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The standard exposition of the internal resistance of a battery, that a battery comprises a source of emf in series with an internal resistance, as given in engineering and physics text-books, is lacking in proper explanation. It is treated…

Classical Physics · Physics 2018-04-25 Ashok K. Singal

We present a theory of the hydrodynamic forces in the drainage flow of an electrolyte between a sphere and a plane with charged surfaces. Our theory considers a thin electrolyte film which is at all times in local equilibrium across its…

Soft Condensed Matter · Physics 2025-04-01 C. Cramail , R. Lhermerout , E. Charlaix

We show that a cyclic unitary process can extract work from the thermodynamic equilibrium state of an engineered quantum dissipative process. Systems in the equilibrium states of these processes serve as batteries, storing energy. The…

Quantum Physics · Physics 2019-06-05 Felipe Barra

Lithium-ion batteries are used to store energy in electric vehicles. Physical models based on electro-chemistry accurately predict the cell dynamics, in particular the state of charge. However, these models are nonlinear partial…

Analysis of PDEs · Mathematics 2017-09-13 Sepideh Afshar , Kirsten Morris , Amir Khajepour

Polymer electrolytes (PEs) are promising candidates for use in next-generation high-voltage batteries, as they possess advantageous elastic and electrochemical properties. However, PEs still suffer from low ionic conductivity and need to be…

The conversion of heat into current can be obtained by a process with two stages. In the first one, the heat is used for distilling a solution and obtaining two flows with different concentrations. In the second stage, the two flows are…

Chemical Physics · Physics 2014-03-18 M. Marino , L. Misuri , A. Carati , D. Brogioli

We present a scattering theory of the electromotive force and internal resistance of an electron pump. The characterization of the device performance in terms of only two parameters requires the assumption of incoherent multiple scattering…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Miguel Rey , Fernando Sols

We analyse a device aimed at the conversion of heat into electrical energy, based on a closed cycle in which a distiller generates two solutions at different concentrations, and an electrochemical cell consumes the concentration difference,…

Chemical Physics · Physics 2022-09-14 Andrea Carati , Massimo Marino , Doriano Brogioli

A system in thermal equilibrium with a bath will generally be in an athermal state, if the system-bath coupling is strong. In some cases, it will be possible to extract work from that athermal state, after disconnecting the system from the…

Quantum Physics · Physics 2020-09-17 Karen V. Hovhannisyan , Felipe Barra , Alberto Imparato

A particular type of surface chemical reaction resulted in direct charge ejection. Several different experimental observations strongly support the hypothesis that nearly all of the molecular kinetic energy of a highly excited vibrating…

Chemical Physics · Physics 2009-04-30 Anthony Zuppero , Thomas J. Dolan

At photoelectrosynthetic interfaces, an electrochemical reaction is driven by excited charge-carriers from a semiconducting photoabsorber. Structure and composition of this interface determine both the electronic and electrochemical…

Chemical Physics · Physics 2022-05-30 Matthias M. May , Wolfram Jaegermann

A quantum system which can store energy, and from which one can extract useful work, is known as a quantum battery. Such a device raises interesting issues surrounding how quantum physics can provide certain advantages in the charging,…

Quantum Physics · Physics 2024-05-21 C. A. Downing , M. S. Ukhtary

We present a coupled continuum formulation for the electrostatic, chemical, thermal and mechanical processes in battery materials. Our treatment applies on the macroscopic scale, at which electrodes can be modelled as porous materials made…

Chemical Physics · Physics 2017-07-25 Zhenlin Wang , Jason B. Siegel , Krishna Garikipati

Chemical reactions involve the movement of charges, and this work presents a mathematical model for describing chemical reactions in electrolytes. The model is developed using an energy variational method that aligns with classical…

Chemical Physics · Physics 2023-11-02 Shixin Xu , Robert Eisenberg , Zilong Song , Huaxiong Huang

We study synchronization of two cardiomyocytes mediated by elastic interactions through the substrate. Modeling each cell as an oscillating force dipole governed by a Rayleigh-type equation, we derive an effective mechanical coupling from…

Soft Condensed Matter · Physics 2026-05-15 Akinari Tomiie , Nariya Uchida

In realistic open-system environments, decoherence and dissipation naturally drive quantum batteries toward passive states, thereby limiting their maximum extractable work (ergotropy). While quantum catalysis has been proposed to mitigate…

Quantum Physics · Physics 2026-04-29 Shun-Cai Zhao

Quantifying the outcomes of cells collisions is a crucial step in building the foundations of a kinetic theory of living matter. Here, we develop a mechanical theory of such collisions by first representing individual cells as extended…

Biological Physics · Physics 2019-12-11 Pierre Recho , Thibaut Putelat , Lev Truskinovsky

The interface plays a critical role in electrochemical systems, driving the development of various theories to investigate properties at nanoscale and microscale levels, including the electrictrochemical double layer (EDL) theory and…

Materials Science · Physics 2025-04-08 Yitao He

We present a coupled continuum formulation for the electrostatic, chemical, thermal, mechanical and fluid physics in battery materials. Our treatment is at the particle scale, at which the active particles held together by carbon-binders,…

Computational Physics · Physics 2018-07-26 Zhenlin Wang , Krishna Garikipati

We develop Electrochemical Mean-Field Kinetic Equations (EMFKE) to simulate electrochemical cells. We start from a microscopic lattice-gas model with charged particles, and build mean-field kinetic equations following the lines of earlier…

Materials Science · Physics 2009-11-10 Marc-Olivier Bernard , Mathis Plapp , Jean-Francois Gouyet
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