic scale…

Materials Science · Physics 2019-03-27 Hongsheng Liu , Gotthard Seifert , Cristiana Di Valentin