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Excitons are key quasiparticles determining the optical properties of solids. As such, they can be utilized to coherently control the electronic structure of materials using optical femtosecond pulses. Identifying the decoherence mechanism…

Vibrational dynamics governs the fundamental properties of molecular crystals, shaping their thermodynamics, mechanics, spectroscopy, and transport phenomena. However desirable, the first-principles calculation of solid-state vibrations,…

Materials Science · Physics 2025-03-25 Lorenzo Soprani , Andrea Giunchi , Marco Bardini , Quintin N. Meier , Gabriele D'Avino

We propose a novel approach to calculate dynamical processes at ultrafast time scale in molecules in which vibrational and electronic motions are strongly mixed. The relevant electronic orbitals and their interactions are described by a…

Strongly Correlated Electrons · Physics 2009-11-07 L. Arrachea , A. A. Aligia , G. E. Santoro

Electron motion on the (sub-)femtosecond time scale constitutes the fastest response in many natural phenomena such as light-induced phase transitions and chemical reactions. Whereas static electron densities in single molecules can be…

Non-diffusive, fluid-like transport of charge and heat has been observed in several materials, raising the question of whether they can emerge simultaneously and how they are related to bi-component electron-phonon fluids. Here we introduce…

Mesoscale and Nanoscale Physics · Physics 2026-03-23 Jennifer Coulter , Bogdan Rajkov , Michele Simoncelli

Metals exhibit nonequilibrium electron and lattice subsystems at transient times following femtosecond laser excitation. In the past four decades, various optical spectroscopy and time-resolved diffraction methods have been used to study…

Chemical Physics · Physics 2024-05-17 Xing He , Mithun Ghosh , Ding-Shyue Yang

Understanding nonequilibrium electron-phonon interactions at the microscopic level and on ultrafast timescales is a central goal of modern condensed matter physics. Combining time- and angle-resolved extreme ultraviolet photoemission…

Interactions between the lattice and charge carriers can drive the formation of phases and ordering phenomena that give rise to conventional superconductivity, insulator-to-metal transitions, and charge-density waves. These couplings also…

The ultrafast response of metals to light is governed by intriguing non-equilibrium dynamics involving the interplay of excited electrons and phonons. The coupling between them gives rise to nonlinear diffusion behavior on ultrashort…

Although extensive experimental and theoretical works have been conducted to understand the ballistic and diffusive phonon transport in nanomaterials recently, direct observation of temperature and thermal nonequilibrium of different phonon…

Mesoscale and Nanoscale Physics · Physics 2017-05-17 Tianli Feng , Wenjun Yao , Zuyuan Wang , Jingjing Shi , Chuang Li , Bingyang Cao , Xiulin Ruan

The element specificity of soft X-ray spectroscopy makes it an ideal tool for analyzing the microscopic origin of ultrafast dynamics induced by localized optical excitation in metal-insulator heterostructures. Using [Fe/MgO]$_n$ as a model…

The non-equilibrium dynamics of matter excited by light may produce electronic phases that do not exist in equilibrium, such as laser-induced high-transition-temperature superconductivity. Here we simulate the dynamics of a metal driven at…

Strongly Correlated Electrons · Physics 2022-12-05 John Sous , Benedikt Kloss , Dante M. Kennes , David R. Reichman , Andrew J. Millis

We present a detailed calculation of intensities of two-phonon and four-phonon Raman peaks in graphene. Writing the low-energy hamiltonian of the interaction of electrons with the crystal vibrations and the electromagnetic field from pure…

Materials Science · Physics 2009-11-13 D. M. Basko

We introduce a novel method for the simulation of the impact scattering in vibrational scanning transmission electron microscopy electron energy loss spectroscopy (STEM-EELS) simulations. The phonon-loss process is modeled by a combination…

Materials Science · Physics 2020-01-22 Paul M. Zeiger , Ján Rusz

A resonantly excited coherent phonon leads to a periodic oscillation of the atomic lattice in a crystal structure bringing the material into a non-equilibrium electronic configuration. Periodically oscillating quantum systems can be…

Materials Science · Physics 2018-01-31 Hannes Hübener , Umberto De Giovannini , Angel Rubio

Quantum materials hold immense promises for future applications due to their intriguing electronic, magnetic, thermal, and mechanical properties that often arise from a complex interplay between microscopic degrees of freedom. Important…

Strongly Correlated Electrons · Physics 2025-02-18 Chenhang Xu , Alfred Zong

Ultrafast measurement technology provides essential contributions to our microscopic understanding of the properties and functions of solids and nanostructures. Atomic-scale vistas with ever-growing spatial and temporal resolution are…

Mesoscale and Nanoscale Physics · Physics 2020-08-26 Armin Feist , Gero Storeck , Sascha Schäfer , Claus Ropers

We present a new paradigm for understanding optical absorption and hot electron dynamics experiments in graphene. Our analysis pivots on assigning proper importance to phonon assisted indirect processes and bleaching of direct processes. We…

Materials Science · Physics 2017-11-22 Yuan Yang , Grigory Kolesov , Lucas Kocia , Eric J. Heller

We develop a first-principles many-body framework to describe the dynamics of photocarriers and phonons in semiconductors following ultrafast excitation. Our approach incorporates explicit ab initio light-matter coupling and…

Materials Science · Physics 2025-12-10 Stefano Mocatti , Giovanni Marini , Giulio Volpato , Pierluigi Cudazzo , Matteo Calandra

Time resolved measurements provide a new way to disentangle complex interactions in quantum materials due to their different timescales. We used pump-probe Raman scattering to investigate the apical oxygen vibration in…

Superconductivity · Physics 2021-12-07 N. Pellatz , S. Roy , J-W. Lee , J. L. Schad , H. Kandel , N. Arndt , C. B. Eom , A. F. Kemper , D. Reznik