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Strain-induced transitions of polarization reversal in thin films of a ferrielectric CuInP$_2$S$_6$ (CIPS) with ideally-conductive electrodes is explored using the Landau-Ginzburg-Devonshire (LGD) approach with an eighth-order free energy…

Nanoscale ferroelectric 2D materials offer unique opportunity to investigate curvature and strain effects on materials functionalities. Among these, CuInP2S6 (CIPS) has attracted tremendous research interest in recent years due to…

The switching dynamics of ferroelectric materials is a crucial intrinsic property which directly affects the operation and performance of ferroelectric devices. In conventional ferroelectric materials, the typical ferroelectric switching…

Materials Science · Physics 2023-08-02 Ri He , Hua Wang , Fucai Liu , Shi Liu , Houfang Liu , Zhicheng Zhong

The van der Waals layered material CuInP2S6 features interesting functional behavior, including the existence of four uniaxial polarization states, polarization reversal against the electric field through Cu ion migration, a…

Bulk single-crystal relaxor-ferroelectrics, like Pb(Mg1/3Nb2/3)O3-PbTiO3 (PMN-PT), are widely known for their large piezoelectricity. This is attributed to polarization rotation which is facilitated by the presence of various crystal…

Electric polarization and metallicity are long believed not to coexist until the emergence of exceptionally rare material examples including the bulk polar metals and more recently two-dimensional (2D) van der Waals (vdW) materials such as…

Mesoscale and Nanoscale Physics · Physics 2025-10-13 Zhou Zhou , Xiyao Peng , Jianfeng Bi , Fei Xue , Jie Jiang , Huizhen Wu , Zhiwen Shi , Haoliang Qian , Toshikaze Kariyado , Sihan Zhao

VO2 is well known for its dual phase transitions; electrical as well as structural, at a single temperature of 340K. The low temperature structural phases of VO2 are different from its high temperature counterpart by means of structural…

Materials Science · Physics 2021-09-16 Raktima Basu , G. Mangamma , Sandip Dhara

We derive first- and second-order piezoelectric coefficients for the zinc-blende III-V semiconductors, {Al,Ga,In}-{N,P,As,Sb}. The results are obtained within the Heyd-Scuseria-Ernzerhof hybrid-functional approach in the framework of…

Materials Science · Physics 2015-02-20 Miguel A. Caro , Stefan Schulz , Eoin P. O'Reilly

We developed a lattice dynamical theory of an atomically-thin compressional piezoelectric resonator. Acoustic and optical dynamic displacement response functions are derived and account for frequency-dependent electromechanical coupling.…

Mesoscale and Nanoscale Physics · Physics 2024-10-07 Karl H. Michel , Cem Sevik , Milorad V. Milosevic

Sliding ferroelectricity is a recently observed polarity existing in two-dimensional materials. However, due to their weak polarization and poor electrical insulation in these materials, all available experimental evidence till now are…

Materials Science · Physics 2023-05-22 Le-Ping Miao , Ning Ding , Na Wang , Chao Shi , Heng-Yun Ye , Linglong Li , Ye-Feng Yao , Shuai Dong , Yi Zhang

We show how van der Waals (vdW) forces outcompete covalent and ionic forces to control ferroelectric ordering in CuInP2S6 nanoflakes as well as in CuInP2S6 and CuBiP2Se6 crystals. While the self-assembly of these 2D layered materials is…

Materials Science · Physics 2018-05-31 Jeffrey R. Reimers , Sherif Abdulkader Tawfik , Michael J. Ford

Despite their ionic nature, many layered diatomic crystals avoid internal electric polarization by forming a centrosymmetric lattice at their optimal anti-parallel van-der-Waals stacking. Here, we report a stable ferroelectric order…

Sliding ferroelectricity is a phenomenon that arises from the insurgence of spontaneous electronic polarization perpendicular to the layers of two-dimensional (2D) systems upon the relative sliding of the atomic layer constituents. Because…

Materials Science · Physics 2026-04-21 Matteo D'Alessio , Daniele Varsano , Elisa Molinari , Massimo Rontani

Using first-principles calculations we model the out-of-plane switching of local dipoles in CuInP$_2$S$_6$ (CIPS) that are largely induced by Cu off-centering. Previously, a coherent switching of polarization via a quadruple-well potential…

Materials Science · Physics 2023-06-23 N. Sivadas , Bobby G. Sumpter , P. Ganesh

Topological polar textures in ferroelectrics have attracted significant interest for their potential for energy-efficient and high-density data storage and processing. Among these, polar merons and antimerons are predicted in strained and…

The magnetic, thermodynamic, and pyroelectric properties of LiFeP$_2$O$_7$ single crystals are investigated with emphasis on the magnetoelectric interaction of the electrical polarization with the magnetic order parameter. The magnetic…

Strongly Correlated Electrons · Physics 2012-09-13 K. -C. Liang , W. Zhang , B. Lorenz , Y. Y. Sun , P. S. Halasyamani , C. W. Chu

Copper indium thiophosphate, CuInP2S6, has attracted much attention in recent years due to its van der Waals layered structure and robust ferroelectricity at room temperature. In this review, we aim to give an overview of the various…

Materials Science · Physics 2020-09-07 Shuang Zhou , Lu You , Hailin Zhou , Yong Pu , Zhigang Gui , Junling Wang

The so-called interlayer-sliding ferroelectricity was recently proposed as an unconventional route to pursuit electric polarity in van der Waals multi-layers, which was already experimentally confirmed in WTe$_2$ bilayer even though it is…

Materials Science · Physics 2021-08-17 Ning Ding , Jun Chen , Churen Gui , Haipeng You , Xiaoyan Yao , Shuai Dong

Negative Poisson's ratio as the anomalous characteristic generally exists in artificial architectures, such as re-entrant and honeycomb structures. The structures with negative Poisson's ratio have attracted intensive attention due to their…

Piezoresistance, the change of a material's electrical resistance ($R$) in response to an applied mechanical stress ($\sigma$), is the driving principle of electromechanical devices such as strain gauges, accelerometers, and cantilever…

Strongly Correlated Electrons · Physics 2022-07-20 S. Ghosh , C. Lane , F. Ronning , E. D. Bauer , J. D. Thompson , J. -X. Zhu , P. F. S. Rosa , S. M. Thomas