Related papers: A full-chain tube-based constitutive model for liv…
Solutions of polymer chains are modelled using non-equilibrium Brownian dynamics simulations, with physically associative beads which form reversible crosslinks to establish a system-spanning physical gel network. Rheological properties…
We construct a finite element approximation of a strain-limiting elastic model on a bounded open domain in $\mathbb{R}^d$, $d \in \{2,3\}$. The sequence of finite element approximations is shown to exhibit strong convergence to the unique…
We study stress relaxation in several types of entangled monodisperse linear polymer melts by comparing the shear stress relaxation modulus, $G(t)$, with the end-to-end vector autocorrelation function, $P(t)$. The study includes three…
This work concerns the continuum basis and numerical formulation for deformable materials with viscous dissipative mechanisms. We derive a viscohyperelastic modeling framework based on fundamental thermomechanical principles. Since most…
We consider a poromechanics model including frictionless contact mechanics. The resulting model consists of the Biot equations with contact boundary conditions leading to a variational inequality modelling mechanical deformations coupled to…
When subjected to sufficiently strong velocity gradients, solutions of long, flexible polymers exhibit flow instabilities and chaotic motion, often referred to as elastic turbulence. Its mechanism differs from the familiar, inertia-driven…
It is often said that well-entangled and fast-breaking living polymers (such as wormlike micelles) exhibit a single relaxation time in their reptation dynamics, but the full story is somewhat more complicated. Understanding departures from…
We derive a thermodynamically consistent framework for incorporating entanglement dynamics into constitutive equations for flowing polymer melts. We use this to combine the convected constraint release (CCR) dynamics of…
A new master equation to mimic the dynamics of a collection of interacting random walkers in an open system is proposed and solved numerically.In this model, the random walkers interact through excluded volume interaction (single-file…
We present an asymptotic framework that rigorously generates nonlinear constitutive relations between stress and linearized strain for elastic bodies. Each of these relations arises as the leading order relationship satisfied by a…
We study model near-critical polymer gelling systems made of gluten proteins dispersions stabilized at different distances from the gel point. We impose different shear rates and follow the time evolution of the stress. For sufficiently…
This article focuses on a preaveraging description of polymer nonequilibrium stretching, where a single polymer undergoes a transient process from equilibrium to nonequilibrium steady state by pulling one chain end. The preaveraging method…
The dynamic-mechanical response of flexible polymer networks is studied in the framework of tube model, in the limit of small affine deformations, using the approach based on Rayleighian dissipation function. The dynamic complex modulus G*…
In 1975 Doi and Edwards predicted that entangled polymer melts and solutions can have a constitutive instability, signified by a decreasing stress for shear rates greater than the inverse of the reptation time. Experiments did not support…
An $hp$-adaptive continuous Galerkin finite element method is developed to analyze a static anti-plane shear crack embedded in a nonlinear, strain-limiting elastic body. The geometrically linear material is described by a constitutive law…
We investigate the nonequilibrium tube length fluctuations during the relaxation of an initially stretched, entangled polymer chain. The time-dependent variance $\sigma^2$ of the tube length follows in the early-time regime a simple…
This study proposes a simple and novel class of stretch-limiting constitutive relations for perfectly flexible elastic strings drawing from modern advances in constitutive theory for elastic bodies. We investigate strings governed by…
Placed slightly out of dynamical equilibrium, an isolated stellar system quickly returns towards a steady virialized state. We study this process of collisionless relaxation using the matrix method of linear response theory. We show that…
We analyze the nonequilibrium dynamics of single inextensible semiflexible biopolymers as stretching forces are applied at the ends. Based on different (contradicting) heuristic arguments, various scaling laws have been proposed for the…
This paper examines the linearized stability of plane Couette flow for stress-power law fluids, which exhibit non-monotonic stress-strain rate behavior. The constitutive model is derived from a thermodynamic framework using a non-convex…