English
Related papers

Related papers: Resonant collisional shielding of reactive molecul…

200 papers

The dipolar collision between ultracold polar molecules is an important topic both by its own right from the fundamental point of view and for the successful exploration of many-body physics with strong and long-range dipolar interactions.…

Exploring inelastic and reactive collisions on the quantum level is a main goal of the developing field of ultracold chemistry. We present first experimental studies of inelastic collisions of metastable ultracold triplet molecules in the…

Controlling interactions between cold molecules using external fields can elucidate the role of quantum mechanics in molecular collisions. We create a new experimental platform in which ultracold rubidium atoms and cold ammonia molecules…

Atomic Physics · Physics 2011-05-24 L. P. Parazzoli , N. J. Fitch , P. S. Zuchowski , J. M. Hutson , H. J. Lewandowski

We show that the electric dipole-dipole interaction between a pair of polar molecules undergoes an all-out transformation when superimposed by a far-off resonant optical field. The combined interaction potential becomes tunable by variation…

Atomic Physics · Physics 2015-05-30 Mikhail Lemeshko , Bretislav Friedrich

We present a unified formalism for describing chemical reaction rates of trapped, ultracold molecules. This formalism reduces the scattering to its essential features, namely, a propagation of the reactant molecules through a gauntlet of…

Quantum Physics · Physics 2015-05-19 Zbigniew Idziaszek , Goulven Quéméner , John L. Bohn , Paul S. Julienne

We propose a method to suppress the chemical reactions between ultracold bosonic ground-state $^{23}$Na$^{87}$Rb molecules based on optical shielding. By applying a laser with a frequency blue-detuned from the transition between the lowest…

Quantum Gases · Physics 2020-10-14 T. Xie , M. Lepers , R. Vexiau , A. Orban , O. Dulieu , N. Bouloufa-Maafa

We present a time-independent quantum formalism to describe the dynamics of molecules with permanent electric dipole moments in a two-dimensional confined geometry such as a one-dimensional optical lattice, in the presence of an electric…

Atomic Physics · Physics 2011-01-17 Goulven Quéméner , John L. Bohn

This article reviews the current state of the art in the field of cold and ultracold molecules and demonstrates that chemical reactions, inelastic collisions and dissociation of molecules at subKelvin temperatures can be manipulated with…

Atomic Physics · Physics 2015-06-26 R. V. Krems

Laser cooled Rb atoms were optically excited to 46d Rydberg states. A microwave pulse transferred a fraction of the atoms to the 47p Rydberg state. The resonant electric dipole-dipole interactions between atoms in these two states were…

Atomic Physics · Physics 2007-05-23 K. Afrousheh , P. Bohlouli-Zanjani , J. D. Carter , A. Mugford , J. D. D. Martin

We calculate the microwave spectra of ultracold KRb alkali metal dimers, including hyperfine interactions and in the presence of electric and magnetic fields. We show that microwave transitions may be used to transfer molecules between…

Chemical Physics · Physics 2015-05-13 J. Aldegunde , Hong Ran , Jeremy M. Hutson

We present a simple technique for studying collisions of ultracold atoms in the presence of a magnetic field and radio-frequency radiation (rf). Resonant control of scattering properties can be achieved by using rf to couple a colliding…

Quantum Gases · Physics 2010-09-28 Thomas M. Hanna , Eite Tiesinga , Paul S. Julienne

Compared to purely atomic collisions, ultracold molecular collisions potentially support a much larger number of Fano-Feshbach resonances due to the enormous number of ro-vibrational states available. In fact, for alkali-metal dimers we…

Atomic Physics · Physics 2012-10-19 Michael Mayle , Goulven Quéméner , Brandon P. Ruzic , John L. Bohn

We theoretically investigate the collisions between ultracold polar molecules in the presence of two lasers ensuring a Raman resonant transition on individual molecules to suppress photon scattering, taking the example of bosonic…

We determine trapping conditions for ultracold polar molecules, where pairs of internal states experience identical trapping potentials. Such conditions could ensure that detrimental effects of inevitable inhomogeneities across an ultracold…

Atomic Physics · Physics 2015-06-12 Alexander Petrov , Constantinos Makrides , Svetlana Kotochigova

With the creation of ultracold atoms and molecules, a new type of chemistry - "resonance" chemistry - emerges: chemical reactions can occur when the energy of colliding atoms and molecules matches a bound state of the combined molecule…

Other Condensed Matter · Physics 2009-11-11 V. V. Flambaum , J. S. M. Ginges

Collisional resonances are an important tool which has been used to modify interactions in ultracold gases, for realizing novel Hamiltonians in quantum simulations, for creating molecules from atomic gases and for controlling chemical…

Quantum Gases · Physics 2023-02-06 Juliana J. Park , Yu-Kun Lu , Alan O. Jamison , Timur Tscherbul , Wolfgang Ketterle

We produce ultracold dense trapped samples of 87Rb133Cs molecules in their rovibrational ground state, with full nuclear hyperfine state control, by stimulated Raman adiabatic passage (STIRAP) with efficiencies of 90%. We observe the onset…

It is demonstrated that elastic collisions of ultracold atoms forming a heteronuclear collision complex can be manipulated by laboratory practicable dc electric fields. The mechanism of electric field control is based on the interaction of…

Atomic Physics · Physics 2007-05-23 R. V. Krems

In this study, we achieved magnetic control of reactive scattering in an ultracold mixture of $^{23}$Na atoms and $^{23}$Na$^{6}$Li molecules. In most molecular collisions, particles react or are lost near short range with unity…

Atomic Physics · Physics 2022-03-14 Hyungmok Son , Juliana J. Park , Yu-Kun Lu , Alan O. Jamison , Tijs Karman , Wolfgang Ketterle

Progress in ultracold experiments with polar molecules requires a clear understanding of their interactions and reactivity at ultra-low collisional energies. Two important theoretical steps in this process are the characterization of…

Atomic Physics · Physics 2015-05-18 Svetlana Kotochigova