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Microscopic control over polar molecules with tunable interactions would enable realization of novel quantum phenomena. Using an applied electric field gradient, we demonstrate layer-resolved state preparation and imaging of ultracold…

We investigate the ultracold collisions of rotationally excited dipolar molecules in free-space, taking the hetero-nuclear bi-alkali molecule of KRb as an example. We show that we can sharply tune the elastic, inelastic and reactive rate…

Atomic Physics · Physics 2015-03-31 Gaoren Wang , Goulven Quéméner

We theoretically study collisions between ultracold polar molecules that are polarized by microwave or static electric fields. We systematically study the dependence on field strength, microwave polarization, and detuning from rotational…

Atomic Physics · Physics 2022-02-09 Tijs Karman , Zoe Z. Yan , Martin Zwierlein

Ultracold polar molecules offer the possibility of exploring quantum gases with interparticle interactions that are strong, long-range, and spatially anisotropic. This is in stark contrast to the dilute gases of ultracold atoms, which have…

Atomic Physics · Physics 2015-05-18 K. -K. Ni , S. Ospelkaus , D. Wang , G. Quemener , B. Neyenhuis , M. H. G. de Miranda , J. L. Bohn , J. Ye , D. S. Jin

The prospects for shielding ultracold, paramagnetic, dipolar molecules from inelastic and chemical collisions are investigated. Molecules placed in their first rotationally excited states are found to exhibit effective long-range repulsion…

Atomic Physics · Physics 2016-01-20 Goulven Quéméner , John L. Bohn

We report the investigation on dipolar collisions in rotational state mixtures of ultracold bosonic $^{23}$Na$^{87}$Rb molecules. The large resonant dipole-dipole interaction between molecules in rotational states of opposite parities…

Atomic Physics · Physics 2021-01-13 Junyu He , Xin Ye , Junyu Lin , Mingyang Guo , Goulven Quéméner , Dajun Wang

Ultracold molecules provide opportunities for exploring quantum matter, chemical dynamics and information processing thanks to their rich interactions, which can be controlled by external fields. Magnetic fields tune interactions through…

Chemical reaction rates often depend strongly on stereodynamics, namely the orientation and movement of molecules in three-dimensional space. An ultracold molecular gas, with a temperature below 1 uK, provides a highly unusual regime for…

Quantum Physics · Physics 2016-11-25 M. H. G. de Miranda , A. Chotia , B. Neyenhuis , D. Wang , G. Quemener , S. Ospelkaus , J. L. Bohn , J. Ye , D. S. Jin

We probe resonant dipolar interactions between ultracold $^{40}$K$^{87}$Rb molecules and Rydberg $^{87}$Rb atoms in an optically trapped ensemble. Through state-selective ionization detection of the KRb molecules, we observe resonant energy…

Atomic Physics · Physics 2025-04-10 Lingbang Zhu , Jeshurun Luke , Roy Shaham , Yi-Xiang Liu , Kang-Kuen Ni

We report the creation and characterization of a near quantum-degenerate gas of polar $^{40}$K-$^{87}$Rb molecules in their absolute rovibrational ground state. Starting from weakly bound heteronuclear KRb Feshbach molecules, we implement…

By leveraging the hyperfine interaction between the rotational and nuclear spin degrees of freedom, we demonstrate extensive magnetic control over the electric dipole moments, electric dipolar interactions, and ac Stark shifts of…

Atomic Physics · Physics 2024-01-11 Rebekah Hermsmeier , Ana Maria Rey , Timur V. Tscherbul

Molecules are the building blocks of matter and their control is key to the investigation of new quantum phases, where rich degrees of freedom can be used to encode information and strong interactions can be precisely tuned. Inelastic…

Quantum Gases · Physics 2021-01-27 Giacomo Valtolina , Kyle Matsuda , William G. Tobias , Jun-Ru Li , Luigi De Marco , Jun Ye

We demonstrate microwave dressing on ultracold, fermionic ${}^{23}$Na${}^{40}$K ground-state molecules and observe resonant dipolar collisions with cross sections exceeding three times the $s$-wave unitarity limit. The origin of these…

Quantum Gases · Physics 2020-08-06 Zoe Z. Yan , Jee Woo Park , Yiqi Ni , Huanqian Loh , Sebastian Will , Tijs Karman , Martin Zwierlein

Ultracold polar molecules offer strong electric dipole moments and rich internal structure, which makes them ideal building blocks to explore exotic quantum matter, implement novel quantum information schemes, or test fundamental symmetries…

We formulate the theory for a diatomic molecule in a spatially degenerate electronic state interacting with a non-resonant laser field and investigate its rovibrational structure in the presence of the field. We report on \textit{ab initio}…

We consider ultracold collisions of polar molecules confined in a one dimensional optical lattice. Using a quantum scattering formalism and a frame transformation method, we calculate elastic and chemical quenching rate constants for…

Atomic Physics · Physics 2010-06-11 Goulven Quéméner , John L. Bohn

We develop a collisional formalism adapted for the dynamics of ultracold dipolar particles in a confined geometry and in fields tilted relative to the confinement axis. Using tesseral harmonics instead of the usual spherical harmonics to…

Atomic Physics · Physics 2015-10-21 Goulven Quéméner , Maxence Lepers , Olivier Dulieu

How does a chemical reaction proceed at ultralow temperatures? Can simple quantum mechanical rules such as quantum statistics, single scattering partial waves, and quantum threshold laws provide a clear understanding for the molecular…

We study the resonant control of two nonreactive polar molecules in an optical lattice site, focussing on the example of RbCs. Collisional control can be achieved by tuning bound states of the intermolecular dipolar potential, by varying…

Quantum Gases · Physics 2015-06-03 Thomas M. Hanna , Eite Tiesinga , William F. Mitchell , Paul S. Julienne

We propose a one-channel, simple model to describe the dynamics of ultracold dipolar molecules around a F\"orster resonance. Slightly above a specific electric field, a collisional shielding can take place, suppressing the molecular losses…

Quantum Gases · Physics 2024-06-21 Lucas Lassablière , Goulven Quéméner
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