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We report the systematic synthesis, crystal structure, magnetization, and powder neutron diffraction of single crystalline and polycrystalline CaCo$_2$TeO$_6$ samples. CaCo$_2$TeO$_6$ crystallizes in an orthorhombic structure with $Pnma$…

Strongly Correlated Electrons · Physics 2025-05-19 Xing Huang , Peiyue Ma , Mengwu Huo , Chaoxin Huang , Hualei Sun , Xiang Chen , Sihao Deng , Lunhua He , Tao Xie , Zhangzhen He , Meng Wang

We report on the crystal structure of the quantum magnet (CuCl)LaNb2O7 that was controversially described with respect to its structural organization and magnetic behavior. Using high-resolution synchrotron powder x-ray diffraction,…

Materials Science · Physics 2015-03-17 Alexander A. Tsirlin , Artem M. Abakumov , Gustaaf Van Tendeloo , Helge Rosner

Magnetism in the orthorhombic metal CaFe$_4$As$_3$ was examined through neutron diffraction for powder and single crystalline samples. Incommensurate (${\bm q}_{\rm m}\approx (0.37-0.39)\times{\bm b}^{\ast}$) and predominantly…

We present a comprehensive magnetic and structural phase diagram for $\mathrm{Y_{1-x}Lu_xBaCo_4O_7}$, established through neutron diffraction and magnetization measurements. Our results outline the evolution of various nuclear structures,…

Strongly Correlated Electrons · Physics 2023-12-08 Sevda Sahinbay , Hong Zheng , John F. Mitchell , Stephan Rosenkranz , Omar Chmaissem

We report the effects of Al-doping on the structure and magnetic properties in CaBa(Co$_{1-x}$Al$_{x}$)$_4$O$_7$ (0$\leq$x$\leq$0.25). The system exhibits a structural transition from an orthorhombic symmetry to a hexagonal symmetry when…

Materials Science · Physics 2013-04-05 Youming Zou , Zhe Qu , Lei Zhang , Wei Ning , Langsheng Ling , Li Pi , Yuheng Zhang

We studied the structural and magnetic properties of the solid solution Fe$_{1-x}$Ni$_{x}$B through theoretical and experimental approaches. Powder X-ray diffraction, X-ray Pair Distribution Function analysis, and energy dispersive X-ray…

By studying Fe-doped ZnO pellets and thin films with various x-ray spectroscopic techniques, and complementing this with density functional theory calculations, we find that Fe-doping in bulk ZnO induces isovalent (and isostructural) cation…

The candidate magnetoelectric Pb3Mn7O15 has a structure consisting of 1/3 filled Kagome layers linked by ribbons of edge-sharing octahedra in the stacking direction. Previous reports have indicated a complex hexagonal-orthorhombic…

Strongly Correlated Electrons · Physics 2012-04-18 Simon A. J. Kimber

The dynamic magnetic properties of the Kondo-insulator state in CeFe2Al10 (spin gap, resonance mode) have been investigated using polarized neutrons on a single crystal of pure CeFe2Al10. The results indicate that the magnetic excitations…

Strongly Correlated Electrons · Physics 2020-09-21 P. A. Alekseev , J. -M. Mignot , D. T. Adroja , V. N. Lazukov , H. Tanida , Y. Muro , M. Sera , T. Takabatake , P. Steffens , S. Rols

In this paper the effect of the chemical pressure induced by the Sr replacement for Ca in the La1.4Sr1.6Mn2O7 lattice is directly probed by means of neutron diffraction as a function of temperature. The results show a progressive change of…

Materials Science · Physics 2007-10-25 Lorenzo Malavasi , Clemens Ritter , M. Cristina Mozzati , Carlo B. Azzoni , Giorgio Flor

The structural and magnetic phase transitions have been studied on NdFeAsO single crystals by neutron and x-ray diffraction complemented by resistivity and specific heat measurements. Two low-temperature phase transitions have been observed…

Atomic, electronic, and magnetic structure of LaSrCo$_{1/2}$Fe$_{1/2}$O$_4$ mixed-metal Ruddlesden-Popper oxide is investigated theoretically using self-consistent ACBN0 DFT + $U$ approach. We show that the electronic and magnetic…

Low temperature magnetic and structural behavior of the extended Kagome system YBaCo4O7 has been studied by single crystal neutron diffraction and high-resolution powder X-ray diffraction. Long-range magnetic ordering associated with a…

Materials Science · Physics 2015-05-19 D. D. Khalyavin , P. Manuel , B. Ouladdiaf , A. Huq , H. Zheng , J. F. Mitchell , L. C. Chapon

We investigate the magnetic structure of Mn3-xFexSn2 using neutron powder diffraction experiments and electronic structure calculations. These alloys crystallize in the orthorhombic Ni3Sn2 type of structure (Pnma) and comprise two…

Materials Science · Physics 2013-09-03 Q. Recour , V. Ban , Z. Gercsi , T. Mazet , M. Francois , B. Malaman

Employing aberration-corrected scanning transmission electron microscopy (STEM), we meticulously investigated the intrinsic chemical heterogeneity of Fe1+yTe, Fe1+yTe0.8Se0.2, and Fe1+yTe0.5Se0.5. Comprehensive analysis reveals the presence…

We have performed non-resonant x-ray diffraction, resonant soft and hard x-ray magnetic diffraction, soft x-ray absorption and x-ray magnetic circular dichroism measurements to clarify the electronic and magnetic states of the Co3+ ions in…

Based on first-principles calculations we show that the oxidation of ultrathin films of Ca$_2$N electrides, electrenes, drives a hexagonal$\rightarrow$tetragonal structural transition. The ground state configuration of the oxidized…

Materials Science · Physics 2020-05-06 Pedro H. Souza , José E. Padilha , Roberto H. Miwa

We have synthesized and characterized different stable phases of sodium cobaltates Na$_{x}$CoO$_{2}$ with sodium content $0.65<x<0.80$. We demonstrate that $^{23}$Na NMR allows to determine the difference in the susceptibility of the phases…

Strongly Correlated Electrons · Physics 2015-03-04 I. R. Mukhamedshin , H. Alloul

The evolution of the electronic structure and magnetic properties with Co substitution for Fe in the solid solution Fe$_{1-x}$Co$_x$Ga$_3$ was studied by means of electrical resistivity, magnetization, ab-initio band structure calculations,…

The local structural environment and the spatial distribution of iron and aluminum ions in sodosilicate glasses with composition NaFexAl1-xSi2O6 (x = 1, 0.8, 0.5 and 0) is studied by high-resolution neutron diffraction combined with…

Materials Science · Physics 2008-12-18 Coralie Weigel , Laurent Cormier , Georges Calas , Laurence Galoisy , Daniel Bowron
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