Related papers: Low Temperature Structural Phase Transition in the…
Under normal conditions, bulk crystals of BiScO$_3$ , BiCrO$_3$, BiMnO$_3$, BiFeO$_3$, and BiCoO$_3$ present three very different variations of the perovskite structure: an antipolar phase, a rhombohedral phase with a large polarization…
Here, the first-principles predictions on the structural stability, magnetic behavior and electronic structure of B-site ordered double perovskite Nd$_{2}$FeCrO$_{6}$ have been reported. Initially, the ground state of the parent single…
We report the results of both angle-dispersive x-ray diffraction and x-ray absorption near-edge structure studies in BaWO4 and PbWO4 at pressures of up to 56 GPa and 24 GPa, respectively. BaWO4 is found to undergo a pressure-driven phase…
The phonon spectrum of cubic BaThO$_3$ with the perovskite structure is calculated from first principles within the density functional theory. The analysis of unstable modes in the phonon spectrum enables to determine the symmetry of all…
We report direct experimental evidence of antiferroelectric to paraelectric phase transition under pressure in NaNbO3 using neutron diffraction at room temperature. The paraelectric phase is found to stabilize above 8 GPa and its crystal…
Single crystals of KOs2O6 have been grown in a sealed quartz ampoule. Detailed single crystal X-ray diffraction studies at room temperature show Bragg peaks that violate Fd-3m symmetry. With a comparative structure refinement the structure…
Among multifunctional double perovskite oxides, La2NiMnO6 has recently drawn significant attention due to its importance both in terms of understanding of fundamental physics and potential for device applications. The relative alteration in…
PbTiO3 has the highest tetragonal distortion (c/a=1.064) and highest spontaneous polarization among perovskite titanates. But, it is hazardous and hence one needs to reduce Pb content by substituting or reducing Pb content for use in…
The crystal structure, anisotropic electrical resistivity and magnetic susceptibility, as well as specific heat results from single crystals of BaFe2As2, BaNi2As2, and BaFeNiAs2 are surveyed. BaFe2As2 properties demonstrate the equivalence…
In this study, we report a tetragonal perovskite structure of SrIrO$_3$ (P4/mmm, a = 3.9362(9) \r{A}, c = 7.880(3) \r{A}) synthesized at 6 GPa and 1400 $\deg$C, employing the ambient pressure monoclinic SrIrO$_3$ with distorted 6H structure…
Perovskite structured materials contain myriad tunable ordered phases of electronic and magnetic origin with proven technological importance and strong promise for a variety of energy solutions. An always-contributing influence beneath…
Oxygen loss is one of the common defect types in perovskite oxides whose formation can be caused by a low oxygen background pressure during growth or by straining the thin film. Crystalline BaBiO3-{\delta} thin films are grown by molecular…
A single-phase 65PMN-35PT ceramic was synthesized at a relatively low temperature (875 oC) using a modified columbite method. X-ray diffraction analysis confirmed the single-phase formation of perovskite 65PMN-35PT with a tetragonal…
By means of in situ synchrotron X-ray diffraction and Raman spectroscopy under hydrostatic pressure, we investigate the structural stability of the quadruple perovskite LaMn7O12. At 34 GPa, the data unveil a first-order structural phase…
In a recent paper [arXiv:0804.3569], Takatoshi Nomura {\it et al.} reported a structural phase transition near 150 K in LaOFeAs and used space group "Cmma" to describe their X-ray diffraction data. However, they did not discuss how their…
In this work, a temperature-induced valence-state transition is studied in a narrow composition range of Ba$_{2-x}$Sr$_x$TbIrO$_6$. The valence-state transition involves an electron transfer between Tb and Ir leading to the valence-state…
Frustrated magnetism continues to attract significant attention due to its potential to host novel quantum many-body phenomena and associated exotic excitations that transcend existing paradigms. Herein, we present our reply to the comment…
The structures of the new compound La1.2Sr2.7IrO7+d and the recently discovered La1.2Sr2.7RuO7+d have been solved using a combination of X-ray and neutron diffraction. Both compounds crystallize in the trigonal space group R-3m and contain…
High-temperature electronic materials are in constant demand as the required operational range for various industries increases. Here we design $(A,A^\prime)B_2$O$_6$ perovskite oxides with [111] ``rock salt" $A$-site cation order and…
A metastable perovskite BiFe0.5Sc0.5O3 synthesized under high-pressure (6 GPa) and high- temperature (1500 K) conditions was obtained in two different polymorphs, antipolar Pnma and polar Ima2, through an irreversible behaviour under a…