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Selective sensing of chiral molecules is a key aspect in fields spanning biology, chemistry, and pharmacology. However, conventional optical methods, such as circular dichroism (CD), encounter limitations owing to weak chiral light-matter…

Chiral and axial materials offer platforms for intriguing phenomena, such as cross-correlated responses and chirality-induced spin selectivity. However, quantifying the properties of such materials has generally been considered challenging.…

Materials Science · Physics 2025-10-07 Tatsuya Miki , Hiroaki Ikeda , Michi-To Suzuki , Shintaro Hoshino

Polarization-sensitive devices rely on meta-materials to exhibit varying degrees of absorption of light of a given handedness. The chiral surface states of a topological insulator(TI) selectively absorb right and left circularly polarized…

Mesoscale and Nanoscale Physics · Physics 2016-02-17 Parijat Sengupta , Enrico Bellotti

The recent discovery that linearly polarized light with a helical wavefront can exhibit vortex dichroism (also referred to as helical dichroism) has opened up new horizons in chiroptical spectroscopy with structured chiral light. Recent…

Optics · Physics 2025-02-05 Luke Cheeseman , Kayn A Forbes

Conventional linear optical activity effects are widely used for studying chiral materials. However, poor contrast and artifacts due to sample anisotropy limit the applicability of these methods. Here we demonstrate that nonlinear…

Biological Physics · Physics 2016-02-16 Mei-Yu Chen , Mikko J. Huttunen , Che-Wei Kan , Yen-Yin Lin , Cin-Wei Ye , Meng-Jer Wu , Hsiang-Lin Liu , Shi-Wei Chu

We show that the combination of two achiral components - atomic or molecular target plus a circularly polarized photon - can yield chirally structured photoelectron angular distributions. For photoionization of CO, the angular distribution…

Determination of enantiomeric excess is important and remains challenges. We theoretically propose a new spectroscopic method for this issue based on the chirality-dependent AC Stark effects in cyclic three-level models under the…

Optics · Physics 2019-09-17 Chong Ye , Quansheng Zhang , Yu-Yuan Chen , Yong Li

The optical activity of oriented molecular systems is investigated using bianisotropic material constitutives for Maxwell's equations. It is shown that the circular birefringence and circular dichroism in a given direction can be…

Chemical Physics · Physics 2015-06-19 Oriol Arteaga

We propose a highly efficient atomically-resolved mode of electron magnetic chiral dichroism. This method exploits the recently introduced orbital angular momentum spectrometer to analyze the inelastically scattered electrons allowing for…

The ability to detect light over a broad spectral range is central for practical optoelectronic applications, and has been successfully demonstrated with photodetectors of two-dimensional layered crystals such as graphene and MoS2. However,…

Circular Dichroism (CD) can distinguish the handedness of chiral molecules. However, it is typically very weak due to vanishing absorption at low molecular concentrations. Here, we suggest Thermal Circular Dichroism (TCD) for chiral…

Optics · Physics 2024-07-19 Ershad Mohammadi , Giulia Tagliabue

The enantiopurification of racemic mixtures of chiral molecules is important for a range of applications. Recent work has shown that chiral group-directed photoisomerization is a promising approach to enantioenrich racemic mixtures of…

Chemical Physics · Physics 2023-01-11 Nam Vu , Grace M. McLeod , Kenneth Hanson , A. Eugene DePrince

Photons with spin angular momentum possess intrinsic chirality which underpins many phenomena including nonlinear optics1, quantum optics2, topological photonics3 and chiroptics4. Intrinsic chirality is weak in natural materials, and recent…

Numerous non-classicality criteria based on the probabilities of experimental photocount or theoretical photon-number distributions are derived using several approaches. Relations among the derived criteria are revealed and the fundamental…

Quantum Physics · Physics 2020-12-02 Jan Perina , Vaclav Michalek , Ondrej Haderka

We develop a microscopic theory of optical absorption and structured-light dichroism in a nonlocal minimal-coupling framework. Starting from the minimal-coupling Hamiltonian, we express absorption as a bilinear functional of the…

Optics · Physics 2026-04-14 Akihito Kato , Nobuhiko Yokoshi

Chiral molecules exhibit enantiosensitive light-matter interactions, with photoelectron circular dichroism (PECD) serving as a sensitive probe of molecular chirality through the asymmetry in the photoelectron wavepacket amplitude. Here, we…

Atomic Physics · Physics 2025-05-07 Zheming Zhou , Yang Li , Xu Zhang , Yueming Zhou , Peixiang Lu

Theory shows that a slab of a dielectric structurally chiral material (DSCM) exhibits both linear and circular dichroisms because of its anisotropy and structural chirality, for normal as well as oblique incidence. This conclusion was…

Optics · Physics 2018-06-11 Patrick D. McAtee , Akhlesh Lakhtakia

In this study, we investigate the nonlinear optical phenomena emerging from the interaction of vortex and vector beams with achiral nanoparticles or nanostructures. We reveal the conditions under which linear or nonlinear dichroism can be…

Optics · Physics 2024-06-13 Anastasia Nikitina , Kristina Frizyuk

We predict a discriminatory interaction between a chiral molecule and an achiral molecule which is mediated by a chiral body. To achieve this, we generalize the van der Waals interaction potential between two ground-state molecules with…

Quantum Physics · Physics 2017-05-19 Pablo Barcellona , Hassan Safari , A. Salam , Stefan Yoshi Buhmann

Molecular chirality detection and enantiomer discrimination are very important issues for many areas of science and technology, prompting intensive investigations via optical methods. However, these methods are hindered by the intrinsically…

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