Direct charge ejection for chemical electric generation
Abstract
A particular type of surface chemical reaction resulted in direct charge ejection. Several different experimental observations strongly support the hypothesis that nearly all of the molecular kinetic energy of a highly excited vibrating molecule was transferred to the kinetic energy of a single electron in a conducting lattice, leaving the molecule in nearly its ground state. This kinetic energy transfer represents the counterpart to the potential energy transfer in a battery, where electrochemical potential energy of reactants is transferred to the electrical potential energy of a separated charge. Here chemical reaction energy is transferred directly to the kinetic energy of a charge instead of to the potential energy of a charge. These observations indicate a breakdown of the Born Oppenheimer approximation.
Cite
@article{arxiv.0904.4522,
title = {Direct charge ejection for chemical electric generation},
author = {Anthony Zuppero and Thomas J. Dolan},
journal= {arXiv preprint arXiv:0904.4522},
year = {2009}
}
Comments
12 pages, 6 figures