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It is widely accepted that the Poisson-Boltzmann (PB) theory provides a valid description for charged surfaces in the so-called weak coupling limit. Here, we show that the image charge repulsion creates a depletion boundary layer that…

Chemical Physics · Physics 2015-06-23 Rui Wang , Zhen-Gang Wang

The properties of ionic solutions between charged surfaces are often studied within the Poisson-Boltzmann framework, by finding the electrostatic potential profile. For example, the osmotic pressure between two charged planar surfaces can…

Soft Condensed Matter · Physics 2022-08-04 Ram M. Adar , David Andelman

The stable configurations formed by two viscoelastic, ellipsoid-shaped droplets during their arrested coalescence has been investigated using micromanipulation experiments. Ellipsoidal droplets are produced by millifluidic emulsification of…

Soft Condensed Matter · Physics 2018-08-14 Chen Hao , Zhaoyu Xie , Timothy J. Atherton , Patrick T. Spicer

When colloidal droplets evaporate, suspended particles are redistributed by a competition between evaporation-driven capillary advection, interfacial Marangoni stresses and particle mobility, leading to diverse deposition patterns relevant…

Soft Condensed Matter · Physics 2026-04-10 Meneka Banik , Ranjini Bandyopadhyay

We study the effect of salts on the thickness of wetting films on melting ice and interactions acting on CO$_2$ bubble near ice-water and vapor-water interfaces. Governing mechanisms are the Lifshitz and the double-layer interactions in the…

Soft Condensed Matter · Physics 2016-08-03 P. Thiyam , E. R. A. Lima , O. I. Malyi , D. F. Parsons , S. Y. Buhmann , C. Persson , M. Boström

For one-dimensional many-body systems interacting via the \textit{Coulomb force} and with \textit{arbitrary} external potential energy, we derive (\textit{i}) the \textit{node coalescence condition} for the wave function. This condition…

Materials Science · Physics 2007-05-23 Xiao-Yin Pan , Viraht Sahni

We consider two charged semipermeable membranes, which bound bulk electrolyte solutions and are separated by a thin film of salt-free liquid. Small counter-ions permeate into the gap, which leads to a steric charge separation in the system.…

Soft Condensed Matter · Physics 2016-11-23 Salim R. Maduar , Olga I. Vinogradova

A mesoscopic theory for water-in-salt electrolytes combining density functional and field-theoretic methods is developed in order to explain the unexpectedly large period of the oscillatory decay of the disjoining pressure observed in…

Soft Condensed Matter · Physics 2021-09-29 Oksana Patsahan , Alina Ciach

Despite its relevance in biology and engineering, the molecular mechanism driving cavitation in water remains unknown. Using computer simulations, we investigate the structure and dynamics of vapor bubbles emerging from metastable water at…

We study the instabilities occurring during the burst of an air balloon in a liquid. These instabilities are typical for the deformation of an interface between two fluids of different densities, similar to fingering in Rayleigh-Taylor…

Fluid Dynamics · Physics 2015-05-13 Enrique Soto , Andrew Belmonte

Water mediates electrostatic interactions via the orientation of its dipoles around ions, molecules, and interfaces. This induced water polarization consequently influences multiple phenomena. In particular, water polarization modulated by…

In this paper we study the dynamics of a layer of incompressible viscous fluid bounded below by a rigid boundary and above by a free boundary, in the presence of a uniform gravitational field. We assume that a mass of surfactant is present…

Analysis of PDEs · Mathematics 2017-02-09 Ian Tice , Lei Wu

The computational and theoretical analysis carried out in this article demonstrates the existence of a nontrivial mechanism for the compression of a submicron-sized gas bubble formed by a gas of classical ions and a gas of degenerate…

It is theoretically shown that the excess liquid-liquid interfacial tension between two electrolyte solutions as a function of the ionic strength I behaves asymptotically as O(- I^0.5) for small I and as O(+- I) for large I. The former…

Soft Condensed Matter · Physics 2011-09-14 Markus Bier , Jos Zwanikken , Rene van Roij

Recent studies of the hydration of micro- and nanoscale solutes have demonstrated a strong {\it coupling} between hydrophobic, dispersion and electrostatic contributions, a fact not accounted for in current implicit solvent models. We…

Chemical Physics · Physics 2009-11-11 J. Dzubiella , J. M. J. Swanson , J. A. McCammon

We predict the nature (attractive or repulsive) and range (exponentially screened or long-range power law) of the electrostatic interactions of oppositely charged and planar plates as a function of the salt concentration and surface charge…

Soft Condensed Matter · Physics 2012-01-31 Dan Ben-Yaakov , Yoram Burak , David Andelman , S. A. Safran

The key kinetic barrier to dolomite formation is related to the surface Mg2+-H2O complex, which hinders binding of surface Mg2+ ions to the CO3 2- ions in solution. It has been proposed that this reaction can be catalyzed by dissolved…

Geophysics · Physics 2016-08-12 Zhizhang Shen , Yun Liu , Philip E. Brown , Izabela Szlufarska , Huifang Xu

Thermocapillary convection is particularly effective for the control of thin liquid film topography or for the actuation of microparticles at the liquid-air interface. Experiments with water are challenging, however, as its interface is…

Soft Condensed Matter · Physics 2024-11-25 Thomas Bickel

The collapse of a gas or vapour bubble near a non-porous boundary is directed at the boundary due to the asymmetry induced by the nearby boundary. High surface pressure and shear stress from this collapse can damage, or clean, the surface.…

Fluid Dynamics · Physics 2023-05-10 Elijah D. Andrews , David Fernández Rivas , Ivo R. Peters

Recent work on single bubble sonoluminescence (SBSL) has shown that many features of this phenomenon, especially the dependence of SBSL intensity and stability on experimental parameters, can be explained within a hydrodynamic approach.…