In this study, we report a tetragonal perovskite structure of SrIrO3 (P4/mmm, a = 3.9362(9) \r{A}, c = 7.880(3) \r{A}) synthesized at 6 GPa and 1400 degC, employing the ambient pressure monoclinic SrIrO3 with distorted 6H structure as a precursor. The crystal structure of tetragonal SrIrO3 was evaluated on the basis of single crystal and powder X-ray diffraction. A cubic indexing was observed attributed to overlooked superlattice reflections. Weak fractional peaks in the H and K dimensions suggest possible structure modulation by oxygen defects. Magnetization study reveals weak paramagnetic behavior down to 2 K, indicative of the interplay between spin-orbit coupling, electron correlations, and crystal electric field. Additionally, measurements of electrical resistivity display metallic behavior with an upturn at about 54 K, ascribed to weak electron localization and possible structural defects.
@article{arxiv.2407.07984,
title = {Pseudosymmetry in Tetragonal Perovskite SrIrO$_3$ Synthesized under High Pressure},
author = {Haozhe Wang and Alberto de la Torre and Joseph T. Race and Qiaochu Wang and Jacob P. C. Ruff and Patrick M. Woodward and Kemp W. Plumb and David Walker and Weiwei Xie},
journal= {arXiv preprint arXiv:2407.07984},
year = {2024}
}