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The shift current photovoltaic effect is conventionally understood as the real-space displacement of a wave packet induced by photoexcitation. However, this interpretation becomes insufficient in flat-band systems, where quasiparticles are…

Materials Science · Physics 2025-02-25 Zhuocheng Lu , Zhihao Gong , Jingshan Qi , Hua Wang , Kai Chang

The bulk photovoltaic effect that is intimately associated with crystalline symmetry has been extensively studied in various nonmagnetic materials, especially ferroelectrics with a switchable electric polarization. In order to further…

Materials Science · Physics 2022-12-28 Chunmei Zhang , Ping Guo , Jian Zhou

In future solar cell technologies, the thermodynamic Shockley-Queisser limit for solar-to-current conversion in traditional p-n junctions could potentially be overcome with a bulk photovoltaic effect by creating an inversion broken symmetry…

Realization of giant and continuously tunable second-order photocurrent is desired for many nonlinear optical (NLO) and optoelectronic applications, which remains to be a great challenge. Here, based on a simple two-band model, we propose a…

Materials Science · Physics 2023-07-05 Xiao Jiang , Lei Kang , Jianfeng Wang , Bing Huang

A bulk material without inversion symmetry can generate a direct current under illumination. This interface-free current generation mechanism, referred to as the bulk photovoltaic effect (BPVE), does not rely on $p$-$n$ junctions. Here, we…

Materials Science · Physics 2023-05-01 Zhuang Qian , Jian Zhou , Hua Wang , Shi Liu

We use a first-principles density functional theory approach to calculate the shift current and linear absorption of uniformly illuminated single-layer Ge and Sn monochalcogenides. We predict strong absorption in the visible spectrum and a…

Mesoscale and Nanoscale Physics · Physics 2017-08-29 Tonatiuh Rangel , Benjamin M. Fregoso , Bernardo S. Mendoza , Takahiro Morimoto , Joel E. Moore , Jeffrey B. Neaton

The correlation between the shift current mechanism for the bulk photovoltaic effect (BPVE) and the structural and electronic properties of ferroelectric perovskite oxides is not well understood. Here, we study and engineer the shift…

Materials Science · Physics 2015-03-03 Fenggong Wang , Steve M. Young , Fan Zheng , Ilya Grinberg , Andrew M. Rappe

While new species and properties of two-dimensional (2D) materials are being reported with extraordinary regularity, a significant bottleneck in the field is the ability to controllably process material into working devices. We report a…

Bulk photovoltaic effect, which arises from crystal symmetry-driven charge carrier separation, is an intriguing physical phenomenon that has attracted extensive interest in photovoltaic application due to its junction-free photovoltaic and…

Materials Science · Physics 2023-08-22 Xiaojuan Chen , Kang Xu , Tingxiao Qin , Yubin Wang , Yuzhong Chen , Haiyun Liu , Qihua Xiong

Transition metal dichalcogenides have attracted much attention recently due to their potential applications in spintronics and photonics as a result of the indirect to direct band gap transition and the emergence of the spin-valley coupling…

We calculate the shift current response, which has been identified as the dominant mechanism for the bulk photovoltaic effect, for the polar compounds LiAsS$_\text{2}$, LiAsSe$_\text{2}$, and NaAsSe$_\text{2}$. We find that the magnitudes…

Materials Science · Physics 2014-12-04 John A. Brehm , Steve M. Young , Fan Zheng , Andrew M. Rappe

Achieving high performance in transition-metal-dichalcogenide-based optoelectronic devices is challenging -- the realization of an efficient electrical contacting scheme should not be obtained at the expense of their optical quality. Here…

Mesoscale and Nanoscale Physics · Physics 2025-04-28 Agata Zielińska , Mateusz Dyksik , Alessandro Surrente , Jonathan Eroms , Dieter Weiss , Paulina Płochocka , Mariusz Ciorga

Piezoelectricity appears in the inversion asymmetric crystal that converts mechanical deformational force to electricity. Two-dimensional transition metal dichalcolgenide (TMDC) monolayers exhibit the piezoelectric effect due to the…

Applied Physics · Physics 2019-12-13 Sheng Yu , Quinton Rice , Tikaram Neupane , Bagher Tabibi , Felix Jaetae Seo

The integration of transition metal dichalcogenides (TMDs) with ferroelectric substrates is a powerful strategy to modulate their electronic and optical properties. However, the use of relaxor ferroelectrics for this purpose remains…

Materials Science · Physics 2025-05-06 D. Hernández-Pinilla , D. Cachago , Y. A. Xia , G. López-Polín , M. O Ramírez , L. E. Bausá

The nonlinear shift current, also known as the bulk photovoltaic current generated by linearly polarized light, has long been known to be absent in crystals with inversion symmetry. Here we argue that a non-zero shift current in…

Mesoscale and Nanoscale Physics · Physics 2021-05-19 Li-kun Shi , Dong Zhang , Kai Chang , Justin C. W. Song

We investigate the shift current bulk photovoltaic response of materials close to a band inversion topological phase transition. We find that the bulk photocurrent reverses direction across the band inversion transition, and that its…

Mesoscale and Nanoscale Physics · Physics 2016-09-08 Liang Z. Tan , Andrew M. Rappe

Dislocations in van der Waals materials are linear defects confined to the interfaces between consecutive stoichiometric monolayers of a bulk layered crystal. Here, we present a mesoscale model for the description of interlayer dislocations…

Mesoscale and Nanoscale Physics · Physics 2024-09-19 Isaac Soltero , Vladimir I. Fal'ko

Two-dimensional (2D) layered transition metal dichalcogenides (TMDs) have emerged as promising materials for electronic, optoelectronic, and valleytronic applications. Recent work suggests drastic changes of the band gap and exciton binding…

Mesoscale and Nanoscale Physics · Physics 2017-08-02 Eric Parzinger , Martin Hetzl , Ursula Wurstbauer , Alexander W. Holleitner

The large family of layered transition-metal dichalcogenides is widely believed to constitute a second family of two-dimensional (2D) semiconducting materials that can be used to create novel devices that complement those based on graphene.…

Recently, atomically thin PdSe$_2$ semiconductors with rare pentagonal Se-Pd-Se monolayers were synthesized and were also found to possess superior properties such as ultrahigh air stability, and high carrier mobility, thus offering a new…

Materials Science · Physics 2021-09-21 Vijay Kumar Gudelli , Guang-Yu Guo
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