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The natural orbital functional theory (NOFT) has emerged as an alternative formalism to both density functional (DF) and wavefunction methods. In NOFT, the electronic structure is described in terms of the natural orbitals (NOs) and their…

Computational Physics · Physics 2020-10-28 Mario Piris , Ion Mitxelena

We present a mean-field approach to simulating merging processes of two spherical collisionless stellar systems. This approach is realized with a self-consistent field (SCF) method in which the full spatial dependence of the density and…

Instrumentation and Methods for Astrophysics · Physics 2019-04-17 Shunsuke Hozumi , Masaki Iwasawa , Keigo Nitadori

We present a computational scheme for orbital-free density functional theory (OFDFT) that simultaneously provides access to all-electron values and preserves the OFDFT linear scaling as a function of the system size. Using the projector…

Computational Physics · Physics 2014-12-23 J. Lehtomäki , I. Makkonen , M. A. Caro , A. Harju , O. Lopez-Acevedo

We propose a hybrid approach which employs the dynamical mean-field theory (DMFT) self-energy for the correlated, typically rather localized orbitals and a conventional density functional theory (DFT) exchange-correlation potential for the…

Strongly Correlated Electrons · Physics 2021-06-16 Sumanta Bhandary , Karsten Held

One of the most promising techniques used for studying the electronic properties of materials is based on Density Functional Theory (DFT) approach and its extensions. DFT has been widely applied in traditional solid state physics problems…

Materials Science · Physics 2013-06-03 Nicola Varini , Davide Ceresoli , Layla Martin-Samos , Ivan Girotto , Carlo Cavazzoni

The $\Delta$SCF DFT approach defines the system energy as a function of orbital occupancy. Inspired by Landau Fermi liquid theory, we develop an occupancy extrapolation (OE) method that captures excited-state energies via a Taylor expansion…

Chemical Physics · Physics 2026-03-30 Yichen Fan , Weitao Yang

Propagation characteristics of a wave are defined by the dispersion relationship, from which the governing partial differential equation (PDE) can be recovered. PDEs are commonly solved numerically using the finite-difference (FD) method,…

Numerical Analysis · Mathematics 2021-07-29 Edward Caunt

We present DFT-FE 1.0, building on DFT-FE 0.6 [Comput. Phys. Commun. 246, 106853 (2020)], to conduct fast and accurate large-scale density functional theory (DFT) calculations (reaching ~ $100,000$ electrons) on both many-core CPU and…

Computational Physics · Physics 2022-08-31 Sambit Das , Phani Motamarri , Vishal Subramanian , David M. Rogers , Vikram Gavini

Recently an efficient numerical method has been developed to implement the constraints of crossing symmetry and unitarity on the operator dimensions and OPE coefficients of conformal field theories (CFT) in diverse space-time dimensions. It…

High Energy Physics - Theory · Physics 2013-10-30 Ferdinando Gliozzi

In his monograph Chebyshev and Fourier Spectral Methods, John Boyd claimed that, regarding Fourier spectral methods for solving differential equations, ``[t]he virtues of the Fast Fourier Transform will continue to improve as the relentless…

Numerical Analysis · Mathematics 2023-02-03 Craig Gross , Mark Iwen

The practical success of density functional theory (DFT) is largely credited to the Kohn-Sham approach, which enables the exact calculation of the non-interacting electron kinetic energy via an auxiliary noninteracting system. Yet, the…

Computational Physics · Physics 2025-03-21 Sangita Majumdar , Zekun Shi , Giovanni Vignale

Singlet fission (SF) is an electronic transition that in the last decade has been under the spotlight for its applications in optoelectronics, from photovoltaics to spintronics. Despite considerable experimental and theoretical…

Quantum Physics · Physics 2024-11-12 Francesco Campaioli , Alice Pagano , Daniel Jaschke , Simone Montangero

The distribution optimal power flow (D-OPF) models have gained attention in recent years to optimally operate acentrally-managed distribution grid. On account of nonconvex formulation that is difficult to solve, several relaxation methods…

Optimization and Control · Mathematics 2019-12-10 Rahul Ranjan Jha , Anamika Dubey

Probabilistic ordinary differential equation (ODE) solvers have been introduced over the past decade as uncertainty-aware numerical integrators. They typically proceed by assuming a functional prior to the ODE solution, which is then…

Numerical Analysis · Mathematics 2025-03-25 Yvann Le Fay , Simo Särkkä , Adrien Corenflos

We present a method to perform fully selfconsistent density-functional calculations, which scales linearly with the system size and which is well suited for very large systems. It uses strictly localized pseudoatomic orbitals as basis…

Condensed Matter · Physics 2009-10-28 Pablo Ordejon , Emilio Artacho , Jose M. Soler

We present a novel implementation of the complete active space self-consistent field (CASSCF) method that makes use of the many-body expanded full configuration interaction (MBE-FCI) method to incrementally approximate electronic structures…

The self-consistent procedure in electronic structure calculations is revisited using a highly efficient and robust algorithm for solving the non-linear eigenvector problem i.e. H({{\psi}}){\psi} = E{\psi}. This new scheme is derived from a…

Computational Physics · Physics 2015-06-12 Brendan Gavin , Eric Polizzi

In this paper, we use crossing symmetry and unitarity constraints to put a lower bound on the central charge of conformal field theories in large space-time dimensions $D$. Specifically, we work with the four-point function of identical…

High Energy Physics - Theory · Physics 2023-06-07 Abhijit Gadde , Mrunmay Jagadale , Shraiyance Jain , Trakshu Sharma

The reported new algorithm determines the exact exchange potential v_x in a iterative way using energy and orbital shifts (ES, OS) obtained - with finite-difference formulas - from the solutions (occupied orbitals and their energies) of the…

Atomic Physics · Physics 2015-05-20 M. Cinal , A. Holas

Singlet fission (SF) is a multi-exciton generation process that could be harnessed to improve the efficiency of photovoltaic devices. Experimentally, systems derived from the pentacene molecule have been shown to exhibit ultrafast SF with…

Chemical Physics · Physics 2020-06-23 David H. P. Turban , Gilberto Teobaldi , David D. O'Regan , Nicholas D. M. Hine
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