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Single crystals of Fe-substituted Cu2Mn1-xFexBO5 ludwigites have been synthesized using flux technique (x=0.2, 0.4, 0.5 - in the initial flux system). Structural properties of the synthesized compounds were studied by the single crystal and…

The effect of chemical substitution on the ground state of the geometrically frustrated antiferromagnet CsCrF$_4$ has been investigated through a neutron powder diffraction experiment. Magnetic Fe-substituted CsCr$_{0.94}$Fe$_{0.06}$F$_{4}$…

Strongly Correlated Electrons · Physics 2020-12-01 Shohei Hayashida , Masato Hagihala , Maxim Avdeev , Yoko Miura , Hirotaka Manaka , Takatsugu Masuda

According to defect chemistry, the experimental observations of enhanced cation diffusion in a reducing atmosphere in zirconia, ceria and barium titanate are in support of an interstitial mechanism. Yet previous computational studies always…

Materials Science · Physics 2018-08-16 Yanhao Dong , Liang Qi , Ju Li , I-Wei Chen

Different configurations of magnetic orders and cation distributions for NiFe2O4 are studied by the density functional based methods with the possible inclusion of the on-site Coulomb interaction U. The lowest energy state is an inverse…

Materials Science · Physics 2011-05-10 Ching Cheng

The geometrically frustrated antiferromagnetic Swedenborgite DyBaCo$_{4}$O$_{7}$ is investigated by a combination of xray diffraction, magnetization and dielectric measurements. Systematic doping in the series…

Strongly Correlated Electrons · Physics 2016-10-12 Soumendra Nath Panja , Jitender Kumar , Shanu Dengre , Sunil Nair

Neutron and X-ray diffraction, magnetic susceptibility, and specific heat measurements have been used to investigate the magnetic and structural phase transitions of the spinel system Fe1+xCr2-xO4(0.0<=x<=1.0). The temperature versus Fe…

A systematic study using neutron diffraction and magnetic susceptibility are reported on Mn substituted ferrimagnetic inverse spinel Ti$_{1-x}$Mn$_{x}$Co$_2$O$_4$ in the temperature interval 1.6 K $\leq$ $T$ $\leq$ 300 K. Our neutron…

Strongly Correlated Electrons · Physics 2020-03-23 P. Pramanik , D. C. Joshi , M. Reehuis , A. Hoser , J. U. Hoffmann , R. S. Manna , T. Sarkar , S. Thota

We investigate the effects of Fe and Co substitutions on the phase stability of the martensitic phase, mechanical, electronic and magnetic properties of magnetic shape memory system Mn$_{2}$NiGa by first-principles Density functional…

Materials Science · Physics 2017-11-15 Ashis Kundu , Sheuly Ghosh , Subhradip Ghosh

A detailed diffraction study of Ca10Cr7O28 is presented which adds significant new insights into the structural and magnetic properties of this compound. A new crystal structure type was used where the a and b axes are doubled compared to…

We present a comprehensive single crystal neutron diffraction investigation of the $\rm Mn_{1-x}Co_{x}WO_4$ with $0.02\leq x \leq0.30$. At lower concentration $x \leq 0.05$, the system is quickly driven into the multiferroic phase with spin…

Strongly Correlated Electrons · Physics 2012-10-01 Feng Ye , Songxue Chi , Jaime A. Fernandez-Baca , Huibo Cao , K. -C. Liang , Yaqi Wang , Bernd Lorenz , C. W. Chu

We study the effects of Cu substitution in Fe1.1Te, the non-superconducting parent compound of the iron-based superconductor, Fe1+yTe1-xSex, utilizing neutron scattering techniques. It is found that the structural and magnetic transitions,…

Orthorhombic Y$_{1-x}$Ca$_x$MnO$_3$ ($0 \leq x \leq 0.5$) was prepared under high pressure and the variations with $x$ of its structural, magnetic, electrical properties and the polarized Raman spectra were investigated. The lattice…

Materials Science · Physics 2009-11-10 M. N. Iliev , B. Lorenz , A. P. Litvinchuk , Y. -Q. Wang , Y. Y. Sun , C. W. Chu

Very recently, a 3$d$ based honeycomb cobaltate Na$_2$Co$_2$TeO$_6$ has garnered tremendous attention due to the proposed proximity to the Kitaev spin-liquid state as its 4$d$/5$d$ counterparts. Here, we use Zn to substitute Co in a broad…

Single crystal neutron diffraction is used to investigate the magnetic and structural phase diagram of the electron doped superconductor Ba(Fe$_{1-x}$Co$_x$)$_2$As$_2$. Heat capacity and resistivity measurements have demonstrated that Co…

The magnetic and electronic structures of Fe4O5 have been investigated at ambient and high pressures via a combination of representation analysis, density functional theory (DFT+U) calculations, and M\"ossbauer spectroscopy. A few spin…

Materials Science · Physics 2023-01-10 V. S. Zhandun , N. V. Kazak , I. Kupenko , D. M. Vasiukov , X. Li , E. Blackburn , S. G. Ovchinnikov

The antiferromagnetic - ferromagnetic phase transition in YBaCo2O5.50 and YBaCo2O5.44 cobaltites with different types of oxygen-ion ordering in the [YO0.5/0.44] layers has been studied by neutron powder diffraction. Using the magnetic…

Materials Science · Physics 2007-05-23 D. D. Khalyavin , D. N. Argyriou , U. Amann , A. A. Yaremchenko , V. V. Kharton

The structural transitions, magnetic properties, and electronic structures of Co(Fe)-doped MnNiSi compounds are investigated by x-ray powder diffraction (XRD), differential scanning calorimetry (DSC), magnetic measurements, and…

Materials Science · Physics 2015-04-17 Y. Li , Z. Y. Wei , E. K. Liu , G. D. Liu , S. G. Wang , W. H. Wang , G. H. Wu

Zn1-xRxO (R = Li, Mg, Cr, Mn, Fe and Cd) were obtained by using co-precipitation synthesis technique with constant weight percent of 3% from R ions. The phase composition, crystal structure, morphology, Density Functional Theory (DFT), and,…

Materials Science · Physics 2021-10-26 T. A. Abdel-Baset , M. Abdel-Hafiez

Change in structure and magnetic properties of SmCo5-xFex permanent magnets for different values of x ranging from 0 to 2 have been studied. Structural investigation from X-ray diffraction (XRD) patterns confirms the hexagonal CaCu5-type…

Materials Science · Physics 2014-02-04 Bhaskar Das , Balamurugan Balasubramanian , David J. Sellmyer

The role of Co substitution in the low-energy electronic structure of Ca(Fe$_{0.944}$Co$_{0.056}$)$_2$As$_2$ is investigated by resonant photoemission spectroscopy and density functional theory. The Co 3d-state center-of-mass is observed at…

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