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Related papers: Towards the surface hydroxyl species in CeO$_2$ na…

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Cerium oxide nanoparticles are known to catalyze the decomposition of reactive oxygen species such as superoxide radical and hydrogen peroxide. Herein, we examine the superoxide dismutase (SOD) and catalase (CAT) mimetic catalytic…

Materials Science · Physics 2021-09-21 V. Baldim , F. Bedioui , N. Mignet , I. Margaill , J. -F. Berret

Research on cerium oxide nanoparticles (nanoceria) has captivated the scientific community due to their unique physical and chemical properties, such as redox activity and oxygen buffering capacity, which made them available for many…

Materials Science · Physics 2021-09-21 Megan S. Lord , Jean Francois Berret , Sanjay Singh , Ajayan Vinu , Ajay S. Karakoti

Due to the increasing use of nanometric cerium oxide in applications, concerns about the toxicity of these particles have been raised and have resulted in a large number of investigations. We report here on the interactions between 7 nm…

Biological Physics · Physics 2013-08-06 N. Ould-Moussa , M. Safi , M. A. Guedeau-Boudeville , D. Montero , H. Conjeaud , J. F. Berret

Nanomaterials made of the cerium oxides CeO$_2$ and Ce$_2$O$_3$ have a broad range of applications, from catalysts in automotive, industrial or energy operations to promising materials to enhance hadrontherapy effectiveness in oncological…

Cerium oxide nanoparticles have been shown to mimic oxidoreductase enzymes by catalyzing the decomposition of organic substrates and reactive oxygen species. This mimicry can be found in superoxide radicals and hydrogen peroxides, harmful…

Rare earth cerium oxide (ceria) nanoparticles are stabilized using end-functional phosphonated-PEG oligomers. The complexation process and structure of the resulting hybrid core-shell singlet nanocolloids are described, characterized and…

Soft Condensed Matter · Physics 2008-04-23 L. Qi , A. Sehgal , J. -C. Castaing , J. -P. Chapel , J. Fresnais , J. -F. Berret , F. Cousin

In this work, we study the influence of the average crystallite size and dopant oxide on the reducibility of CeO2-based nanomaterials. Samples were prepared from commercial Gd2O3-, Sm2O3- and Y2O3-doped CeO2 powders by calcination at…

Using electron tomography in combination with spatially resolved electron energy-loss spectroscopy at high energy resolution, we are able to map the valency of the Ce ions in CeO$_{2-x}$ nanocrystals. Our three-dimensional results show a…

Materials Science · Physics 2014-07-10 Bart Goris , Stuart Turner , Sara Bals , Gustaaf Van Tendeloo

In a recent publication, we have highlighted the potential of phosphonic acid terminated PEG oligomers to functionalize strong UV absorption cerium oxide nanoparticles[1], which yield suspensions that are stable in aqueous or organic…

Materials Science · Physics 2013-05-07 L. Qi , J. Fresnais , P. Muller , O. Theodoly , J. -F. Berret , J. -P. Chapel

Silicon nanowires have attracted considerable interest due to their wide-ranging applications in nanoelectromechanical systems and nanoelectronics. Molecular dynamics simulations are powerful tools for studying the mechanical properties of…

Materials Science · Physics 2023-08-25 Sina Zare Pakzad , Mohammad Nasr Esfahani , B. Erdem Alaca

Recent nanotoxicity studies revealed that the physico-chemical characteristics of engineered nanomaterials play an important role in the interactions with living cells. Here, we report on the toxicity and uptake of the cerium and iron oxide…

Materials Science · Physics 2010-11-09 M. Safi , H. Sarrouj , O. Sandre , N. Mignet , J. -F. Berret

CeO$_x$-based nanoforms are widely used in catalysis, or biomedical applications due to their redox activity and oxygen storage capacity. The key parameters determining their surface chemistry are the Ce$^{3+}$/Ce$^{4+}$ ratio and the…

Materials Science · Physics 2025-07-08 Klára Beranová , Kevin C. Prince , Mariana Klementová , Marek Vronka , Oleksandr Romanyuk

Silicon oxide (SiOx) has been widely used in many electronic systems as a supportive and insulating medium. Here we demonstrate various electrical phenomena such as negative differential resistance, resistive switching and current…

Materials Science · Physics 2011-02-17 Jun Yao , Lin Zhong , Douglas Natelson , James M. Tour

Functional polymers, such as poly(ethylene glycol) (PEG) terminated with a single phosphonic acid, hereafter PEGik-Ph are often applied to coat metal oxide surfaces during post synthesis steps, but are not sufficient to stabilize sub-10 nm…

Anti-icing coatings are intended to prevent ice formation on surfaces, minimising the risk of surface-related damage and also reducing ice-related hazards in society. $\mathrm{CeO}_{2}$ coatings are robust, hydrophobic, and transmit light,…

In situ high pressure XRD diffraction and Raman spectroscopy have been performed on 12 nm CeO2 nanoparticles. Surprisingly, under quasihydrostatic condition, 12 nm CeO2 nanoparticles maintain the fluorite-type structure in the whole…

Materials Science · Physics 2015-06-15 Bo Liu , Ran Liu , Quan-Jun Li , Ming-Guang Yao , Bo Zou , Tian Cui , Bing-Bing Liu

Some of the synthesis methods and physical properties of iron-oxide based magnetic nanoparticles such as Fe3-xO4 and CoxFe3-xO4 are reviewed because of their interest in health, environmental applications, and ultra-high-density magnetic…

Nanoscale multiferroics are basic model objects for studying polar, magnetic and magnetoelectric properties and mutual couplings. Bismuth-samarium ferrite (Bi1-xSmxFeO3) is a model orthoferrite, whose polar, magnetic and magnetoelectric…

SiC is set to enable a new era in power electronics impacting a wide range of energy technologies, from electric vehicles to renewable energy. Its physical characteristics outperform silicon in many aspects, including band gap, breakdown…

The magnetic behavior of $Fe_{3-x}O_4$ nanoparticles synthesized either by high-temperature decomposition of an organic iron precursor or low-temperature co-precipitation in aqueous conditions, is compared. Transmission electron microscopy,…

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