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Direct charge ejection for chemical electric generation

Chemical Physics 2009-04-30 v1

Abstract

A particular type of surface chemical reaction resulted in direct charge ejection. Several different experimental observations strongly support the hypothesis that nearly all of the molecular kinetic energy of a highly excited vibrating molecule was transferred to the kinetic energy of a single electron in a conducting lattice, leaving the molecule in nearly its ground state. This kinetic energy transfer represents the counterpart to the potential energy transfer in a battery, where electrochemical potential energy of reactants is transferred to the electrical potential energy of a separated charge. Here chemical reaction energy is transferred directly to the kinetic energy of a charge instead of to the potential energy of a charge. These observations indicate a breakdown of the Born Oppenheimer approximation.

Keywords

Cite

@article{arxiv.0904.4522,
  title  = {Direct charge ejection for chemical electric generation},
  author = {Anthony Zuppero and Thomas J. Dolan},
  journal= {arXiv preprint arXiv:0904.4522},
  year   = {2009}
}

Comments

12 pages, 6 figures

R2 v1 2026-06-21T12:56:10.869Z